WPP/NWPCB/POE复合材料的制备及其热解特性

doi:10.11949/j.issn.0438-1157.20150671

化工学报 ›› 2015, Vol. 66 ›› Issue (12): 5163-5170.DOI: 10.11949/j.issn.0438-1157.20150671

• 材料化学工程与纳米技术 • 上一篇下一篇

WPP/NWPCB/POE复合材料的制备及其热解特性

陈义忠, 吴曼, 谢恒来, 刘新民, 郭庆杰

青岛科技大学化工学院, 清洁化工过程山东省高校重点实验室, 山东青岛 266042

收稿日期:2015-05-22 修回日期:2015-07-15 出版日期:2015-12-05 发布日期:2015-12-05
通讯作者: 郭庆杰
基金资助:
国家高技术研究发展计划项目(SS2012AA062613);山东省科技攻关项目(2008GG10006010)。

Pyrolysis characteristics and preparation of WPP/NWPCB/POE composites

CHEN Yizhong, WU Man, XIE Henglai, LIU Xinmin, GUO Qingjie

Key Laboratory of Clean Chemical Processing of Shandong Province, Qingdao University of Science &Technology, Qingdao 266042, Shandong, China

Received:2015-05-22 Revised:2015-07-15 Online:2015-12-05 Published:2015-12-05
Supported by:
supported by the National High Technology Research and Development Program of China (SS2012AA062613) and the Key Scientific and Technological Project in Shandong Province (2008GG10006010).

摘要/Abstract

摘要：

以废旧汽车保险杠(WPP)为基体,废弃线路板非金属粉(NWPCB)为填料,通过熔融共混的方法制备了系列WPP/NWPCB复合材料。在此基础上,用乙烯-辛烯共聚物(POE)和马来酸酐接枝聚丙烯(PP-g-MAH)对复合材料进行了协同改性,以增强复合材料的性能。力学性能测试和冲击断面微观形貌分析表明,POE显著提高了WPP/NWPCB复合材料的韧性,当POE用量为15 g·(100 g)^-1时,冲击强度较改性前提高129%;PP-g-MAH能够有效改善复合材料中填料与基体相容性,当添加量为9 g·(100 g)^-1时,复合材料的机械性能达到最佳,冲击强度、弯曲强度和拉伸强度较改性前分别提高7.8%、23.4%和20%。通过热重-红外联用研究了WPP/NWPCB/POE复合材料的热解过程,结果表明,复合材料在热解过程中除产生烷烃、烯烃及CO₂外,还产生了少量的苯酚类芳香族化合物与HBr等有害气体,同时NWPCB填料的添加提高了复合材料中WPP的热稳定性。

关键词: 废弃线路板非金属粉, 弹性体, 复合材料, 机械性能, 热解

Abstract:

With the waste polypropylene (WPP) as matrix and the modificated non-metallic powder from waste printed circuit boards (NWPCB) as filler, the WPP/NWPCB composites were prepared by means of the melt blending. To enhance the mechanical characters, the WPP/NWPCB composites were synergistically modified by ethylene octene copolymer (POE) and maleic anhydride grafted polypropylene (PP-g-MAH). The mechanical properties and morphology analysis showed that POE greatly improved the impact strength of WPP/NWPCB composite materials. When the content of POE was 15 g·(100 g)^-1, the impact strength of WPP/NWPCB composites was increased by 129%. The interface bonding strength between filler and matrix was improved with modification by 9 g·(100 g)^-1 PP-g-MAH. The impact strength, tensile strength and flexural strength were increased by 7.8%, 23.4% and 20% respectively. The pyrolysis characteristics of WPP/NWPCB/POE composite materials were investigated by means of TGA-FTIR at nitrogen atmosphere. It indicated that the heat stability of WPP material in the composites was improved by the addition of NWPCB. The alkanes, olefins and CO₂ were released during the pyrolysis process of WPP/NWPCB composites, whereas a small amount of harmful gas such as phenol aromatic compounds and hydrogen bromide was also produced.

Key words: waste printed circuit boards nonmetal particles, elastomer, composites, mechanical property, pyrolysis

中图分类号:

X783.2

陈义忠, 吴曼, 谢恒来, 刘新民, 郭庆杰. WPP/NWPCB/POE复合材料的制备及其热解特性[J]. 化工学报, 2015, 66(12): 5163-5170.

CHEN Yizhong, WU Man, XIE Henglai, LIU Xinmin, GUO Qingjie. Pyrolysis characteristics and preparation of WPP/NWPCB/POE composites[J]. CIESC Journal, 2015, 66(12): 5163-5170.

