CIESC Journal ›› 2019, Vol. 70 ›› Issue (S2): 50-53.DOI: 10.11949/0438-1157.20190579
• Thermodynamics • Previous Articles Next Articles
Bo SONG1(),Min YANG1,Ran AN2,Xiaopo WANG1
Received:
2019-05-28
Revised:
2019-06-12
Online:
2019-09-06
Published:
2019-09-06
Contact:
Bo SONG
通讯作者:
宋渤
作者简介:
宋渤(1986—),男,博士,副教授,基金资助:
CLC Number:
Bo SONG,Min YANG,Ran AN,Xiaopo WANG. Accurate calculations of second dielectric virial coefficient of noble gases[J]. CIESC Journal, 2019, 70(S2): 50-53.
宋渤,杨敏,安然,王晓坡. 单原子气体第二介电维里系数准确计算[J]. 化工学报, 2019, 70(S2): 50-53.
文献 | 年份 | 对象 | 不确定度 |
---|---|---|---|
[ | 2017 | He-He | 0.0023% |
[ | 2008 | Ne-Ne | 未给出 |
[ | 2010 | Ar-Ar | 0.32% |
Table 1 Ab initio interatomic potential
文献 | 年份 | 对象 | 不确定度 |
---|---|---|---|
[ | 2017 | He-He | 0.0023% |
[ | 2008 | Ne-Ne | 未给出 |
[ | 2010 | Ar-Ar | 0.32% |
文献 | 年份 | 对象 | 不确定度 |
---|---|---|---|
[ | 2011 | He-He | 0.00023% |
[ | 2003 | Ne-Ne | 未给出 |
[ | 2010 | Ar-Ar | 未给出 |
Table 2 Ab initio interatomic polarizability
文献 | 年份 | 对象 | 不确定度 |
---|---|---|---|
[ | 2011 | He-He | 0.00023% |
[ | 2003 | Ne-Ne | 未给出 |
[ | 2010 | Ar-Ar | 未给出 |
T/K | B ε/ (cm6·mol-2) | [1/1] Padé/(cm6·mol-2) | σ/ (cm6·mol-2) | σ from V/% | σ from Δα ave/% |
---|---|---|---|---|---|
25 | -0.01162 | -0.008735 | 0.000177 | 0.13 | 99.86 |
30 | -0.01179 | -0.01017 | 0.00018 | 0.13 | 99.87 |
35 | -0.01255 | -0.01153 | 0.00017 | 0.13 | 99.87 |
40 | -0.01353 | -0.01285 | 0.00017 | 0.13 | 99.87 |
45 | -0.01459 | -0.01411 | 0.00017 | 0.12 | 99.88 |
50 | -0.01568 | -0.01533 | 0.00017 | 0.12 | 99.88 |
60 | -0.01785 | -0.01764 | 0.00017 | 0.12 | 99.88 |
70 | -0.01995 | -0.01982 | 0.00017 | 0.12 | 99.88 |
80 | -0.02197 | -0.02188 | 0.00017 | 0.12 | 99.88 |
90 | -0.02391 | -0.02385 | 0.00017 | 0.12 | 99.88 |
100 | -0.02578 | -0.02573 | 0.00017 | 0.12 | 99.88 |
150 | -0.03417 | -0.03415 | 0.00017 | 0.11 | 99.89 |
200 | -0.04142 | -0.04141 | 0.00017 | 0.11 | 99.89 |
250 | -0.04787 | -0.04787 | 0.00018 | 0.11 | 99.89 |
273.15 | -0.05065 | -0.05065 | 0.00018 | 0.11 | 99.89 |
273.16 | -0.05065 | -0.05065 | 0.00018 | 0.11 | 99.89 |
293.15 | -0.05296 | -0.05296 | 0.00018 | 0.11 | 99.89 |
298.15 | -0.05353 | -0.05352 | 0.00018 | 0.11 | 99.89 |
300 | -0.05373 | -0.05373 | 0.00018 | 0.11 | 99.89 |
350 | -0.05913 | -0.05912 | 0.00018 | 0.11 | 99.89 |
400 | -0.06414 | -0.06414 | 0.00018 | 0.11 | 99.89 |
450 | -0.06884 | -0.06884 | 0.00018 | 0.11 | 99.89 |
500 | -0.07327 | -0.07326 | 0.00018 | 0.11 | 99.89 |
600 | -0.08145 | -0.08145 | 0.00018 | 0.11 | 99.89 |
? | ? | ? | ? | ? | ? |
10000 | -0.29473 | -0.29473 | 0.000199 | 0.09 | 99.91 |
Table 3 Second dielectric virial coefficient of helium-4
T/K | B ε/ (cm6·mol-2) | [1/1] Padé/(cm6·mol-2) | σ/ (cm6·mol-2) | σ from V/% | σ from Δα ave/% |
---|---|---|---|---|---|
25 | -0.01162 | -0.008735 | 0.000177 | 0.13 | 99.86 |
30 | -0.01179 | -0.01017 | 0.00018 | 0.13 | 99.87 |
35 | -0.01255 | -0.01153 | 0.00017 | 0.13 | 99.87 |
40 | -0.01353 | -0.01285 | 0.00017 | 0.13 | 99.87 |
45 | -0.01459 | -0.01411 | 0.00017 | 0.12 | 99.88 |
50 | -0.01568 | -0.01533 | 0.00017 | 0.12 | 99.88 |
60 | -0.01785 | -0.01764 | 0.00017 | 0.12 | 99.88 |
70 | -0.01995 | -0.01982 | 0.00017 | 0.12 | 99.88 |
80 | -0.02197 | -0.02188 | 0.00017 | 0.12 | 99.88 |
90 | -0.02391 | -0.02385 | 0.00017 | 0.12 | 99.88 |
100 | -0.02578 | -0.02573 | 0.00017 | 0.12 | 99.88 |
150 | -0.03417 | -0.03415 | 0.00017 | 0.11 | 99.89 |
200 | -0.04142 | -0.04141 | 0.00017 | 0.11 | 99.89 |
250 | -0.04787 | -0.04787 | 0.00018 | 0.11 | 99.89 |
273.15 | -0.05065 | -0.05065 | 0.00018 | 0.11 | 99.89 |
273.16 | -0.05065 | -0.05065 | 0.00018 | 0.11 | 99.89 |
293.15 | -0.05296 | -0.05296 | 0.00018 | 0.11 | 99.89 |
298.15 | -0.05353 | -0.05352 | 0.00018 | 0.11 | 99.89 |
300 | -0.05373 | -0.05373 | 0.00018 | 0.11 | 99.89 |
350 | -0.05913 | -0.05912 | 0.00018 | 0.11 | 99.89 |
400 | -0.06414 | -0.06414 | 0.00018 | 0.11 | 99.89 |
450 | -0.06884 | -0.06884 | 0.00018 | 0.11 | 99.89 |
500 | -0.07327 | -0.07326 | 0.00018 | 0.11 | 99.89 |
600 | -0.08145 | -0.08145 | 0.00018 | 0.11 | 99.89 |
? | ? | ? | ? | ? | ? |
10000 | -0.29473 | -0.29473 | 0.000199 | 0.09 | 99.91 |
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