CIESC Journal ›› 2021, Vol. 72 ›› Issue (1): 14-26.DOI: 10.11949/0438-1157.20200863
• Reviews and monographs • Previous Articles Next Articles
CHEN Rundao1(),ZHENG Fang1,GUO Lidong1,YANG Qiwei1,2,ZHANG Zhiguo1,2,YANG Yiwen1,2,REN Qilong1,2,BAO Zongbi1,2()
Received:
2020-07-01
Revised:
2020-07-16
Online:
2021-01-05
Published:
2021-01-05
Contact:
BAO Zongbi
陈润道1(),郑芳1,郭立东1,杨启炜1,2,张治国1,2,杨亦文1,2,任其龙1,2,鲍宗必1,2()
通讯作者:
鲍宗必
作者简介:
陈润道(1998—),男,博士研究生,基金资助:
CLC Number:
CHEN Rundao, ZHENG Fang, GUO Lidong, YANG Qiwei, ZHANG Zhiguo, YANG Yiwen, REN Qilong, BAO Zongbi. Advancements in adsorption separation of Xe/Kr noble gases[J]. CIESC Journal, 2021, 72(1): 14-26.
陈润道, 郑芳, 郭立东, 杨启炜, 张治国, 杨亦文, 任其龙, 鲍宗必. 稀有气体Xe/Kr吸附分离研究进展[J]. 化工学报, 2021, 72(1): 14-26.
Fig.2 Pore structure of SBMOF-2(a); Binding sites of Xe with pore Ⅰ (upper) and pore II (lower) in SBMOF-2 (b); Isotherms of Xe/Kr in SBMOF-2 collected at 298 K (c)
Fig.3 Structure of UiO-66(a); Functionalized ligands for UiO-66 (b); IAST-predicted Xe/Kr selectivity at 283 K for pristine and functionalized UiO-66 materials (Xe/Kr=20∶80) (c)
Fig.6 Co squarate structure with -OH groups decorated in channels (a); Xe binding site in Co squarate (b); Xe adsorption isotherms of Co squarate at low pressure at 298 K and comparison with other materials (c); Comparison of the IAST selectivity of Co squarate versus other materials for Xe/Kr (20/80) mixtures at 298 K (d)
吸附剂 | Xe吸附容量/ (mmol·g-1) | IAST选择性 (Xe/Kr=20∶80) | Xe等量吸附热Qst/ (kJ·mol-1) | Xe Henry系数/(mmol·g-1·bar-1) | Henry选择性 |
---|---|---|---|---|---|
MOF-5 | 1.98 | 3 | 13.75 | — | 8.56 |
HKUST-1 | 3.3 | 2.6 | 17.5 | 12.2 | 8.5 |
Ni-MOF-74 | 4.2 | 4 | 22 | 8.4 | 5.8 |
Ag@Ni-MOF-74 | 4.6 | 11.5 | 23.6 | — | — |
MOF-505 | 6.31 | 9~10 | — | 10.26 | 6.8 |
Co3(HCOO)6 | 2 | 12 | 28 | 9.9 | 8.7 |
MOF-Cu-H | 3.19 | 15.8 | 33.4 | 39.74 | 15.8 |
UiO-66 | 1.58 | ~7 | ~22 | — | — |
NU-403-PSDH | 2.23 | ~9 | ~26 | — | — |
CPM-6 | 2.89 | 7.3 | 25.1 | 6.15 | 7.2 |
Co2+-CPM-6 | 3.20 | 9.3 | 25.9 | 6.28 | 7.8 |
SBMOF-2 | 2.83 | 10 | 26.4 | 10.5 | 8.6 |
SBMOF-1 | 1.38 | 16① | 35 | 38.42 | 16.2 |
CROFOUR-1-Ni | 1.8 | 22 | 37.4 | 18.73 | 24.3 |
CROFOUR-2-Ni | 1.5 | 15.5 | 30.5 | 15.95 | 18.5 |
Co squarate | 1.35 | 69.7 | 43.6 | 192.06 | 51.4 |
UTSA-49 | 3 | 9.2 | 23.53 | — | — |
ZU-62 | 3.76 | 9.72② | 35.2③ | — | — |
FMOF-Cu | 0.8 | 2④ | 15 | — | — |
NaA | 1.52~2.28 | 4.5⑤ | — | — | — |
AgZ-PAN | 0.46⑥ | 4.6⑦ | — | — | — |
Ag@ZSM-5 | ~1.2 | ~40 | 65 | — | ~3 |
activated carbon | 4.2 | 2.9 | 28.2 | 16.2 | 9.1 |
Z11CBF-1000-2 | 4.87 | 13.0 | 32.1 | 80.0 | 19.7 |
CC3 | 2.69 | 20.4 | 31.3 | ~19 | ~2 |
Noria | 1.55 | 9.4 | 24.5~26.9 | ~9 | ~9.5 |
Table 1 Xe adsorption capacity and Xe/Kr selectivity for various materials at 298 K and 100 kPa
吸附剂 | Xe吸附容量/ (mmol·g-1) | IAST选择性 (Xe/Kr=20∶80) | Xe等量吸附热Qst/ (kJ·mol-1) | Xe Henry系数/(mmol·g-1·bar-1) | Henry选择性 |
---|---|---|---|---|---|
MOF-5 | 1.98 | 3 | 13.75 | — | 8.56 |
HKUST-1 | 3.3 | 2.6 | 17.5 | 12.2 | 8.5 |
Ni-MOF-74 | 4.2 | 4 | 22 | 8.4 | 5.8 |
Ag@Ni-MOF-74 | 4.6 | 11.5 | 23.6 | — | — |
MOF-505 | 6.31 | 9~10 | — | 10.26 | 6.8 |
Co3(HCOO)6 | 2 | 12 | 28 | 9.9 | 8.7 |
MOF-Cu-H | 3.19 | 15.8 | 33.4 | 39.74 | 15.8 |
UiO-66 | 1.58 | ~7 | ~22 | — | — |
NU-403-PSDH | 2.23 | ~9 | ~26 | — | — |
CPM-6 | 2.89 | 7.3 | 25.1 | 6.15 | 7.2 |
Co2+-CPM-6 | 3.20 | 9.3 | 25.9 | 6.28 | 7.8 |
SBMOF-2 | 2.83 | 10 | 26.4 | 10.5 | 8.6 |
SBMOF-1 | 1.38 | 16① | 35 | 38.42 | 16.2 |
CROFOUR-1-Ni | 1.8 | 22 | 37.4 | 18.73 | 24.3 |
CROFOUR-2-Ni | 1.5 | 15.5 | 30.5 | 15.95 | 18.5 |
Co squarate | 1.35 | 69.7 | 43.6 | 192.06 | 51.4 |
UTSA-49 | 3 | 9.2 | 23.53 | — | — |
ZU-62 | 3.76 | 9.72② | 35.2③ | — | — |
FMOF-Cu | 0.8 | 2④ | 15 | — | — |
NaA | 1.52~2.28 | 4.5⑤ | — | — | — |
AgZ-PAN | 0.46⑥ | 4.6⑦ | — | — | — |
Ag@ZSM-5 | ~1.2 | ~40 | 65 | — | ~3 |
activated carbon | 4.2 | 2.9 | 28.2 | 16.2 | 9.1 |
Z11CBF-1000-2 | 4.87 | 13.0 | 32.1 | 80.0 | 19.7 |
CC3 | 2.69 | 20.4 | 31.3 | ~19 | ~2 |
Noria | 1.55 | 9.4 | 24.5~26.9 | ~9 | ~9.5 |
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