Progress in pore size regulation of metal-organic frameworks

doi:10.11949/0438-1157.20190801

Abstract

Abstract:

Metal-organic frameworks (MOFs) have attractecl wide attention due to their flexible pore structure, large porosity and specific surface area. Designing and constructing MOFs with suitable pore size distribution to achieve the desired function is related to the application of MOFs in the fields of separation, catalysis, proton conduction, etc. In this paper, the main methods of regulating MOFs pore size are reviewed, including in-situ synthesis, post-synthesis modification, intercalation regulation and auxiliary synthesis. The characteristics and shortcomings of the four regulation methods are summarized, and the future direction of MOFs pore size regulation is also prospected.

Key words: metal-organic frameworks, pore size, in-situ synthesis, post-synthetic modification, interpenetrating regulation, auxiliary synthesis

摘要：

金属有机框架(MOFs)以其可灵活调节的孔道结构、大孔隙率和大比表面积等特点受到广泛关注。设计并构建能够实现目标功能的、具有合适孔径分布的MOFs材料关系到MOFs材料在分离、催化以及质子传导等领域中的应用。综述了MOFs材料孔径的主要调控方法，包括原位合成调控、后合成修饰调控、穿插调控以及辅助合成调控，总结了四种调控方法的特点和不足，并对未来MOFs孔径调控的发展方向进行了展望。

关键词: 金属有机框架, 孔径, 原位合成, 后合成修饰, 穿插调控, 辅助合成

CLC Number:

TQ 028.8

Ye YUAN, Ming WANG, Yunqi ZHOU, Zhi WANG, Jixiao WANG. Progress in pore size regulation of metal-organic frameworks[J]. CIESC Journal, 2020, 71(2): 429-450.

原野, 王明, 周云琪, 王志, 王纪孝. 金属有机框架孔径调控进展[J]. 化工学报, 2020, 71(2): 429-450.

Figures/Tables 1

References 158

1	崔希利, 邢华斌. 金属有机框架材料分离低碳烃的研究进展[J]. 化工学报, 2018, 69(6): 2339-2352.
	Cui X L, Xing H B. Separation of light hydrocarbons with metal-organic frameworks[J]. CIESC Journal, 2018, 69(6): 2339-2352.
2	Zhao X, Wang Y, Li D S, et al. Metal-organic frameworks for separation[J]. Advanced Materials, 2018, 30(37): 1705189.
3	Li J R, Sculley J, Zhou H C. Metal-organic frameworks for separations[J]. Chemical Reviews, 2012, 112(2): 869-932.
4	Kitagawa S, Matsuda R. Chemistry of coordination space of porous coordination polymers[J]. Coordination Chemistry Reviews, 2007, 251(21): 2490-2509.
5	Xue D X, Wang Q, Bai J F. Amide-functionalized metal-organic frameworks: syntheses, structures and improved gas storage and separation properties[J]. Coordination Chemistry Reviews, 2019, 378: 2-16.
6	Yu G L, Zou X Q, Sun L, et al. Constructing connected paths between UiO-66 and PIM-1 to improve membrane CO₂ separation with crystal-like gas selectivity[J]. Advanced Materials, 2019, 31(15): 1806853.
7	Jiao Y, Hong W Z, Li P Y, et al. Metal-organic framework derived Ni/NiO micro-particles with subtle lattice distortions for high-performance electrocatalyst and supercapacitor[J]. Applied Catalysis B-Environmental, 2019, 244: 732-739.
8	Xu C P, Fang R Q, Luque R, et al. Functional metal-organic frameworks for catalytic applications[J]. Coordination Chemistry Reviews, 2019, 388: 268-292.
9	Jurcic M, Peveler W J, Savory C N, et al. Sensing and discrimination of explosives at variable concentrations with a large-pore MOF as part of a luminescent array[J]. ACS Applied Materials & Interfaces, 2019, 11(12): 11618-11626.
10	Yang N N, Zhou L J, Li P, et al. Space-confined indicator displacement assay inside a metal-organic framework for fluorescence turn-on sensing[J]. Chemical Science, 2019, 10(11): 3307-3314.
11	Joarder B, Lin J B, Romero Z, et al. Single crystal proton conduction study of a metal organic framework of modest water stability[J]. Journal of the American Chemical Society, 2017, 139(21): 7176-7179.
12	Zhang F M, Dong L Z, Qin J S, et al. Effect of imidazole arrangements on proton-conductivity in metal-organic frameworks[J]. Journal of the American Chemical Society, 2017, 139(17): 6183-6189.
13	Liang Z B, Qu C, Guo W H, et al. Pristine metal-organic frameworks and their composites for energy storage and conversion[J]. Advanced Materials, 2018, 30(37): 1702891
14	Liu J L, Zhu D D, Guo C X, et al. Design strategies toward advanced MOF-derived electrocatalysts for energy-conversion reactions[J]. Advanced Energy Materials, 2017, 7(23): 1700518
15	He S, Chen Y, Zhang Z, et al. Competitive coordination strategy for the synthesis of hierarchical-pore metal-organic framework nanostructures[J]. Chemical Science, 2016, 7(12): 7101-7105.
16	Bradshaw D, El-Hankari S, Lupica-Spagnolo L. Supramolecular templating of hierarchically porous metal-organic frameworks[J]. Chemical Society Reviews, 2014, 43(16): 5431-5443.
17	Hu M L, Masoomi M Y, Morsali A. Template strategies with MOFs[J]. Coordination Chemistry Reviews, 2019, 387: 415-435.
18	Huang H, Li J R, Wang K, et al. An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks[J]. Nature Communications, 2015, 6: 8847.
19	Xuan W, Zhu C, Liu Y, et al. Mesoporous metal-organic framework materials[J]. Chemical Society Reviews, 2012, 41(5): 1677-1695.
20	马子健. 小分子胺和MOFs分别改性聚乙烯基胺制备高性能CO₂分离膜[D]. 天津: 天津大学, 2014.
	Ma Z J. Preparation of high performance CO₂ separation membrane by modifying polyvinylamine with low molecular weight amines or MOFs[D]. Tianjin: Tianjin University, 2014.
21	Qiao Z, Sheng M, Wang J, et al. Metal-induced polymer framework membrane with high performance for CO₂ separation[J]. AIChE Journal, 2019, 65(1): 239-249.
22	Qiao Z, Zhao S, Wang J, et al. A highly permeable aligned montmorillonite mixed-matrix membrane for CO₂ separation[J]. Angewandte Chemie, 2016, 128(32): 9467-9471.
23	Cao X, Wang Z, Qiao Z, et al. Penetrated COF channels: amino environment and suitable size for CO₂ preferential adsorption and transport in mixed matrix membranes[J]. ACS Applied Materials & Interfaces, 2019, 11(5): 5306-5315.
24	Halder A, Ghoshal D. Structure and properties of dynamic metal-organic frameworks: a brief accounts of crystalline-to-crystalline and crystalline-to-amorphous transformations[J]. CrystEngComm, 2018, 20(10): 1322-1345.