参考文献 26

[1]	Huang K, Guo J, Xu Z. Recycling of waste printed circuitboards: a review of current technologies and treatment status in China [J]. Journal of Hazardous Materials, 2009, 164 (2/3): 399-408.
[2]	Veit H M, Diehl T R, Salami A P, Rodrigues J S, Bernardes A M, Tenório J A S. Utilization of magnetic and electrostatic separation in the recycling of printed circuit boards scrap [J]. Waste Management, 2005, 25 (1): 67-74.
[3]	Guo J, Li J, Rao Q L, Xu Z M. Phenolic moldingcompound filled with nonmetals of waste PCBs [J]. Environmental Science & Technology, 2008, 42 (2): 624-628.
[4]	Wang Xinjie (王新杰), Guo Yuwen (郭玉文), Zhang Jianqiang (张建强), Qiao Qi (乔琦), Liu Jingyang (刘景洋). Properties of non-metallic powder recycled form paper-based printed circuit boards and performance of composites [J]. CIESC Journal (化工学报), 2010, 61 (3): 795-800.
[5]	Zheng Y H, Shen Z G, Cai C J, Ma S L, XingY S. The reuse of nonmetals recycled from waste printed circuit boards as reinforcing fillers in the polypropylene composites [J]. Journal of Hazardous Materials, 2009, 163 (2/3): 600-606.
[6]	Liu Luyan (刘鲁艳), Guo Qingjie (郭庆杰), Wu Man (吴曼), Liu Xinmin (刘新民), Xie Henglai (谢恒来), Wang Xuyun (王许云). Preparation and performance of composites using waste poly- propylene and waste non-metallic powder recycled from printed circuit board [J]. CIESC Journal (化工学报), 2013, 65 (4): 1495- 1502.
[7]	Xie Henglai (谢恒来), Wu Man (吴曼), Zhao Jun (赵军), Chen Yizhong (陈义忠), Guo Qingjie (郭庆杰). Coating modification of non-metal particles of waste printed circuit boards in spout-fluid bed with draft tube [J]. CIESC Journal (化工学报), 2015, 66 (3): 1185- 1193.
[8]	Zheng Jiaxing (郑佳星), Li Yingchun (李迎春), Guo Xiaochen (郭晓晨). Influence of surface treatments on the mechanical properties of PA6 composites filled with wasted printed circuit board basement [J]. China Plastics Industry (塑料工业), 2013, 41 (2): 32-36.
[9]	Wang Feng (王丰), He Hui (何慧), Chen Jizun (陈继尊), Jia Zhixin (贾志欣), Luo Yuanfang (罗远芳), Jia Demin (贾德民). Modifying of PE wood-plastic composite with waste printed circuit board nonmetal powder [J]. Polymer Materials Science and Engineering (高分子材料科学与工程), 2012, 28 (8): 174-177.
[10]	CJ/T 212-2005. Water grate made of polymer matrix composites [S].
[11]	CJ/T 211-2005. Inspection manhole lid made of polymer matrix composites [S].
[12]	Yang J, Zhang Y, Zhang Y. Brittle-ductile transition of PP/POE blends in both impact and high speed tensile tests [J]. Polymer, 2003, 44 (3): 5047-5052.
[13]	Yuan B, Chen X, He B. Studies on rheology and morphology of POE/PP thermoplastic elastomer dynamically crosslinked by peroxide [J]. Journal of Vinyl & Additive Technology, 2008, 14 (2): 45-54.
[14]	Cui J, Forssberg E. Mechanical recycling of waste electricand electronic equipment: a review [J]. Journal of Hazardous Materials, 2003, 99 (3): 243-263.
[15]	Sun Lushi (孙路石), Lu Jidong (陆继东), Wang Shijie (王世杰), et al. Experimental research on pyrolysis characteristics of printed circuit board wastes [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2003, 54 (3): 408-412.
[16]	Hornung A, Donner S, Balabanovich A, et al. Polypropylene as a reductive agent for dehaloge-nation of brominated organic compounds [J]. Journal of Cleaner Production, 2005, 13 (5): 525-530.
[17]	Bai H, Wang Y, Song B, et al. Nucleating agent induced impact fracture behavior change in PP/POE blend [J]. Polymer Bulletin, 2009, 62 (3): 405-419.
[18]	Dai S S, Ye L, Hu G H. Preparation and properties of PP/PC/POE blends [J]. Polymers Advanced Technologies, 2009, 10 (1002): 279-288.
[19]	Li X, Wu H, Wang Y, et al. Study on the β to α transformation of PP/POE blends with β-phase nucleating agent during the tensile deformation process [J]. Materials Science & Engineering A, 2010, 527 (3): 531-538.
[20]	Benalia K, Aicha S. Properties of polypropylene/polyamide nanocomposites prepared by melt processing with a PP-g-MAH compatibilizer [J]. Materials and Design, 2012, 34: 313-318.
[21]	Zhou Xiaodong (周晓东), Lin Qunfang (林群芳), Guo Wenjun (郭文军), Dai Gance (戴干策). Influence of the flexible interlayer on the mechanical properties of glass matreinforced polypropylene composite [J]. Polymer Materials Science and Engineering (高分子材料科学与工程), 2001, 17 (2): 137-140.
[22]	Jiang X L, Zhang Y, Zhang Y X. Dynamically cured PP/epoxy blends compatibilized with MAH-g-PP [J]. Polymer & Polymer Composites, 2004, 12 (1): 1-14.
[23]	Liu Xuexi (刘学习), Dai Gance (戴干策). Compare the compatibilizing mechanism of silane-grafted polypropylene with maleic anhydride grafted polypropylene on PP/GF composites [J]. Polymer Materials Science and Engineering (高分子材料科学与工程), 2007, 23 (5): 128-131.
[24]	Blazsó M, Czégény Z, Csoma C. Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis [J]. Journal of Analytical & Applied Pyrolysis, 2002, 64 (2): 249-261.
[25]	Peng Shaohong (彭绍洪), Chen Lieqiang (陈烈强), Gan Ge (甘舸), Cai Mingzhao (蔡明招).Vacuum pyrolysis of waste printed circuit boards [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2006, 57 (11): 2720-2726.
[26]	Zhou Y, Qiu K. A new technology for recycling materials from waste printed circuit boards [J]. Journal of Hazardous Materials, 2010, 175(1-3): 823-828.

WPP/NWPCB/POE复合材料的制备及其热解特性

Pyrolysis characteristics and preparation of WPP/NWPCB/POE composites

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