CIESC Journal ›› 2022, Vol. 73 ›› Issue (4): 1781-1793.DOI: 10.11949/0438-1157.20211846
• Material science and engineering, nanotechnology • Previous Articles Next Articles
Shanshan YANG1,2(),Yuyang YAO1,Yundi DONG1,Zhipeng XU1,Shangshang GAO1,Huimin RUAN1,Jiangnan SHEN1()
Received:
2021-12-30
Revised:
2022-02-10
Online:
2022-04-25
Published:
2022-04-05
Contact:
Jiangnan SHEN
杨珊珊1,2(),姚宇洋1,董云迪1,徐志鹏1,高尚上1,阮慧敏1,沈江南1()
通讯作者:
沈江南
作者简介:
杨珊珊(1990—),女,博士,基金资助:
CLC Number:
Shanshan YANG, Yuyang YAO, Yundi DONG, Zhipeng XU, Shangshang GAO, Huimin RUAN, Jiangnan SHEN. Preparation and performance of ion exchange membrane with K+ selectivity based on dibenzo-18-crown-6 modification[J]. CIESC Journal, 2022, 73(4): 1781-1793.
杨珊珊, 姚宇洋, 董云迪, 徐志鹏, 高尚上, 阮慧敏, 沈江南. 基于二苯并-18-冠-6基体改性的K+选择性离子交换膜的制备及性能研究[J]. 化工学报, 2022, 73(4): 1781-1793.
膜名称 | 厚度/μm | 爆破强度/MPa | 面电阻/ (Ω·cm2) | 迁移数/% |
---|---|---|---|---|
AMX | 140 | ≥ 0.25 | 1.8 | 98 |
CIMS | 150 | ≥ 0.10 | 2.4 | > 96 |
Table 1 Commercial membranes used in measurement and their characteristic properties
膜名称 | 厚度/μm | 爆破强度/MPa | 面电阻/ (Ω·cm2) | 迁移数/% |
---|---|---|---|---|
AMX | 140 | ≥ 0.25 | 1.8 | 98 |
CIMS | 150 | ≥ 0.10 | 2.4 | > 96 |
膜种类 | C 1s窄谱中可能存在的化学基团的含量/% | ||
---|---|---|---|
C—C/C—H (284.6 eV) | C—O/C—N (286.2 eV) | OC—O (288.2 eV) | |
M-A18C6-10% | 84.21 | 14.54 | 1.25 |
M-A18C6-5%-T30 | 73.93 | 16.20 | 9.87 |
M-A18C6-10%-T30 | 79.81 | 17.64 | 2.54 |
M-A18C6-20%-T30 | 70.45 | 25.46 | 4.09 |
Table 2 The probable chemical species and content in modified membranes obtained from narrow-spectrum of C 1s
膜种类 | C 1s窄谱中可能存在的化学基团的含量/% | ||
---|---|---|---|
C—C/C—H (284.6 eV) | C—O/C—N (286.2 eV) | OC—O (288.2 eV) | |
M-A18C6-10% | 84.21 | 14.54 | 1.25 |
M-A18C6-5%-T30 | 73.93 | 16.20 | 9.87 |
M-A18C6-10%-T30 | 79.81 | 17.64 | 2.54 |
M-A18C6-20%-T30 | 70.45 | 25.46 | 4.09 |
Fig.13 Cation fluxes of the pristine membrane, modified membranes and commercial monovalent cation exchange membrane CIMS in the ED process for K+/Mg2+ separation
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