Determination of three-dimensional solubility parameters using IGC and HSPiP

doi:10.11949/j.issn.0438-1157.20170609

Abstract

Abstract:

The three-dimensional solubility parameters(HSP) of raw coal were determined by inverse gas chromatography (IGC) in the temperature range 433.15 to 473.15 K. The HSP concept was applied to determine components (δ_d, δ_p and δ_h) of corrected solubility parameter (δ_t), and the HSP of raw coal was derived as δ_d=20.83(J·cm^-3)^1/2, δ_p=11.95(J·cm^-3)^1/2, δ_h=11.08(J·cm^-3)^1/2 and δ_t=26.44(J·cm^-3)^1/2 by extrapolation method at room temperature (298.15 K), the HSP of raw coal that was measured as δ_d=19.92(J·cm^-3)^1/2, δ_p=11.18(J·cm^-3)^1/2, δ_h=11.47(J·cm^-3)^1/2 and δ_t=25.56(J·cm^-3)^1/2by the HSPiP method at room temperature. The results are consistent through two approaches. The results of the study provide a reference for the study of the thermodynamic properties of coal and the choice of its swelling agent.

Key words: coal, thermodynamic properties, solubility parameters, inverse gas chromatography, HSPiP

摘要：

采用反气相色谱法（IGC）研究原煤在温度433.15、443.15、453.15、463.15和473.15 K时的三维溶解度参数（HSP），并使用外推法得到原煤室温（298.15 K）时HSP的色散力分量（δ_d）、极性力分量（δ_p）、氢键力分量（δ_h）以及校正溶解度参数（δ_t）分别为δ_d=20.83（J·cm^-3）^1/2，δ_p=11.95（J·cm^-3）^1/2，δ_h=11.08（J·cm^-3）^1/2，δ_t=26.44（J·cm^-3）^1/2。同时，采用汉森三维溶解度参数软件（HSPiP）模拟原煤在室温下的HSP，得到δ_d=19.92（J·cm^-3）^1/2，δ_p=11.18（J·cm^-3）^1/2，δ_h=11.47（J·cm^-3）^1/2，δ_t=25.56（J·cm^-3）^1/2。IGC与HSPiP得出的数据一致，研究结果为煤的热力学性质研究及其溶胀剂的选择等应用提供了参考。

关键词: 煤, 热力学性质, 溶解度参数, 反气相色谱技术, 汉森三维溶解度参数软件

CLC Number:

TQ511

PAN Xinyu, ZHAO Li, MA Kongjun, WANG Qiang. Determination of three-dimensional solubility parameters using IGC and HSPiP[J]. CIESC Journal, 2017, 68(12): 4494-4499.

潘薪羽, 赵丽, 马空军, 王强. 反气相色谱法与汉森溶解度参数软件测定原煤的三维溶解度参数[J]. 化工学报, 2017, 68(12): 4494-4499.

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