Chin.J.Chem.Eng. ›› 2012, Vol. 20 ›› Issue (4): 641-648.

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles     Next Articles

Removal of Cu (II) from aqueous solution using a novel crosslinked alumina-chitosan hybrid adsorbent

JI Guijuan1; BAO Weiwei1; GAO Guimei1; AN Baichao2; ZOU Haifeng1; GAN Shucai1   

  1. 1 College of Chemistry, Jilin University, Changchun 130026, China 2 College of Engineering and Architecture, Liaoning Technical University, Fuxin 123000, China
  • Received:2011-03-07 Revised:2011-08-20 Online:2011-08-20 Published:2012-08-28

交联氧化铝-壳聚糖新杂化吸附剂的制备及去除废水中Cu(II)

季桂娟1; 包维维1; 高桂梅1; 安佰超2; 邹海峰1; 甘树才1   

  1. 1 College of Chemistry, Jilin University, Changchun 130026, China 2 College of Engineering and Architecture, Liaoning Technical University, Fuxin 123000, China

Abstract: A novel biosorbent was developed by coating chitosan, a naturally and abundantly available biopolymer, on to activated alumina based on oil shale ash via crosslinking. The adsorbent was characterized by various techniques, such as Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and X-ray photoelectron spectroscope. Batch isothermal equilibrium adsorption experiments were condcted to evaluate the adsorbent for the removal of Cu(II) from wastewater. The effect of pH and agitation time on the adsorption capacity was also investigated, indicating that the optimum pH was 6.0. The equilibrium adsorp-tion data were correlated with Langmuir and Freundlich models. The maximum monolayer adsorption capacity of chitosan coated alumina sorbent as obtained from Langmuir adsorption isotherm was found to be 315.46 mg•g?1 for Cu(II). The adsorbent loaded with Cu(II) was readily regenerated using 0.1 mol•L?1 sodium hydroxide solution. All these indicated that chitosan coated alumina adsorbent not only have high adsorption activity, but also had good stability in the wastewater treatment process.

Key words: chitosan, adsorbent, alumina, Cu(II), oil shale ash

摘要: A novel biosorbent was developed by coating chitosan, a naturally and abundantly available biopolymer, on to activated alumina based on oil shale ash via crosslinking. The adsorbent was characterized by various techniques, such as Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and X-ray photoelectron spectroscope. Batch isothermal equilibrium adsorption experiments were condcted to evaluate the adsorbent for the removal of Cu(II) from wastewater. The effect of pH and agitation time on the adsorption capacity was also investigated, indicating that the optimum pH was 6.0. The equilibrium adsorp-tion data were correlated with Langmuir and Freundlich models. The maximum monolayer adsorption capacity of chitosan coated alumina sorbent as obtained from Langmuir adsorption isotherm was found to be 315.46 mg•g?1 for Cu(II). The adsorbent loaded with Cu(II) was readily regenerated using 0.1 mol•L?1 sodium hydroxide solution. All these indicated that chitosan coated alumina adsorbent not only have high adsorption activity, but also had good stability in the wastewater treatment process.

关键词: chitosan, adsorbent, alumina, Cu(II), oil shale ash