CIESC Journal ›› 2022, Vol. 73 ›› Issue (1): 255-265.DOI: 10.11949/0438-1157.20211149
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Qianhao WANG1,2(),Lu ZHAO1(),Fulin SUN1,3,Kegong FANG1
Received:
2021-08-12
Revised:
2021-11-10
Online:
2022-01-18
Published:
2022-01-05
Contact:
Lu ZHAO
通讯作者:
赵璐
作者简介:
王乾浩(1994—),男,硕士研究生,基金资助:
CLC Number:
Qianhao WANG, Lu ZHAO, Fulin SUN, Kegong FANG. Production of syngas derived from H2S-CO2via synergy of ZSM-5 catalyst and non-thermal plasma[J]. CIESC Journal, 2022, 73(1): 255-265.
王乾浩, 赵璐, 孙付琳, 房克功. ZSM-5催化剂与低温等离子体协同转化H2S-CO2制合成气[J]. 化工学报, 2022, 73(1): 255-265.
Si/Al比 | 比表面积/(m2/g) | 介电常数ε |
---|---|---|
25 | 305 | 3.15 |
38 | 318 | 3.27 |
50 | 324 | 3.37 |
80 | 306 | 3.42 |
200 | 307 | 3.49 |
Table 1 Specific surface area and dielectric constant of ZSM-5 catalysts with various Si/Al molar ratios
Si/Al比 | 比表面积/(m2/g) | 介电常数ε |
---|---|---|
25 | 305 | 3.15 |
38 | 318 | 3.27 |
50 | 324 | 3.37 |
80 | 306 | 3.42 |
200 | 307 | 3.49 |
Si/Al比 | H2S转化率/% | CO2转化率/% |
---|---|---|
25 | 5.0 | 0.9 |
38 | 2.9 | 0.8 |
50 | 3.5 | 1.3 |
80 | 5.3 | 1.4 |
200 | 5.9 | 1.2 |
Table 2 The thermal conversion of H2S-CO2 in the presence of packing various ZSM-5 catalysts without non-thermal plasma
Si/Al比 | H2S转化率/% | CO2转化率/% |
---|---|---|
25 | 5.0 | 0.9 |
38 | 2.9 | 0.8 |
50 | 3.5 | 1.3 |
80 | 5.3 | 1.4 |
200 | 5.9 | 1.2 |
Fig.4 H2S-CO2 conversion as a function of SEI in the presence of packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml)
Fig.5 Gaseous product distributions, H2 and CO yields and H2/CO molar ratios in H2S-CO2 conversion with packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml)
Fig.6 Q-U Lissajous figures, discharge power and effective capacitance in H2S-CO2 conversion with packing various ZSM-5 catalysts in non-thermal plasma(feed: H2S/CO2 molar ratio = 1∶4; 20%(vol) N2 in H2S-CO2 gas; feed flow rate 200 ml/min; material bed volume 15 ml; input power 95 W)
1 | Hendrickson R G, Chang A, Hamilton R J. Co-worker fatalities from hydrogen sulfide[J]. American Journal of Industrial Medicine, 2004, 45(4): 346-350. |
2 | 刘昌俊, 郭秋婷, 叶静云, 等. 二氧化碳转化催化剂研究进展及相关问题思考[J]. 化工学报, 2016, 67(1): 6-13. |
Liu C J, Guo Q T, Ye J Y, et al. Perspective on catalyst investigation for CO2 conversion and related issues[J]. CIESC Journal, 2016, 67(1): 6-13. | |
3 | Bai S T, de Smet G, Liao Y, et al. Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions[J]. Chemical Society Reviews, 2021, 50(7): 4259-4298. |
4 | Liu J L, Park H W, Chung W J, et al. High-efficient conversion of CO2 in AC-pulsed tornado gliding arc plasma[J]. Plasma Chemistry and Plasma Processing, 2016, 36(2): 437-449. |
5 | Kim S C, Lim M S, Chun Y N. Reduction characteristics of carbon dioxide using a plasmatron[J]. Plasma Chemistry and Plasma Processing, 2014, 34(1): 125-143. |
6 | Zhang K, Mukhriza T, Liu X T, et al. A study on CO2 and CH4 conversion to synthesis gas and higher hydrocarbons by the combination of catalysts and dielectric-barrier discharges[J]. Applied Catalysis A: General, 2015, 502: 138-149. |