25	Graham A J, Allan D R, Muszkiewicz A, et al. The effect of high pressure on MOF-5: guest-induced modification of pore size and content at high pressure[J]. Angewandte Chemie-International Edition, 2011, 50(47): 11138-11141.
26	Teplensky M H, Fantham M, Li P, et al. Temperature treatment of highly porous zirconium-containing metal-organic frameworks extends drug delivery release[J]. Journal of the American Chemical Society, 2017, 139(22): 7522-7532.
27	Li H, Hill M R. Low-energy CO₂ release from metal-organic frameworks triggered by external stimuli[J]. Accounts of Chemical Research, 2017, 50(4): 778-786.
28	Fernandez C A, Martin P C, Schaef T, et al. An electrically switchable metal-organic framework[J]. Scientific Reports, 2014, 4: 6114.
29	Fu J, Li H, Mu Y, et al. Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu²⁺⋯I^- interactions and modification of the structures and properties of MOFs[J]. Chemical Communications, 2011, 47(18): 5271-5273.
30	Garai B, Mallick A, Banerjee R. Photochromic metal-organic frameworks for inkless and erasable printing[J]. Chemical Science, 2016, 7(3): 2195-2200.
31	Mehlana G, Bourne S A. Unravelling chromism in metal-organic frameworks[J]. CrystEngComm, 2017, 19(30): 4238-4259.
32	Khan N A, Hasan Z, Jhung S H. Beyond pristine metal-organic frameworks: preparation and application of nanostructured, nanosized, and analogous MOFs[J]. Coordination Chemistry Reviews, 2018, 376: 20-45.
33	Yaghi O M, O'keeffe M, Ockwig N W, et al. Reticular synthesis and the design of new materials[J]. Nature, 2003, 423(6941): 705-714.
34	Guillerm V, Grancha T, Imaz I, et al. Zigzag ligands for transversal design in reticular chemistry: unveiling new structural opportunities for metal-organic frameworks[J]. Journal of the American Chemical Society, 2018, 140(32): 10153-10157.
35	Haque E, Jeong J H, Jhung S H. Synthesis of isostructural porous metal-benzenedicarboxylates: effect of metal ions on the kinetics of synthesis[J]. CrystEngComm, 2010, 12(10): 2749-2754.
36	Cavka J H, Jakobsen S, Olsbye U, et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J]. Journal of the American Chemical Society, 2008, 130(42): 13850-13851.
37	Kang I J, Khan N A, Haque E, et al. Chemical and thermal stability of isotypic metal-organic frameworks: effect of metal ions[J]. Chemistry - A European Journal, 2011, 17(23): 6437-6442.
38	Leus K, Bogaerts T, De Decker J, et al. Systematic study of the chemical and hydrothermal stability of selected “stable” Metal Organic Frameworks[J]. Microporous and Mesoporous Materials, 2016, 226: 110-116.
39	Gomes S C, Luz I, Llabrés I X F X, et al. Water stable Zr-benzenedicarboxylate metal-organic frameworks as photocatalysts for hydrogen generation[J]. Chemistry - A European Journal, 2010, 16(36): 11133-11138.
40	Chen Z, Hanna S L, Redfern L R, et al. Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs[J]. Coordination Chemistry Reviews, 2019, 386: 32-49.
41	Furukawa H, Gándara F, Zhang Y B, et al. Water adsorption in porous metal-organic frameworks and related materials[J]. Journal of the American Chemical Society, 2014, 136(11): 4369-4381.
42	Yuan S, Lu W, Chen Y P, et al. Sequential linker installation: precise placement of functional groups in multivariate metal-organic frameworks[J]. Journal of the American Chemical Society, 2015, 137(9): 3177-3180.
43	Feng D, Gu Z Y, Li J R, et al. Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts[J]. Angewandte Chemie-International Edition, 2012, 51(41): 10307-10310.
44	Morris W, Volosskiy B, Demir S, et al. Synthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks[J]. Inorganic Chemistry, 2012, 51(12): 6443-6445.
45	Shearer G C, Forselv S, Chavan S, et al. In situ infrared spectroscopic and gravimetric characterisation of the solvent removal and dehydroxylation of the metal-organic frameworks UiO-66 and UiO-67[J]. Topics in Catalysis, 2013, 56(9): 770-782.
46	Zhang M, Chen Y P, Bosch M, et al. Symmetry-guided synthesis of highly porous metal-organic frameworks with fluorite topology[J]. Angewandte Chemie-International Edition, 2014, 53(3): 815-818.
47	Nguyen P T K, Nguyen H T D, Nguyen H N, et al. New metal-organic frameworks for chemical fixation of CO₂[J]. ACS Applied Materials & Interfaces, 2018, 10(1): 733-744.
48	Alezi D, Spanopoulos I, Tsangarakis C, et al. Reticular chemistry at its best: directed assembly of hexagonal building units into the awaited metal-organic framework with the intricate polybenzene topology, pbz-MOF[J]. Journal of the American Chemical Society, 2016, 138(39): 12767-12770.
49	Zhang Y, Zhang X, Lyu J, et al. A flexible metal-organic framework with 4-connected Zr₆ nodes[J]. Journal of the American Chemical Society, 2018, 140(36): 11179-11183.
50	Bon V, Senkovskyy V, Senkovska I, et al. Zr(Ⅳ) and Hf(Ⅳ) based metal-organic frameworks with reo-topology[J]. Chemical Communications, 2012, 48(67): 8407-8409.
51	Deria P, Gómez-Gualdrón D A, Hod I, et al. Framework-topology-dependent catalytic activity of zirconium-based (porphinato)zinc(II) MOFs[J]. Journal of the American Chemical Society, 2016, 138(43): 14449-14457.
52	Kung C W, Wang T C, Mondloch J E, et al. metal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism[J]. Chemistry of Materials, 2013, 25(24): 5012-5017.
53	Feng D, Chung W C, Wei Z, et al. Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination[J]. Journal of the American Chemical Society, 2013, 135(45): 17105-17110.
54	Feng D, Gu Z Y, Chen Y P, et al. A highly stable porphyrinic zirconium metal-organic framework with shp-a topology[J]. Journal of the American Chemical Society, 2014, 136(51): 17714-17717.
55	Feng D, Wang K, Su J, et al. A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores[J]. Angewandte Chemie-International Edition, 2015, 54(1): 149-154.
56	Jiang H L, Feng D, Wang K, et al. An exceptionally stable, porphyrinic Zr metal-organic framework exhibiting pH-dependent fluorescence[J]. Journal of the American Chemical Society, 2013, 135(37): 13934-13938.
57	Wang B, Lyu X L, Feng D, et al. Highly stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water[J]. Journal of the American Chemical Society, 2016, 138(19): 6204-6216.
58	Liu T F, Vermeulen N A, Howarth A J, et al. Adding to the arsenal of zirconium-based metal-organic frameworks: the topology as a platform for solvent-assisted metal incorporation[J]. European Journal of Inorganic Chemistry, 2016, 2016(27): 4349-4352.
59	Férey G. Hybrid porous solids: past, present, future[J]. Chemical Society Reviews, 2008, 37(1): 191-214.
60	Rosi N L, Kim J, Eddaoudi M, et al. Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units[J]. Journal of the American Chemical Society, 2005, 127(5): 1504-1518.
61	Xin Z, Bai J, Shen Y, et al. Hierarchically micro- and mesoporous coordination polymer nanostructures with high adsorption performance[J]. Crystal Growth & Design, 2010, 10(6): 2451-2454.
62	Rezaee S, Shahrokhian S. Facile synthesis of petal-like NiCo/NiO-CoO/nanoporous carbon composite based on mixed-metallic MOFs and their application for electrocatalytic oxidation of methanol[J]. Applied Catalysis B: Environmental, 2019, 244: 802-813.
63	Loiseau T, Serre C, Huguenard C, et al. A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration[J]. Chemistry - A European Journal, 2004, 10(6): 1373-1382.
64	Alaerts L, Maes M, Giebeler L, et al. Selective adsorption and separation of ortho-substituted alkylaromatics with the microporous aluminum terephthalate MIL-53[J]. Journal of the American Chemical Society, 2008, 130(43): 14170-14178.
65	Barthelet K, Marrot J, Riou D, et al. A breathing hybrid organic-inorganic solid with very large pores and high magnetic characteristics[J]. Angewandte Chemie, 2002, 114(2): 291-294.
66	Horcajada P, Chalati T, Serre C, et al. Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging[J]. Nature Materials, 2009, 9: 172-178.
67	Dan-Hardi M, Serre C, Frot T, et al. A new photoactive crystalline highly porous titanium(Ⅳ) dicarboxylate[J]. Journal of the American Chemical Society, 2009, 131(31): 10857-10859.
68	Liu D, Zou D, Zhu H, et al. Mesoporous metal-organic frameworks: synthetic strategies and emerging applications[J]. Small, 2018, 14(37): 1801454.
69	Low J J, Benin A I, Jakubczak P, et al. Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration[J]. Journal of the American Chemical Society, 2009, 131(43): 15834-15842.
