CIESC Journal ›› 2021, Vol. 72 ›› Issue (8): 4371-4380.DOI: 10.11949/0438-1157.20201787

• Energy and environmental engineering • Previous Articles     Next Articles

Application of Ce1-xNixOy oxygen carriers in chemical-looping reforming of methane coupled with CO2 reduction

Linzhou ZHAO1(),Yan'e ZHENG1,2(),Kongzhai Li2,3,Yaming WANG1,Lihong JIANG1,Haoxi FAN1,Yajing WANG1,Xing ZHU2,3,Yonggang WEI2,3   

  1. 1.Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
    2.State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
    3.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
  • Received:2020-12-09 Revised:2021-04-02 Online:2021-08-05 Published:2021-08-05
  • Contact: Yan'e ZHENG

Ce1-xNixOy氧载体在化学链甲烷重整耦合CO2还原中的应用

赵林洲1(),郑燕娥1,2(),李孔斋2,3,王亚明1,蒋丽红1,范浩熙1,王雅静1,祝星2,3,魏永刚2,3   

  1. 1.昆明理工大学化学工程学院,云南 昆明 650093
    2.昆明理工大学,复杂有色金属资源清洁利用国家重点实验室,云南 昆明 650093
    3.昆明理工大学冶金与能源工程学院,云南 昆明 650093
  • 通讯作者: 郑燕娥
  • 作者简介:赵林洲(1994—),男,硕士研究生,2099941833@qq.com
  • 基金资助:
    国家自然科学基金项目(21706108);云南省应用基础研究项目(2018FD032)

Abstract:

Chemical-looping reforming of methane coupled with CO2 reduction technology can not only produce syngas, but also reduce CO2 to generate CO. In this paper, a series of Ce1-xNixOy(x = 0, 0.2, 0.4, 0.6, 0.8, 1) oxygen carriers with different Ce/Ni molar ratios were prepared by co-precipitation method. The physical and chemical properties of oxygen carriers were characterized by means of XRD, BET, XPS and CH4-TPR. The performance of Ce1-xNixOy oxygen carriers in chemical-looping reforming of methane coupled with CO2 reduction reaction was systematically investigated. Compared with single metal oxide NiO and CeO2, Ce1-xNixOy composite oxygen carriers have higher activity and thermal stability in this reaction. During the partial oxidation of methane, Ce0.2Ni0.8Oy and Ce0.4Ni0.6Oy oxygen carriers have higher CH4 conversion. After 20 redox cycle experiments, the CO2 conversion rate of the Ce0.2Ni0.8Oy oxygen carrier remained almost unchanged, indicating that the Ce0.2Ni0.8Oy oxygen carrier has high thermal stability.

Key words: chemical-looping, reforming of methane, CO2 reduction, syngas, Ce1-xNixOy oxygen carriers

摘要:

化学链甲烷重整耦合CO2还原技术既能生产合成气还可以还原CO2生成CO。采用共沉淀法制备不同Ce/Ni摩尔比的系列Ce1-xNixOyx = 0,0.2,0.4,0.6,0.8,1)氧载体。通过XRD、BET、XPS及CH4-TPR等表征对氧载体的理化性质进行了研究。系统考察了Ce1-xNixOy氧载体在化学链甲烷重整耦合CO2还原反应中的反应性能。与单一金属氧化物NiO和CeO2相比,Ce1-xNixOy复合氧载体在该反应中具有更高的活性和热稳定性。在甲烷部分氧化阶段,Ce0.2Ni0.8Oy和Ce0.4Ni0.6Oy氧载体具有较高的CH4转化率。经历了20次redox循环实验,Ce0.2Ni0.8Oy氧载体的CO2转化率几乎保持不变,表明Ce0.2Ni0.8Oy氧载体具有较高的热稳定性。

关键词: 化学链, 甲烷重整, CO2还原, 合成气, Ce1-xNixOy氧载体

CLC Number: