CIESC Journal ›› 2022, Vol. 73 ›› Issue (8): 3406-3416.DOI: 10.11949/0438-1157.20220518
• Reviews and monographs • Previous Articles Next Articles
Dan GUO(), Yujie FANG, Yihan XU, Zhiyuan LI, Shouying HUANG(), Shengping WANG, Xinbin MA
Received:
2022-04-11
Revised:
2022-07-09
Online:
2022-09-06
Published:
2022-08-05
Contact:
Shouying HUANG
郭丹(), 方雨洁, 许一寒, 李致远, 黄守莹(), 王胜平, 马新宾
通讯作者:
黄守莹
作者简介:
郭丹(1993—),女,博士研究生,guodan207@tju.edu.cn
基金资助:
CLC Number:
Dan GUO, Yujie FANG, Yihan XU, Zhiyuan LI, Shouying HUANG, Shengping WANG, Xinbin MA. Research progress of the catalytic conversion of ethane and carbon dioxide[J]. CIESC Journal, 2022, 73(8): 3406-3416.
郭丹, 方雨洁, 许一寒, 李致远, 黄守莹, 王胜平, 马新宾. 乙烷和二氧化碳催化转化的研究进展[J]. 化工学报, 2022, 73(8): 3406-3416.
Fig.4 The catalytic performance of DRE on supported single-metal catalyst[17,31] and influence of support acidity and alkalinity on performance of Ni-based catalyst[35]
活性 组分 | 载体 | 负载量(质量分数) | 反应 温度/K | 空速/ (ml/(g∙h)) | 转化率/% | CO选择性/% | 反应时间/10-4s | 文献 | |
---|---|---|---|---|---|---|---|---|---|
CO2 | C2H6 | ||||||||
NiPt | CeO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 53.4 | 22.8 | 92.8 | 3.4~4.2 | [ |
NiPt | TiO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 27.9 | 11.1 | 85.5 | 3.4~4.2 | [ |
NiPt | γ-Al2O3 | 1.51%Ni,1.67%Pt | 873 | 24000 | 26.5 | 9.2 | 93.0 | 3.4~4.2 | [ |
NiPt | SiO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 28.2 | 9.2 | 97.0 | 3.4~4.2 | [ |
PdCo | CeO2 | 1%Pd,9%Co | 923 | 18000 | 31.5 | 31.0 | 82.0 | >1.2 | [ |
PdNi | CeO2 | 1%Pd,1%Ni | 923 | 18000 | 53.0 | 39.8 | 86.0 | >1.2 | [ |
PdCu | CeO2 | 1%Pd,1%Cu | 923 | 18000 | 13.0 | 12.5 | 51.0 | >1.2 | [ |
NiFe | CeO2-C2 (25 nm) | 4.0%Ni,1.6%Fe | 873 | 24000 | 8.0 | 3.9 | 53.0 | 4.3 | [ |
NiFe | CeO2 | 0.48%Ni,1.51%Fe | 873 | 150000 | 41.3 | 16.7 | 98.6 | 4.0~4.7 | [ |
NiFe | SiO2 | 0.5%Ni,1.4%Fe | 873 | 24000 | 0.9 | 0.4 | — | 4.0~4.7 | [ |
NiFe | ZrO2 | 0.5%Ni,1.4%Fe | 873 | 24000 | 5.6 | 2.6 | 37.9 | 4.0~4.7 | [ |
NiFe | CeO2 | 2%Ni,5.6%Fe | 873 | 24000 | 13.1 | 3.5 | 67.7 | 4.0~4.7 | [ |
Table 1 Research progress of typical bimetallic catalysts for DRE
活性 组分 | 载体 | 负载量(质量分数) | 反应 温度/K | 空速/ (ml/(g∙h)) | 转化率/% | CO选择性/% | 反应时间/10-4s | 文献 | |
---|---|---|---|---|---|---|---|---|---|
CO2 | C2H6 | ||||||||
NiPt | CeO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 53.4 | 22.8 | 92.8 | 3.4~4.2 | [ |
NiPt | TiO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 27.9 | 11.1 | 85.5 | 3.4~4.2 | [ |
NiPt | γ-Al2O3 | 1.51%Ni,1.67%Pt | 873 | 24000 | 26.5 | 9.2 | 93.0 | 3.4~4.2 | [ |
NiPt | SiO2 | 1.51%Ni,1.67%Pt | 873 | 24000 | 28.2 | 9.2 | 97.0 | 3.4~4.2 | [ |
PdCo | CeO2 | 1%Pd,9%Co | 923 | 18000 | 31.5 | 31.0 | 82.0 | >1.2 | [ |
PdNi | CeO2 | 1%Pd,1%Ni | 923 | 18000 | 53.0 | 39.8 | 86.0 | >1.2 | [ |
PdCu | CeO2 | 1%Pd,1%Cu | 923 | 18000 | 13.0 | 12.5 | 51.0 | >1.2 | [ |
NiFe | CeO2-C2 (25 nm) | 4.0%Ni,1.6%Fe | 873 | 24000 | 8.0 | 3.9 | 53.0 | 4.3 | [ |
NiFe | CeO2 | 0.48%Ni,1.51%Fe | 873 | 150000 | 41.3 | 16.7 | 98.6 | 4.0~4.7 | [ |
NiFe | SiO2 | 0.5%Ni,1.4%Fe | 873 | 24000 | 0.9 | 0.4 | — | 4.0~4.7 | [ |
NiFe | ZrO2 | 0.5%Ni,1.4%Fe | 873 | 24000 | 5.6 | 2.6 | 37.9 | 4.0~4.7 | [ |
NiFe | CeO2 | 2%Ni,5.6%Fe | 873 | 24000 | 13.1 | 3.5 | 67.7 | 4.0~4.7 | [ |
催化剂 | 反应温度/K | 空速/(ml/(g·h)) | 反应时间/h | 文献 | |||
---|---|---|---|---|---|---|---|
CrO x /Al2O3 | 873 | 48000 | — | 6.9 | 96 | 2 | [ |
CrO x /ZrO2 | 873 | 48000 | — | 10 | 91 | 2 | [ |
CrO x /Ce x Zr1-x O2 | 873 | 48000 | — | 2.8 | 77 | 2 | [ |
Cr/TiO2-ZrO2 | 973 | 9000 | — | 48.5 | 95 | — | [ |
(K-Ca)50/(Cr10/H-ZSM-5)5 | 973 | — | 18 | 17 | 96 | — | [ |
Mo2C | 873 | 24000 | — | 12 | 20 | 2 | [ |
1%(质量) Fe/Mo2C | 873 | 24000 | — | 8 | 71 | 2 | [ |
Table 2 Performance of CO2-ODH catalysts
催化剂 | 反应温度/K | 空速/(ml/(g·h)) | 反应时间/h | 文献 | |||
---|---|---|---|---|---|---|---|
CrO x /Al2O3 | 873 | 48000 | — | 6.9 | 96 | 2 | [ |
CrO x /ZrO2 | 873 | 48000 | — | 10 | 91 | 2 | [ |
CrO x /Ce x Zr1-x O2 | 873 | 48000 | — | 2.8 | 77 | 2 | [ |
Cr/TiO2-ZrO2 | 973 | 9000 | — | 48.5 | 95 | — | [ |
(K-Ca)50/(Cr10/H-ZSM-5)5 | 973 | — | 18 | 17 | 96 | — | [ |
Mo2C | 873 | 24000 | — | 12 | 20 | 2 | [ |
1%(质量) Fe/Mo2C | 873 | 24000 | — | 8 | 71 | 2 | [ |
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