70	Banerjee R, Furukawa H, Britt D, et al. Control of pore size and functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective capture properties[J]. Journal of the American Chemical Society, 2009, 131(11): 3875-3877.
71	Phan A, Doonan C J, Uribe-Romo F J, et al. Synthesis, structure, and carbon dioxide capture properties of zeolitic imidazolate frameworks[J]. Accounts of Chemical Research, 2010, 43(1): 58-67.
72	Kaneti Y V, Dutta S, Hossain M S A, et al. Strategies for improving the functionality of zeolitic imidazolate frameworks: tailoring nanoarchitectures for functional applications[J]. Advanced Materials, 2017, 29(38): 1700213.
73	Noh K, Lee J, Kim J. Compositions and structures of zeolitic imidazolate frameworks[J]. Israel Journal of Chemistry, 2018, 58(9/10): 1075-1088.
74	Cohen S M. Postsynthetic methods for the functionalization of metal-organic frameworks[J]. Chemical Reviews, 2012, 112(2): 970-1000.
75	Yin Z, Wan S, Yang J, et al. Recent advances in post-synthetic modification of metal-organic frameworks: new types and tandem reactions[J]. Coordination Chemistry Reviews, 2019, 378: 500-512.
76	Li P Z, Wang X J, Zhao Y. Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks[J]. Coordination Chemistry Reviews, 2019, 380: 484-518.
77	Deria P, Mondloch J E, Karagiaridi O, et al. Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement[J]. Chemical Society Reviews, 2014, 43(16): 5896-5912.
78	Burrows A D, Frost C G, Mahon M F, et al. Post-synthetic modification of tagged metal-organic frameworks[J]. Angewandte Chemie-International Edition, 2008, 47(44): 8482-8486.
79	Wang Z, Tanabe K K, Cohen S M. Accessing postsynthetic modification in a series of metal-organic frameworks and the influence of framework topology on reactivity[J]. Inorganic Chemistry, 2009, 48(1): 296-306.
80	Wang Z, Cohen S M. Tandem Modification of metal-organic frameworks by a postsynthetic approach[J]. Angewandte Chemie-International Edition, 2008, 47(25): 4699-4702.
81	Xu R, Wang Z, Wang M, et al. High nanoparticles loadings mixed matrix membranes via chemical bridging-crosslinking for CO₂ separation[J]. Journal of Membrane Science, 2019, 573: 455-464.
82	Morris W, Doonan C J, Furukawa H, et al. Crystals as molecules: postsynthesis covalent functionalization of zeolitic imidazolate frameworks[J]. Journal of the American Chemical Society, 2008, 130(38): 12626-12627.
83	Kolb H C, Finn M G, Sharpless K B. Click chemistry: diverse chemical function from a few good reactions[J]. Angewandte Chemie-International Edition, 2001, 40(11): 2004-2021.
84	Gadzikwa T, Lu G, Stern C L, et al. Covalent surface modification of a metal-organic framework: selective surface engineering via CuI-catalyzed huisgen cycloaddition[J]. Chemical Communications, 2008, (43): 5493-5495.
85	Li B, Gui B, Hu G, et al. Postsynthetic modification of an alkyne-tagged zirconium metal-organic framework via a “click” reaction[J]. Inorganic Chemistry, 2015, 54(11): 5139-5141.
86	Zhang Y, Gui B, Chen R, et al. Engineering a zirconium MOF through tandem “click” reactions: a general strategy for quantitative loading of bifunctional groups on the pore surface[J]. Inorganic Chemistry, 2018, 57(4): 2288-2295.
87	Chui S S Y, Lo S M F, Charmant J P H, et al. A chemically functionalizable nanoporous material [Cu₃(TMA)₂(H₂O)₃]_n[J]. Science, 1999, 283(5405): 1148-1150.
88	Hwang Y K, Hong D Y, Chang J S, et al. Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation[J]. Angewandte Chemie-International Edition, 2008, 47(22): 4144-4148.
89	Banerjee M, Das S, Yoon M, et al. Postsynthetic modification switches an achiral framework to catalytically active homochiral metal-organic porous materials[J]. Journal of the American Chemical Society, 2009, 131(22): 7524-7525.
90	Park H J, Cheon Y E, Suh M P. Post-synthetic reversible incorporation of organic linkers into porous metal-organic frameworks through single-crystal-to-single-crystal transformations and modification of gas-sorption properties[J]. Chemistry - A European Journal, 2010, 16(38): 11662-11669.
91	Prasad T K, Hong D H, Suh M P. High gas sorption and metal-ion exchange of microporous metal-organic frameworks with incorporated imide groups[J]. Chemistry - A European Journal, 2010, 16(47): 14043-14050.
