CIESC Journal ›› 2016, Vol. 67 ›› Issue (10): 4203-4210.DOI: 10.11949/j.issn.0438-1157.20160608

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Process of two-stage absorption column to strengthen water scrubbing technology to purify biogas

DING Jian, REN Jiajia, LI Zheng, YANG Zhuhong, LU Xiaohua   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China
  • Received:2016-05-09 Revised:2016-07-20 Online:2016-10-05 Published:2016-10-05
  • Supported by:

    supported by the National Basic Research Program of China (2013CB733503) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

二段式吸收塔强化水洗技术提纯沼气过程

丁键, 任佳佳, 李峥, 杨祝红, 陆小华   

  1. 南京工业大学材料化学国家重点实验室, 江苏 南京 210009
  • 通讯作者: 杨祝红
  • 基金资助:

    国家重点基础研究发展计划项目(2013CB733503);江苏高校优势学科建设工程资助项目。

Abstract:

Pressure water scrubbing technology has become one of the key technologies of biogas purification. This paper adopted a packed absorption column to study on carbon dioxide removal. The influences of absorption pressure, absorption temperature, carbon dioxide content on the product gas and height of packing layer on carbon dioxide removal rate as well as those of liquid/gas ratio and biogas flow on volumetric overall absorption coefficient were investigated. At the same time, the intensive tests used a two-stage absorption column combined with a packed column and a spray column for purification process of pressure water. It was shown from the results that the increased absorption pressure, liquid-gas ratio and height of packing layer and reduced absorption temperature were favorable of removing carbon dioxide. Besides, volumetric overall absorption coefficient rose with increasing liquid/gas ratio and biogas flow. Two-stage absorption column was able to improve the effect of carbon dioxide absorption. When the biogas flow was 10 L·min-1, the height of packing layer 100 cm and carbon dioxide content less than 3%, about 12% of the amount of absorption liquid can be reduced by two-stage absorption column compared with the traditional packed tower. Furthermore, when the two-stage absorption column of 110 cm was used, the optimum purification effect can be obtained and the carbon dioxide removal rate can reach 97.4%.

Key words: biogas, carbon dioxide, pressure water scrubbing, two-stage absorption column, volumetric overall absorption coefficient, biomethane

摘要:

压力水洗技术已成为提纯沼气的关键技术之一。采用填料吸收塔进行CO2脱除实验研究,考察了液气比、吸收压力、吸收温度、CO2初始含量、填料层高度对CO2脱除率的影响,以及液气比、沼气流量对总体积吸收系数的影响,并运用填料塔与喷雾塔结合的二段式吸收塔进行压力水洗提纯沼气的过程强化实验。实验结果表明,吸收压力和液气比的增大、吸收温度的降低、填料层高度的增加有利于CO2的脱除,体积总吸收系数随着液气比及沼气流量的增加而增大。二段式吸收塔能够提高CO2吸收效果,当沼气处理量为10 L·min-1,填料层高度为100 cm,CO2含量小于3%时,与填料塔相比二段式吸收塔可以减少约12%的吸收液用量,并且采用110 cm填料的二段式吸收塔获得最佳的提纯效果,CO2脱除率达到97.4%。

关键词: 沼气, 二氧化碳, 压力水洗, 二段式吸收塔, 体积总吸收系数, 生物甲烷

CLC Number: