CIESC Journal ›› 2022, Vol. 73 ›› Issue (12): 5555-5563.DOI: 10.11949/0438-1157.20221339
• Energy and environmental engineering • Previous Articles Next Articles
Bozheng LIU1,2(), Jingbo WANG2, Tao ZENG2, Yaxia YIN1, Yuguo GUO1()
Received:
2022-10-11
Revised:
2022-11-28
Online:
2023-01-17
Published:
2022-12-05
Contact:
Yuguo GUO
刘伯峥1,2(), 王静波2, 曾涛2, 殷雅侠1, 郭玉国1()
通讯作者:
郭玉国
作者简介:
刘伯峥(1989—),男,博士,高级工程师,liubozheng@iccas.ac.cn
基金资助:
CLC Number:
Bozheng LIU, Jingbo WANG, Tao ZENG, Yaxia YIN, Yuguo GUO. Safety differences of LiFePO4 batteries at the beginning of life and end of life[J]. CIESC Journal, 2022, 73(12): 5555-5563.
刘伯峥, 王静波, 曾涛, 殷雅侠, 郭玉国. 磷酸铁锂电池寿命初期与末期安全性差异[J]. 化工学报, 2022, 73(12): 5555-5563.
电池状态 | 热导率/(W/(m·K)) | 比热容/ (J/(g·℃)) | ||
---|---|---|---|---|
高度方向 | 宽度方向 | 厚度方向 | ||
BOL | 25.84 | 21.21 | 1.05 | 1.088 |
EOL | 22.20 | 18.44 | 1.00 | 1.065 |
Table 1 Themal conductivity and specific heat capacity contrast of BOL and EOL batteries
电池状态 | 热导率/(W/(m·K)) | 比热容/ (J/(g·℃)) | ||
---|---|---|---|---|
高度方向 | 宽度方向 | 厚度方向 | ||
BOL | 25.84 | 21.21 | 1.05 | 1.088 |
EOL | 22.20 | 18.44 | 1.00 | 1.065 |
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3345 | +12.5 | 0 | +6.6 |
EOL | -3346 | +65.1 | 0 | +28.0 |
Table 2 Voltage, resistance, mass and thickness change of BOL and EOL batteries after overdischarge
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3345 | +12.5 | 0 | +6.6 |
EOL | -3346 | +65.1 | 0 | +28.0 |
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | +100 | +40.0 | -11.0 | +3.0 |
EOL | +19 | +40.1 | -46.0 | +2.1 |
Table 3 Voltage, resistance, mass and thickness change of BOL and EOL batteries after overcharge
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | +100 | +40.0 | -11.0 | +3.0 |
EOL | +19 | +40.1 | -46.0 | +2.1 |
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -13 | +2655 | 0 | 0.5 |
EOL | -2919 | +30.4 | 0 | 21.1 |
Table 4 Voltage, resistance, mass and thickness change of BOL and EOL batteries after external short circuit
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -13 | +2655 | 0 | 0.5 |
EOL | -2919 | +30.4 | 0 | 21.1 |
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3350 | +21.4 | -588 | +1.7 |
EOL | -3400 | 无 | -568 | +1.3 |
Table 5 Voltage, resistance, mass and thickness change of BOL and EOL batteries after heating
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3350 | +21.4 | -588 | +1.7 |
EOL | -3400 | 无 | -568 | +1.3 |
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3353 | 945.6 | -572 | +6.5 |
EOL | -3326 | 78.6 | -43.5 | +2.8 |
Table 6 Voltage, resistance, mass and thickness change of BOL and EOL batteries after nail penetration
电池状态 | 电压变化/mV | 内阻变化/% | 质量变化/g | 厚度变化/% |
---|---|---|---|---|
BOL | -3353 | 945.6 | -572 | +6.5 |
EOL | -3326 | 78.6 | -43.5 | +2.8 |
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