92	Tu B, Pang Q, Wu D, et al. Ordered vacancies and their chemistry in metal-organic frameworks[J]. Journal of the American Chemical Society, 2014, 136(41): 14465-14471.
93	Wu C D, Hu A, Zhang L, et al. A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis[J]. Journal of the American Chemical Society, 2005, 127(25): 8940-8941.
94	Wu C D, Lin W. Heterogeneous asymmetric catalysis with homochiral metal-organic frameworks: network-structure-dependent catalytic activity[J]. Angewandte Chemie-International Edition, 2007, 46(7): 1075-1078.
95	Ma L, Falkowski J M, Abney C, et al. A series of isoreticular chiral metal-organic frameworks as a tunable platform for asymmetric catalysis[J]. Nature Chemistry, 2010, 2: 838-846.
96	Bloch E D, Britt D, Lee C, et al. Metal insertion in a microporous metal-organic framework lined with 2,2’-bipyridine[J]. Journal of the American Chemical Society, 2010, 132(41): 14382-14384.
97	Lau C H, Babarao R, Hill M R. A route to drastic increase of CO₂ uptake in Zr metal organic framework UiO-66[J]. Chemical Communications, 2013, 49(35): 3634-3636.
98	Burnett B J, Barron P M, Hu C, et al. Stepwise synthesis of metal-organic frameworks: replacement of structural organic linkers[J]. Journal of the American Chemical Society, 2011, 133(26): 9984-9987.
99	Karagiaridi O, Lalonde M B, Bury W, et al. Opening ZIF-8: a catalytically active zeolitic imidazolate framework of sodalite topology with unsubstituted linkers[J]. Journal of the American Chemical Society, 2012, 134(45): 18790-18796.
100	Karagiaridi O, Bury W, Tylianakis E, et al. Opening metal-organic frameworks（2）: Inserting longer pillars into pillared-paddlewheel structures through solvent-assisted linker exchange[J]. Chemistry of Materials, 2013, 25(17): 3499-3503.
101	Li T, Kozlowski M T, Doud E A, et al. Stepwise ligand exchange for the preparation of a family of mesoporous MOFs[J]. Journal of the American Chemical Society, 2013, 135(32): 11688-11691.
102	Yamada T, Kitagawa H. Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks[J]. Journal of the American Chemical Society, 2009, 131(18): 6312-6313.
103	Deshpande R K, Minnaar J L, Telfer S G. Thermolabile groups in metal-organic frameworks: suppression of network interpenetration, post-synthetic cavity expansion, and protection of reactive functional groups[J]. Angewandte Chemie-International Edition, 2010, 49(27): 4598-4602.
104	Lun D J, Waterhouse G I N, Telfer S G. A general thermolabile protecting group strategy for organocatalytic metal-organic frameworks[J]. Journal of the American Chemical Society, 2011, 133(15): 5806-5809.
105	依秀春. 功能化羧酸金属有机骨架的构筑、后合成修饰及性质研究[D]. 上海: 华东师范大学, 2014.
	Yi X C. Syntheses, post-synthetic modification and properties of metal-organic frameworks with functionalized carboxylates[D]. Shanghai: East China Normal University, 2014.
106	Farha O K, Mulfort K L, Hupp J T. An example of node-based postassembly elaboration of a hydrogen-sorbing, metal-organic framework material[J]. Inorganic Chemistry, 2008, 47(22): 10223-10225.
107	Garibay S J, Cohen S M. Isoreticular synthesis and modification of frameworks with the UiO-66 topology[J]. Chemical Communications, 2010, 46(41): 7700-7702.
108	Zheng S T, Bu J T, Li Y, et al. Pore space partition and charge separation in cage-within-cage indium-organic frameworks with high CO₂ uptake[J]. Journal of the American Chemical Society, 2010, 132(48): 17062-17064.
109	Ma S, Wang X S, Yuan D, et al. A coordinatively linked Yb metal-organic framework demonstrates high thermal stability and uncommon gas-adsorption selectivity[J]. Angewandte Chemie-International Edition, 2008, 47(22): 4130-4133.
110	Kim H, Das S, Kim M G, et al. Synthesis of phase-pure interpenetrated MOF-5 and its gas sorption properties[J]. Inorganic Chemistry, 2011, 50(8): 3691-3696.
111	Schnobrich J K, Koh K, Sura K N, et al. A framework for predicting surface areas in microporous coordination polymers[J]. Langmuir, 2010, 26(8): 5808-5814.
112	Lin X, Telepeni I, Blake A J, et al. High capacity hydrogen adsorption in Cu(II) tetracarboxylate framework materials: the role of pore size, ligand functionalization, and exposed metal sites[J]. Journal of the American Chemical Society, 2009, 131(6): 2159-2171.
113	Park Y K, Choi S B, Kim H, et al. Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter[J]. Angewandte Chemie-International Edition, 2007, 46(43): 8230-8233.
