CIESC Journal ›› 2023, Vol. 74 ›› Issue (3): 1332-1342.DOI: 10.11949/0438-1157.20221375
• Energy and environmental engineering • Previous Articles Next Articles
Lingxin ZU1(), Rongting HU1(
), Xin LI1, Yudao CHEN1,2, Guanglin CHEN3
Received:
2022-10-18
Revised:
2022-12-23
Online:
2023-04-19
Published:
2023-03-05
Contact:
Rongting HU
祖凌鑫1(), 胡荣庭1(
), 李鑫1, 陈余道1,2, 陈广林3
通讯作者:
胡荣庭
作者简介:
祖凌鑫(1998—),男,硕士研究生,864868379@qq.com
基金资助:
CLC Number:
Lingxin ZU, Rongting HU, Xin LI, Yudao CHEN, Guanglin CHEN. Carbon release products and denitrification bioavailability from chemical components of woody biomass[J]. CIESC Journal, 2023, 74(3): 1332-1342.
祖凌鑫, 胡荣庭, 李鑫, 陈余道, 陈广林. 木质生物质化学组分的碳释放产物特征和反硝化利用程度[J]. 化工学报, 2023, 74(3): 1332-1342.
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序号 | 指标 | 方法 | 仪器(厂家和型号) |
---|---|---|---|
1 | 碎木组分 | 范氏洗涤法 | 分析天平(美国,HZK-FA110S) |
2 | 红外光谱特征 | 漫反射法 | 原位红外分析仪(美国,Frontier GMT500A) |
3 | 三维荧光光谱 | 三维荧光光谱分析法 | 三维荧光扫描光谱仪(日本,Aqualog~UV~800) |
4 | DOC | 燃烧氧化法 | 总有机碳分析仪(德国,multi N/C 3100) |
5 | NO | 紫外分光光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
6 | NO | N-(1-萘基)-乙二胺光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
7 | NH | 纳氏试剂光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
Table 1 Determination methods of indexes and instruments during experiments
序号 | 指标 | 方法 | 仪器(厂家和型号) |
---|---|---|---|
1 | 碎木组分 | 范氏洗涤法 | 分析天平(美国,HZK-FA110S) |
2 | 红外光谱特征 | 漫反射法 | 原位红外分析仪(美国,Frontier GMT500A) |
3 | 三维荧光光谱 | 三维荧光光谱分析法 | 三维荧光扫描光谱仪(日本,Aqualog~UV~800) |
4 | DOC | 燃烧氧化法 | 总有机碳分析仪(德国,multi N/C 3100) |
5 | NO | 紫外分光光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
6 | NO | N-(1-萘基)-乙二胺光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
7 | NH | 纳氏试剂光度法 | 紫外-可见光谱分光光度计(中国,UV-2355) |
碎木,碳释放时间 | 组分/% | ||||
---|---|---|---|---|---|
中性 溶解物 | 半纤维素 | 纤维素 | 木质素 | 灰分 | |
NW,0 d | 11.5 | 11.6 | 45.2 | 31.2 | 0.5 |
RL,0 d | 13.1 | 8.1 | 77.8 | 1.0 | 0.3 |
AF,0 d | 9.2 | 2.3 | 88.2 | 0.1 | 0.1 |
NW,58 d | 11.3 | 8.3 | 49.6 | 30.9 | 0.1 |
RL,58 d | 10.2 | 7.7 | 82.0 | 0.2 | 0.1 |
AF,58 d | 6.6 | 3.0 | 90.3 | 0.1 | 0.1 |
Table 2 Separating solid components and chemical components after carbon release for woody biomass
碎木,碳释放时间 | 组分/% | ||||
---|---|---|---|---|---|
中性 溶解物 | 半纤维素 | 纤维素 | 木质素 | 灰分 | |
NW,0 d | 11.5 | 11.6 | 45.2 | 31.2 | 0.5 |
RL,0 d | 13.1 | 8.1 | 77.8 | 1.0 | 0.3 |
AF,0 d | 9.2 | 2.3 | 88.2 | 0.1 | 0.1 |
NW,58 d | 11.3 | 8.3 | 49.6 | 30.9 | 0.1 |
RL,58 d | 10.2 | 7.7 | 82.0 | 0.2 | 0.1 |
AF,58 d | 6.6 | 3.0 | 90.3 | 0.1 | 0.1 |
碎木 分离组分 | 二级反应动力学方程 | Ritger-Peppas动力学方程 | ||||||
---|---|---|---|---|---|---|---|---|
拟合公式 | R2 | cm | K | t0.5 | 拟合公式 | R2 | n | |
NW | 0.906 | 14.8 | 0.13 | 111.4 | 0.993 | 0.26 | ||
RL | 0.932 | 45.8 | 1.13 | 40.5 | 0.984 | 0.16 | ||
AF | 0.930 | 24.9 | 0.45 | 55.6 | 0.990 | 0.20 |
Table 3 Fitting results of kinetic equation for the carbon release process of chemical compositions in woodchip
碎木 分离组分 | 二级反应动力学方程 | Ritger-Peppas动力学方程 | ||||||
---|---|---|---|---|---|---|---|---|
拟合公式 | R2 | cm | K | t0.5 | 拟合公式 | R2 | n | |
NW | 0.906 | 14.8 | 0.13 | 111.4 | 0.993 | 0.26 | ||
RL | 0.932 | 45.8 | 1.13 | 40.5 | 0.984 | 0.16 | ||
AF | 0.930 | 24.9 | 0.45 | 55.6 | 0.990 | 0.20 |
Fig.6 Three-dimensional fluorescence characteristics for leachates of 0—2 d [(a)—(c)] and 52—58 d [(d)—(f)] carbon release, and after denitrification [(g)—(i)] for the latter leachate
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