7 | Schieweck B G, Jürling-Will P, Klankermayer J. Structurally versatile ligand system for the ruthenium catalyzed one-pot hydrogenation of CO2 to methanol[J]. ACS Catalysis, 2020, 10(6): 3890-3894. |
8 | 吴秀章. 煤制低碳烯烃工艺与工程[M]. 北京: 化学工业出版社, 2014: 111. |
Wu X Z. Coal-to-olefins Technology and Engineering [M]. Beijing: Chemical Industry Press, 2014: 111. | |
9 | Fridman A. Plasma Chemistry[M]. New York:Cambridge University Press, 2008: 13. |
10 | Saleem F, Zhang K, Harvey A P. Decomposition of benzene as a tar analogue in CO2 and H2 carrier gases, using a non-thermal plasma[J]. Chemical Engineering Journal, 2019, 360: 714-720. |
11 | Ellmer K, Lichtenberger D. Plasma diagnostics by energy resolved quadrupole mass spectrometry of a reactive magnetron sputtering discharge from an Fe target in Ar-H2S atmospheres[J]. Surface and Coatings Technology, 1995, 74/75: 586-593. |
12 | Lan L Y, Wang A J, Wang Y. CO2 hydrogenation to lower hydrocarbons over ZSM-5-supported catalysts in a dielectric-barrier discharge plasma reactor[J]. Catalysis Communications, 2019, 130: 105761. |
13 | Zhao L, Wang Y, Jin L, et al. Decomposition of hydrogen sulfide in non-thermal plasma aided by supported CdS and ZnS semiconductors[J]. Green Chemistry, 2013, 15(6): 1509-1513. |
14 | 周柒, 丁红蕾, 郭得通, 等. CO2催化氢化制清洁能源的研究进展及趋势[J]. 化工学报, 2020, 71(8): 3428-3443. |
Zhou Q, Ding H L, Guo D T, et al. Recent advances in catalytic methods of CO2 hydrogenation to clean energy[J]. CIESC Journal, 2020, 71(8): 3428-3443. | |
15 | Zhao L, Liu X Z, Mu X L, et al. Highly selective conversion of H2S-CO2 to syngas by combination of non-thermal plasma and MoS2/Al2O3[J]. Journal of CO2 Utilization, 2020, 37: 45-54. |
16 | 房克功, 赵璐, 李文斌, 等. 转化二氧化碳和硫化氢混合气制取合成气的方法及装置: 107244652B[P]. 2019-12-06. |
Fang K G, Zhao L, Li W B, et al. Method and device for preparing synthetic gas by converting carbon dioxide and hydrogen sulfide mixture: 107244652B[P]. 2019-12-06. | |
17 | Cundy C S, Cox P A. The hydrothermal synthesis of zeolites: precursors, intermediates and reaction mechanism[J]. Microporous and Mesoporous Materials, 2005, 82(1/2): 1-78. |
18 | Derouane E G, Determmerie S, Gabelica Z, et al. Synthesis and characterization of ZSM-5 type zeolites Ⅰ. Physico-chemical properties of precursors and intermediates[J]. Applied Catalysis, 1981, 1(3/4): 201-224. |
19 | Kim H H, Lee Y H, Ogata A, et al. Plasma-driven catalyst processing packed with photocatalyst for gas-phase benzene decomposition[J]. Catalysis Communications, 2003, 4(7): 347-351. |
20 | Zhao L, Wang Y, Li X, et al. Hydrogen production via decomposition of hydrogen sulfide by synergy of non-thermal plasma and semiconductor catalysis[J]. International Journal of Hydrogen Energy, 2013, 38(34): 14415-14423. |
21 | Pour A N, Zare M, Kamali Shahri S M, et al. Catalytic behaviors of bifunctional Fe-HZSM-5 catalyst in Fischer-Tropsch synthesis[J]. Journal of Natural Gas Science and Engineering, 2009, 1(6): 183-189. |
22 | 滕加伟, 赵国良, 谢在库, 等. ZSM-5分子筛晶粒尺寸对C4烯烃催化裂解制丙烯的影响[J]. 催化学报, 2004, 25(8): 602-606. |