114	Reineke T M, Eddaoudi M, Moler D, et al. Large free volume in maximally interpenetrating networks: The role of secondary building units exemplified by Tb₂(ADB)₃[(CH₃)₂SO]₄·16[(CH₃)₂SO][J]. Journal of the American Chemical Society, 2000, 122(19): 4843-4844.
115	Yao Q, Su J, Cheung O, et al. Interpenetrated metal-organic frameworks and their uptake of CO₂ at relatively low pressures[J]. Journal of Materials Chemistry, 2012, 22(20): 10345.
116	Cui X, Chen K, Xing H, et al. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene[J]. Science, 2016, 353(6295): 141-144.
117	Yang L, Cui X, Zhang Z, et al. An asymmetric anion-pillared metal-organic frameworks as a multisite adsorbent enables simultaneous removal of propyne and propadiene from propylene[J]. Angewandte Chemie-International Edition, 2018, 57(40): 13145-13149.
118	Abbasi A, Soleimani M, Najafi M, et al. New interpenetrated mixed (Co/Ni) metal-organic framework for dye removal under mild conditions[J]. Inorganica Chimica Acta, 2016, 439: 18-23.
119	Sezginel K B, Asinger P A, Babaei H, et al. Thermal transport in interpenetrated metal-organic frameworks[J]. Chemistry of Materials, 2018, 30(7): 2281-2286.
120	Orefuwa S, Iriowen E, Yang H, et al. Effects of nitro-functionalization on the gas adsorption properties of isoreticular metal-organic framework-eight (IRMOF-8)[J]. Microporous and Mesoporous Materials, 2013, 177: 82-90.
121	Souto M, Santiago-Portillo A, Palomino M, et al. A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst[J]. Chemical Science, 2018, 9(9): 2413-2418.
122	Vicent-Morales M, Vitórica-Yrezábal I J, Souto M, et al. Influence of interpenetration on the flexibility of MUV-2[J]. CrystEngComm, 2019, 21(19): 3031-3035.
123	Xin Q, Ouyang J, Liu T, et al. Enhanced interfacial interaction and CO₂ separation performance of mixed matrix membrane by incorporating polyethylenimine-decorated metal-organic frameworks[J]. ACS Applied Materials & Interfaces, 2015, 7(2): 1065-1077.
124	Maji T K, Matsuda R, Kitagawa S. A flexible interpenetrating coordination framework with a bimodal porous functionality[J]. Nature Materials, 2007, 6(2): 142-148.
125	Zhu R, Ding J, Jin L, et al. Interpenetrated structures appeared in supramolecular cages, MOFs, COFs[J]. Coordination Chemistry Reviews, 2019, 389: 119-140.
126	Bae T H, Lee J S, Qiu W, et al. A high-performance gas-separation membrane containing submicrometer-sized metal-organic framework crystals[J]. Angewandte Chemie-International Edition, 2010, 49(51): 9863-9866.
127	Hossain M I, Udoh A, Grabicka B E, et al. Membrane-coated UiO-66 MOF adsorbents[J]. Industrial & Engineering Chemistry Research, 2019, 58(3): 1352-1362.
128	Lee Y R, Cho S M, Ahn W S. Effects of polydimethylsiloxane coating of Ni-MOF-74 on CH₄ storage[J]. Korean Journal of Chemical Engineering, 2018, 35(7): 1542-1546.
129	Vahed T A, Naimi-Jamal M R, Panahi L. Alginate-coated ZIF-8 metal-organic framework as a green and bioactive platform for controlled drug release[J]. Journal of Drug Delivery Science and Technology, 2019, 49: 570-576.
130	Masoomi M Y, Morsali A. Morphological study and potential applications of nano metal-organic coordination polymers[J]. RSC Advances, 2013, 3(42): 19191-19218.
131	Dissegna S, Epp K, Heinz W R, et al. Defective metal-organic frameworks[J]. Advanced Materials, 2018, 30(37): 1704501.
132	Shearer G C, Chavan S, Bordiga S, et al. Defect engineering: tuning the porosity and composition of the metal-organic framework UiO-66 via modulated synthesis[J]. Chemistry of Materials, 2016, 28(11): 3749-3761.
133	Wu H, Chua Y S, Krungleviciute V, et al. Unusual and highly tunable missing-linker defects in zirconium metal-organic framework UiO-66 and their important effects on gas adsorption[J]. Journal of the American Chemical Society, 2013, 135(28): 10525-10532.
134	Cai G, Jiang H L. A modulator-induced defect-formation strategy to hierarchically porous metal-organic frameworks with high stability[J]. Angewandte Chemie-International Edition, 2017, 56(2): 563-567.
135	Vermoortele F, Bueken B, Le Bars G, et al. Synthesis modulation as a tool to increase the catalytic activity of metal-organic frameworks: The unique case of UiO-66(Zr)[J]. Journal of the American Chemical Society, 2013, 135(31): 11465-11468.
