CIESC Journal ›› 2023, Vol. 74 ›› Issue (4): 1457-1473.DOI: 10.11949/0438-1157.20221461
• Reviews and monographs • Previous Articles Next Articles
Zijian WANG(), Ming KE(), Jiahan LI, Shuting LI, Jinru SUN, Yanbing TONG, Zhiping ZHAO, Jiaying LIU, Lu REN
Received:
2022-11-08
Revised:
2023-03-22
Online:
2023-06-02
Published:
2023-04-05
Contact:
Ming KE
王子健(), 柯明(), 李佳涵, 李舒婷, 孙巾茹, 童燕兵, 赵治平, 刘加英, 任璐
通讯作者:
柯明
作者简介:
王子健(1995—),男,博士研究生, 757496137@qq.com
基金资助:
CLC Number:
Zijian WANG, Ming KE, Jiahan LI, Shuting LI, Jinru SUN, Yanbing TONG, Zhiping ZHAO, Jiaying LIU, Lu REN. Progress in preparation and application of short b-axis ZSM-5 molecular sieve[J]. CIESC Journal, 2023, 74(4): 1457-1473.
王子健, 柯明, 李佳涵, 李舒婷, 孙巾茹, 童燕兵, 赵治平, 刘加英, 任璐. 短b轴ZSM-5分子筛制备方法及应用研究进展[J]. 化工学报, 2023, 74(4): 1457-1473.
Fig.2 Crystallization of MFI nanosheets: (a) Structure model for the single MFI nanosheet (Surfactant molecules are aligned along the straight channel of MFI framework. Two quaternary ammonium groups (indicated as a red sphere) are located at the channel intersections. One is inside the framework, and the other is at the pore mouth of the external surface); (b) Many MFI nanosheets form either multilamellar stacking along the b-axis; (c) A random assembly of unilamellar structure [31]
Fig.8 Formation mechanism of the single-crystalline hierarchical plate-like ZSM-5 crystal for zeolite syntheses in one step (at 170℃) or in two steps (at 80℃ and then at 170℃)[63]
Fig.9 Average product selectivity (a) and catalyst lifetime (b) for MTP reactions over the ZSM-5 catalysts [glucose/SiO2 is Z5-A: 0, Z5-B: 0.12, Z5-C: 0.24; Z5-C loading P is Z5-CP: 1.5%(mass), Z5-CP2: 2.0%(mass), Z5-CP3: 3.0%(mass)][76]
Fig. 11 Catalytic conversion of methanol (a); Product selectivity (LPG, C5+ and aromatics) (b); TG profiles (c) and GC-MS chromatograms (d) of organic species retained in the spent catalysts of U-ZSM-5-0.03 and SH-ZSM-5 after the methanol conversion[81]
Fig. 12 n-Heptane cracking performance of ZSM-5 nanosheets with different b-axis thicknesses: Conversion of n-heptane as a function of time on stream (a); TG analysis of coke content over spent ZSM-5 nanosheets (b)[86]
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