化工学报 ›› 2018, Vol. 69 ›› Issue (S1): 129-135.DOI: 10.11949/j.issn.0438-1157.20180748

• 材料化学工程与纳米技术 • 上一篇    下一篇

碳酸盐复合蓄热材料的制备及热物性研究

桑丽霞, 李锋   

  1. 北京工业大学环境与能源工程学院, 传热强化与过程节能教育部重点实验室及传热与能源利用北京市重点实验室, 北京 100124
  • 收稿日期:2018-07-05 修回日期:2018-07-12 出版日期:2018-09-30 发布日期:2018-09-30
  • 通讯作者: 桑丽霞(1975-),女,博士,研究员,E-mail:sanglixia@bjut.edu.cn
  • 基金资助:

    北京市自然科学基金项目(3151001)。

Study on preparation and thermal properties of carbonates composite heat storage materials

SANG Lixia, LI Feng   

  1. Key Laboratory of Enhanced Heat Transfer and Energy Conservation, Ministry of Education and Key Laboratory of Heat Transfer and Energy Conversion of Beijing Municipality, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • Received:2018-07-05 Revised:2018-07-12 Online:2018-09-30 Published:2018-09-30
  • Supported by:

    supported by the Natural Science Foundation of Beijing (3151001).

摘要:

以二元碳酸盐(Li2CO3-K2CO3,BC,62:38,摩尔比)和三元碳酸盐(K2CO3-Li2CO3-Na2CO3,TC,1:2:1,摩尔比)为相变材料,以氧化镁为基体材料,通过混合烧结法制备陶瓷基复合蓄热材料。二元碳酸盐复合材料(BCC)和三元碳酸盐复合材料(TCC)的熔点与相应混合碳酸盐的熔点相近,分别为465.1℃和386.4℃,并在其最高使用温度(800℃)范围内维持较高的比热容;且复合材料的潜热值均大于150.0 J/g。基于XRD和SEM的表征分析,两种复合蓄热材料具有较好的化学稳定性,且基体材料能很好地混合支撑相变材料。两种复合材料分别进行50次热循环,其热物性参数没有发生明显变化,具有较好的热循环稳定性。

关键词: 混合碳酸盐, 制备, 相变, 复合材料, 潜热, 熔点

Abstract:

Ceramic composite heat storage materials were prepared by mixed sintering method with binary carbonates (Li2CO3-K2CO3, BC, 62:38, mole ratio) and ternary carbonates (K2CO3-Li2CO3-Na2CO3, TC, 1:2:1, mole ratio) as phase change materials, and with magnesium oxide as the matrix material. The melting point of binary and ternary carbonates composites (BCC, TCC) are 465.1℃ and 386.4℃ respectively, which is similar to the corresponding mixed carbonates. Composite heat storage materials maintain a high specific heat value within the highest using temperature (800℃), and the latent heat is more than 150 J/g. Based on the characterization analysis of XRD and SEM, two kinds of composite heat storage materials have good chemical stability, and the matrix material can well support the phase change material. The thermal properties of the composite heat storage materials don't change significantly and have good thermal cycling stability after 50 thermal cycles.

Key words: mixed carbonates, preparation, phase change, composite materials, latent heat, melting point

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