136	Kozachuk O, Luz I, Llabrés I Xamena F X, et al. Multifunctional, defect-engineered metal-organic frameworks with ruthenium centers: sorption and catalytic properties[J]. Angewandte Chemie-International Edition, 2014, 53(27): 7058-7062.
137	郝向荣. MOF材料的动态框架、模板效应、孔径调节及应用[M]. 长春: 吉林大学出版社, 2013.
	Hao X R. The Dynamic Framework, Template Effect, Pore Size Control and Application in MOF Materials[M]. Changchun: Jilin University Press, 2013.
138	Tanaka D, Kitagawa S. Template effects in porous coordination polymers[J]. Chemistry of Materials, 2008, 20(3): 922-931.
139	Qiu L G, Xu T, Li Z Q, et al. Hierarchically micro- and mesoporous metal-organic frameworks with tunable porosity[J]. Angewandte Chemie-International Edition, 2008, 47(49): 9487-9491.
140	Choi K M, Jeon H J, Kang J K, et al. Heterogeneity within order in crystals of a porous metal-organic framework[J]. Journal of the American Chemical Society, 2011, 133(31): 11920-11923.
141	Peng L, Zhang J, Li J, et al. Surfactant-directed assembly of mesoporous metal-organic framework nanoplates in ionic liquids[J]. Chemical Communications, 2012, 48(69): 8688-8690.
142	Pham M H, Vuong G T, Fontaine F G, et al. A route to bimodal micro-mesoporous metal-organic frameworks nanocrystals[J]. Crystal Growth & Design, 2012, 12(2): 1008-1013.
143	Abedi S, Morsali A. Ordered mesoporous metal-organic frameworks incorporated with amorphous TiO₂ as photocatalyst for selective aerobic oxidation in sunlight irradiation[J]. ACS Catalysis, 2014, 4(5): 1398-1403.
144	Zhan G, Zeng H C. Alternative synthetic approaches for metal-organic frameworks: transformation from solid matters[J]. Chemical Communications, 2017, 53(1): 72-81.
145	Zhan G, Zeng H C. An alternative synthetic approach for macro-meso-microporous metal-organic frameworks via a “domain growth” mechanism[J]. Chemical Communications, 2016, 52(54): 8432-8435.
146	Sun S, Yang Z. Cu₂O-templated strategy for synthesis of definable hollow architectures[J]. Chemical Communications, 2014, 50(56): 7403-7415.
147	Lei Y, Yang S, Wu M, et al. Surface patterning using templates: concept, properties and device applications[J]. Chemical Society Reviews, 2011, 40(3): 1247-1258.
148	Li L, Zhai T, Zeng H, et al. Polystyrene sphere-assisted one-dimensional nanostructure arrays: synthesis and applications[J]. Journal of Materials Chemistry, 2011, 21(1): 40-56.
149	Shen K, Zhang L, Chen X, et al. Ordered macro-microporous metal-organic framework single crystals[J]. Science, 2018, 359(6372): 206-210.
150	Guo C, Zhang Y, Guo Y, et al. A general and efficient approach for tuning the crystal morphology of classical MOFs[J]. Chemical Communications, 2018, 54(3): 252-255.
151	Schaate A, Roy P, Godt A, et al. Modulated synthesis of Zr-based metal-organic frameworks:from nano to single crystals[J]. Chemistry-A European Journal, 2011, 17(24): 6643-6651.
152	Khan N A, Jhung S H. Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: rapid reaction, phase-selectivity, and size reduction[J]. Coordination Chemistry Reviews, 2015, 285: 11-23.
153	Jhung S H, Lee J H, Yoon J W, et al. Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability[J]. Advanced Materials, 2007, 19(1): 121-124.
154	Tari N E, Tadjarodi A, Tamnanloo J, et al. Facile and fast, one pot microwave synthesis of metal organic framework copper terephthalate and study CO₂ and CH₄ adsorption on it[J]. Journal of Porous Materials, 2015, 22(5): 1161-1169.
155	Chen C, Feng X, Zhu Q, et al. Microwave-assisted rapid synthesis of well-shaped MOF-74 (Ni) for CO₂ efficient capture[J]. Inorganic Chemistry, 2019, 58(4): 2717-2728.
156	Qiao Z, Zhao S, Sheng M, et al. Metal-induced ordered microporous polymers for fabricating large-area gas separation membranes[J]. Nature Materials, 2019, 18(2): 163-168.
157	Qiao Z H, Sheng M L, Wang J X, et al. Metal-induced polymer framework membrane with high performance for CO₂ separation[J]. AIChE Journal, 2019, 65(1): 239-249.
158	Zhang W, Zheng B, Shi W, et al. Site-selective catalysis of a multifunctional linear molecule: the steric hindrance of metal-organic framework channels[J]. Advanced Materials, 2018, 30(23): 1800643.

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