CIESC Journal ›› 2022, Vol. 73 ›› Issue (6): 2690-2697.DOI: 10.11949/0438-1157.20220150
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Chan WANG1,2(),Guoxi XIAO1,Xiaoxue GUO1,Renwei XU3,Yuanyuan YUE1,2(),Xiaojun BAO1,2
Received:
2022-01-25
Revised:
2022-04-08
Online:
2022-06-30
Published:
2022-06-05
Contact:
Yuanyuan YUE
王婵1,2(),肖国锡1,郭小雪1,徐人威3,岳源源1,2(),鲍晓军1,2
通讯作者:
岳源源
作者简介:
王婵(1987—),女,博士,讲师,基金资助:
CLC Number:
Chan WANG, Guoxi XIAO, Xiaoxue GUO, Renwei XU, Yuanyuan YUE, Xiaojun BAO. Green synthesis and application of Beta zeolite prepared via mesoscale depolymerization-reorganization strategy[J]. CIESC Journal, 2022, 73(6): 2690-2697.
王婵, 肖国锡, 郭小雪, 徐人威, 岳源源, 鲍晓军. 基于介尺度结构解聚-重组装的Beta分子筛的绿色合成及应用[J]. 化工学报, 2022, 73(6): 2690-2697.
Sample | SBET①/ (m2/g) | Smicro②/ (m2/g) | Sext②/ (m2/g) | Vtotal①/ (cm3/g) | Vmicro②/ (cm3/g) | Vmeso③/ (cm3/g) |
---|---|---|---|---|---|---|
Beta-Ref | 461 | 344 | 117 | 0.33 | 0.18 | 0.15 |
Beta-Anhyd | 586 | 379 | 207 | 0.50 | 0.20 | 0.30 |
Table 1 Textural characteristics of Beta-Anhyd and Beta-Ref
Sample | SBET①/ (m2/g) | Smicro②/ (m2/g) | Sext②/ (m2/g) | Vtotal①/ (cm3/g) | Vmicro②/ (cm3/g) | Vmeso③/ (cm3/g) |
---|---|---|---|---|---|---|
Beta-Ref | 461 | 344 | 117 | 0.33 | 0.18 | 0.15 |
Beta-Anhyd | 586 | 379 | 207 | 0.50 | 0.20 | 0.30 |
Samples | Amount of acid sites/(μmol/g) | ||||||
---|---|---|---|---|---|---|---|
200℃ | 350℃ | ||||||
B | L | Total | B | L | Total | ||
Beta-Ref | 182.37 | 176.01 | 358.38 | 84.73 | 112.56 | 197.28 | |
Beta-Anhyd | 143.76 | 87.57 | 231.34 | 97.29 | 62.92 | 160.24 | |
Beta-Ref-Deal | 31.94 | 175.84 | 207.78 | 15.37 | 8.59 | 23.96 | |
Beta-Anhyd-Deal | 22.74 | 153.06 | 175.80 | 6.97 | 45.04 | 52.00 |
Table 2 Acid sites amount of Beta-Anhyd-Deal and Beta-Ref-Deal
Samples | Amount of acid sites/(μmol/g) | ||||||
---|---|---|---|---|---|---|---|
200℃ | 350℃ | ||||||
B | L | Total | B | L | Total | ||
Beta-Ref | 182.37 | 176.01 | 358.38 | 84.73 | 112.56 | 197.28 | |
Beta-Anhyd | 143.76 | 87.57 | 231.34 | 97.29 | 62.92 | 160.24 | |
Beta-Ref-Deal | 31.94 | 175.84 | 207.78 | 15.37 | 8.59 | 23.96 | |
Beta-Anhyd-Deal | 22.74 | 153.06 | 175.80 | 6.97 | 45.04 | 52.00 |
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