Teng J W, Zhao G L, Xie Z K, et al. Effect of ZSM-5 zeolite crystal size on propylene production from catalytic cracking of C4 olefins[J]. Chinese Journal of Catalysis, 2004, 25(8): 602-606. | |
23 | Chen H L, Lee H M, Chen S H, et al. Review of plasma catalysis on hydrocarbon reforming for hydrogen production—interaction, integration, and prospects[J]. Applied Catalysis B: Environmental, 2008, 85(1/2): 1-9. |
24 | Zhang X, Liu Y, Zhang M T, et al. Synergy between β-Mo2C nanorods and non-thermal plasma for selective CO2 reduction to CO[J]. Chem, 2020, 6(12): 3312-3328. |
25 | Diao Y N, Zhang X, Liu Y, et al. Plasma-assisted dry reforming of methane over Mo2C-Ni/Al2O3 catalysts: effects of β-Mo2C promoter[J]. Applied Catalysis B: Environmental, 2022, 301: 120779. |
26 | Liu X Z, Zhao L, Li Y, et al. Ni-Mo sulfide semiconductor catalyst with high catalytic activity for one-step conversion of CO2 and H2S to syngas in non-thermal plasma[J]. Catalysts, 2019, 9(6): 525. |
27 | Zeng Y X, Tu X. Plasma-catalytic hydrogenation of CO2 for the cogeneration of CO and CH4 in a dielectric barrier discharge reactor: effect of argon addition[J]. Journal of Physics D: Applied Physics, 2017, 50(18): 184004. |
28 | Liang W J, Fang H P, Li J, et al. Performance of non-thermal DBD plasma reactor during the removal of hydrogen sulfide[J]. Journal of Electrostatics, 2011, 69(3): 206-213. |
29 | Zhang X H, Lin L, Zhang T, et al. Catalytic dehydration of lactic acid to acrylic acid over modified ZSM-5 catalysts[J]. Chemical Engineering Journal, 2016, 284: 934-941. |
30 | 邹吉军. 等离子体处理制备高效催化剂的基础研究[D]. 天津: 天津大学, 2005. |
Zou J J. On the preparation of highly efficient catalysts using cold plasma treatment[D]. Tianjin: Tianjin University, 2005. | |
31 | Snoeckx R, Bogaerts A. Plasma technology—a novel solution for CO2 conversion? [J]. Chemical Society Reviews, 2017, 46(19): 5805-5863. |
32 | Zhang L P, Karakas G, Ozkan U S. NiMoS/γ-Al2O3 catalysts: the nature and the aging behavior of active sites in HDN reactions[J]. Journal of Catalysis, 1998, 178(2): 457-465. |
33 | Zhao L, Wang Y, Wang A J, et al. Cr-doped ZnS semiconductor catalyst with high catalytic activity for hydrogen production from hydrogen sulfide in non-thermal plasma[J]. Catalysis Today, 2019, 337: 83-89. |
34 | Zhao G B, John S, Zhang J J, et al. Production of hydrogen and sulfur from hydrogen sulfide in a nonthermal-plasma pulsed corona discharge reactor[J]. Chemical Engineering Science, 2007, 62(8): 2216-2227. |
35 | Lacroix M, Dumonteil C, Breysse M, et al. Hydrogen activation on alumina supported MoS2 based catalysts: role of the promoter[J]. Journal of Catalysis, 1999, 185(1): 219-222. |
36 | Wang A Q, Ma L, Cong Y, et al. Unique properties of Ir/ZSM-5 catalyst for NO reduction with CO in the presence of excess oxygen[J]. Applied Catalysis B: Environmental, 2003, 40(4): 319-329. |
37 | Lupinetti A J, Fau S, Frenking G, et al. Theoretical analysis of the bonding between CO and positively charged atoms[J]. The Journal of Physical Chemistry A, 1997, 101(49): 9551-9559. |
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