CIESC Journal ›› 2023, Vol. 74 ›› Issue (1): 276-289.DOI: 10.11949/0438-1157.20221574
• Reviews and monographs • Previous Articles Next Articles
Hao ZHANG1(), Ziyue WANG1, Yujie CHENG1, Xiaohui HE1,3(), Hongbing JI1,2,3,4()
Received:
2022-12-07
Revised:
2023-01-11
Online:
2023-03-20
Published:
2023-01-05
Contact:
Xiaohui HE, Hongbing JI
张浩1(), 王子悦1, 程钰洁1, 何晓辉1,3(), 纪红兵1,2,3,4()
通讯作者:
何晓辉,纪红兵
作者简介:
张浩(1995—),男,博士研究生,zhangh577@mail2.sysu.edu.cn
基金资助:
CLC Number:
Hao ZHANG, Ziyue WANG, Yujie CHENG, Xiaohui HE, Hongbing JI. Progress in the mass production of single-atom catalysts[J]. CIESC Journal, 2023, 74(1): 276-289.
张浩, 王子悦, 程钰洁, 何晓辉, 纪红兵. 单原子催化剂规模化制备的研究进展[J]. 化工学报, 2023, 74(1): 276-289.
Fig.1 Synthesis diagram of the synthesis of Sn δ+ single-atom catalyst (a); TEM image of Sn δ+ single-atom catalyst (b); AC HAADF-STEM image of Sn δ+ single-atom catalyst (c); FT-EXAFS spectra of Sn δ+ single-atom catalyst (d) [44]
Fig.2 Schematic diagram of the ligand-mediated strategy for the synthesis of single-atom catalysts (a); AC HAADF-STEM images of different Ni single-atom catalysts with 2.5% (b), 3.4% (c), 4.5% (d), and 5.3% (e) Ni loding; Photograph of a large-scale 2.5% metal-loaded Ni single-atom catalyst (f) [47]; Strategy for the preparation of UHD-SACs (g)[47-48]
Fig.3 Schematic diagram of the synthesis of Pd1/ZnO (a); AC HAADF-STEM images of different scales of Pd1/ZnO (b); FT-EXAFS spectra of Pd1/ZnO-10 and Pd1/ZnO-1000 (c); Pictures of different scales of single-atom catalysts (d) [53]
Fig.4 Schematic diagram of the synthesis of Pt1/Co (a); AC HAADF-STEM images of Pt1/Co and Pt1/Co-1000 [(b),(c)]; AC HAADF-STEM images of different scales of single-atom catalysts (d); AC HAADF-STEM images of different types of single-atom catalysts (e) [55-57]
Fig.5 Schematic diagram of the synthesis of kilogram-scale Ru single-atom catalysts (a); STEM image of Ru1/MAFO (b); AC HAADF-STEM images of Ru1/MAFO[ (c), (d)] [59]
Fig.7 Schematic diagram of the experimental setup and formation mechanism of the gas migration strategy (a); AC HAADF-STEM image of Cu1/N-C [(b), (c)]; FT-EXAFS spectra of Cu1/N-C (d) [67]
Fig.8 Schematic diagram for the quasi-continuous synthesis of Fe/SNC (a); Scanning electron microscopy image of microcapsules (b); AC AC HAADF-STEM image of Fe/SNC (c), Co/SNC (d), and Ni/SNC (e) [68]
Fig.9 Experimental plot of the preparation of Pd1/FeO x (a); Single-atom catalyst synthesis production line (b); AC HAADF-STEM image of Pd1/FeO x from different synthesis batches [(c)-(f)]; FT-EXAFS spectra of Pd1/FeO x -1 and Pd1/FeO x -4 (g)[70]
Fig.10 Scheme for the continuous synthesis of Pd1/TiO2 (a); STEM-EDS elemental mapping of a single Pd1/TiO2 nanosheet (b); AC HAADF-STEM image of Pd1/TiO2 (c) [2]
Fig.11 Schematic of the continuous synthesis of catalysts (a); Histogram of particle size distribution of catalysts (b); AC HAADF-STEM image of Rh single-atom catalyst (c)[71]
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