低温吸湿复合吸附剂的制备及吸湿性能

doi:10.11949/j.issn.0438-1157.20150297

化工学报 ›› 2015, Vol. 66 ›› Issue (S1): 154-158.DOI: 10.11949/j.issn.0438-1157.20150297

低温吸湿复合吸附剂的制备及吸湿性能

赖艳华, 吴涛, 赵琳妍, 董震, 郝宗华, 陈常念, 吕明新

山东大学能源与动力工程学院, 山东济南 250061

收稿日期:2015-03-10 修回日期:2015-03-17 出版日期:2015-06-30 发布日期:2015-06-30
通讯作者: 赖艳华
基金资助:
山东省科技发展计划(2013GGX10403);济南市高校自主创新计划(201202090);国家自然科学基金项目(51476093)。

Preparation and dehumidification performance of composite adsorbent for low-temperature desiccants

LAI Yanhua, WU Tao, ZHAO Linyan, DONG Zhen, HAO Zonghua, CHEN Changnian, LÜ Mingxin

School of Energy and Power Engineering, Shandong University, Jinan 250061, Shandong, China

Received:2015-03-10 Revised:2015-03-17 Online:2015-06-30 Published:2015-06-30
Supported by:
supported by Science and Technology Development Program of Shandong Province(2013GGX10403), the Independent Innovation Foundation of Jinan (201202090), the National Natural Science Foundation of China (51476093).

摘要/Abstract

摘要：

针对冷库结霜严重制约其经济性的问题, 化学固体吸附除湿防霜技术逐渐得到重视。本文将对水吸附能力较强的金属卤化物与容易定型且传热传质性能较好的分子筛相结合, 制成复合吸附剂, 建立了低温情况下吸附材料的吸湿性能测试系统, 并进行了大量测试, 给出了多种材料在-5℃、-10℃、-15℃下的吸湿量及吸湿速率变化, 实验结果表明复合吸附剂的吸附性能与单纯的分子筛相比有了明显的改善, 13X型分子筛浸渍浓度20%的NaBr溶液所得试样吸湿量和吸湿速率性能优越, 复合过程中损失较少, 成本低, 可作为复合吸附剂应用于冷库除湿系统中。

关键词: 低温, 复合吸附剂, 制备, 吸湿性能

Abstract:

Cold storage frost severely restricted its economy, to solve this problem, chemical adsorption dehumidification frost prevention technology has been paid great attention. Some kind of composite adsorbents have been made comparing metal halide which has great water adsorption capacity with molecular sieve, which has good heat and mass transfer properity, and is easy to shape. Moisture adsorption performance testing system has been constructed suitable for material under low temperature. A great many of tests have been made. The moisture adsorption capacity and rate of a variety of materials in -5℃, -10℃, -15℃ have been given. It is shown that the adsorption performance of compound adsorbent was obviously improved compared with pure molecular sieve. 13X molecular sieve dipping solution concentration 20% of NaBr had better amount of moisture adsorption and rate, less loss in the process of composition, low cost, which could be used in cold storage dehumidification system as a composite adsorbent.

Key words: low temperature, composite adsorbent, preparation, moisture adsorption

中图分类号:

TQ21.4

赖艳华, 吴涛, 赵琳妍, 董震, 郝宗华, 陈常念, 吕明新. 低温吸湿复合吸附剂的制备及吸湿性能[J]. 化工学报, 2015, 66(S1): 154-158.

LAI Yanhua, WU Tao, ZHAO Linyan, DONG Zhen, HAO Zonghua, CHEN Changnian, LÜ Mingxin. Preparation and dehumidification performance of composite adsorbent for low-temperature desiccants[J]. CIESC Journal, 2015, 66(S1): 154-158.

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低温吸湿复合吸附剂的制备及吸湿性能

Preparation and dehumidification performance of composite adsorbent for low-temperature desiccants

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