纳米多孔NiO类空心微球负极材料的制备与储锂性能

doi:10.11949/j.issn.0438-1157.20161840

化工学报 ›› 2017, Vol. 68 ›› Issue (6): 2596-2603.DOI: 10.11949/j.issn.0438-1157.20161840

• 材料化学工程与纳米技术 • 上一篇下一篇

纳米多孔NiO类空心微球负极材料的制备与储锂性能

郑远远¹, 姚金环¹, 姜吉琼¹, 李延伟^1,2

1. 广西电磁化学功能物质重点实验室, 桂林理工大学化学与生物工程学院, 广西桂林 541004;
2. 桂林理工大学广西有色金属隐伏矿床勘查及材料开发协同创新中心, 广西桂林 541004

收稿日期:2016-12-30 修回日期:2017-03-14 出版日期:2017-06-05 发布日期:2017-06-05
通讯作者: 李延伟
基金资助:
国家自然科学基金项目（21263003，51664012，51464009）；广西自然科学基金项目（2015GXNSFGA139006，2014GXNSFBA118238）；广西研究生教育创新计划项目（YCSW2017158）

Preparation and lithium storage performance of nanoporous hollow microspheres-like NiO anode materials

ZHENG Yuanyuan¹, YAO Jinhuan¹, JIANG Jiqiong¹, LI Yanwei^1,2

1. Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, China;
2. Guilin University of Technology, Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Guilin 541004, Guangxi, China

Received:2016-12-30 Revised:2017-03-14 Online:2017-06-05 Published:2017-06-05
Contact: 10.11949/j.issn.0438-1157.20161840
Supported by:
supported by the National Natural Science Foundation of China (21263003, 51664012, 51464009), the Natural Science Foundation of Guangxi (2015GXNSFGA139006, 2014GXNSFBA118238) and the Innovation Project of Guangxi Graduate Education (YCSW2017158)

摘要/Abstract

摘要：

以NiCl₂·6H₂O、尿素、葡萄糖为原料采用水热法制备了NiO前体，将前体在空气中烧结最终得到NiO电极活性材料。该NiO样品具有镂空结构的类空心球形貌，且由50~100 nm初级纳米颗粒构成。对该NiO样品作为锂离子电池负极材料的储锂性能进行了研究，结果发现赝电容效应对该材料储锂容量和倍率性能有重要贡献。因独特的空心纳米结构和赝电容效应，该材料表现出出色的电化学循环稳定性和优异的大倍率充放电性能。在500 mA·g^-1电流密度下，100圈充放电循环后放电比容量为650 mA·h·g^-1，容量保持率达86.6%；在10 A·g^-1的超高倍率下，其稳定放电比容量仍高达432 mA·h·g^-1。

关键词: 锂离子电池, 电化学, 水热, 纳米材料, 空心球, 赝电容效应

Abstract:

Using NiCl₂·6H₂O, urea, and glucose as materials, hollow microspheres-like NiO were prepared by hydrothermal method followed by annealing in air at 700℃. The results of microstructural characterization reveal that the hollow microspheres-like NiO are composed of nanosized primary particles (50—100 nm). The electrochemical performances of the prepared NiO samples were investigated. It is found that the pseudocapacitive effect has a prominent contribution to the lithium storage capacity of the NiO electrode. Due to the unique hollow structure and pseudocapacitive effect, the NiO electrode shows outstanding electrochemical cycling stability and excellent high rate capability. For example, the NiO electrode retains a high reversible capacity of 650 mA·h·g^-1 after 100 cycles at a current density of 500 mA·g^-1. Even at ultra-high current density of 10 A·g^-1, the NiO electrode can still deliver a capacity of 432 mA·h·g^-1.

Key words: lithium ion batteries, electrochemistry, hydrothermal, nanomaterials, hollowspheres, pseudocapacitive effects

中图分类号:

TQ152

郑远远, 姚金环, 姜吉琼, 李延伟. 纳米多孔NiO类空心微球负极材料的制备与储锂性能[J]. 化工学报, 2017, 68(6): 2596-2603.

ZHENG Yuanyuan, YAO Jinhuan, JIANG Jiqiong, LI Yanwei. Preparation and lithium storage performance of nanoporous hollow microspheres-like NiO anode materials[J]. CIESC Journal, 2017, 68(6): 2596-2603.

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纳米多孔NiO类空心微球负极材料的制备与储锂性能

Preparation and lithium storage performance of nanoporous hollow microspheres-like NiO anode materials

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