等离子体法制备掺杂Ni碳材料的储氢性能

doi:10.3969/j.issn.0438-1157.2013.02.039

化工学报 ›› 2013, Vol. 64 ›› Issue (2): 696-701.DOI: 10.3969/j.issn.0438-1157.2013.02.039

等离子体法制备掺杂Ni碳材料的储氢性能

王召, 龚俊波

天津大学化工学院,化学工程联合国家重点实验室,天津 300072

收稿日期:2012-07-25 修回日期:2012-08-31 出版日期:2013-02-05 发布日期:2013-02-05
通讯作者: 龚俊波
作者简介:王召(1981—),男,博士,助理研究员。
基金资助:
国家自然科学基金项目(21206109);天津自然科学基金项目(12JCQNJC04500);化学工程联合国家重点实验室开放课题(SKL-ChE-11B02)。

Performance of hydrogen storage of Ni-doped carbon prepared with plasma method

WANG Zhao, GONG Junbo

State Key Laboratory of Chemical Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300072, China

Received:2012-07-25 Revised:2012-08-31 Online:2013-02-05 Published:2013-02-05
Supported by:
supported by the National Natural Science Foundation of China(21206109), Tianjin Municipal Natural Science Foundation(12JCQNJC04500) and the State Key Laboratory of Chemical Engineering(SKL-ChE-11B02).

摘要/Abstract

关键词: 等离子体, 氢溢流, 储氢, 掺杂Ni, 碳材料

Abstract: Hydrogen adsorption performance of a superactived carbon (Maxsorb) doped with Ni nanoparticles, prepared using plasma method, was studied.By comparing the material with sample prepared using traditional H₂ reduction, the effect of plasma on structure and performance of adsorbing H₂ of these samples was analyzed.The hydrogen storage capacity was significantly increased for plasma treatment samples.The H₂ storage capacity for Ni-doped Maxsorb at 298 K and 10 MPa was 1.17%(mass), and only 0.98%(mass) for H₂ reduction sample and 0.68% (mass) for pure Maxsorb one.Doping of Ni made storage capacity of carbon increase via hydrogen spillover mechanism.The sample with plasma treatment had smaller Ni particles that were highly dispersed on carbon.Meanwhile, it was found that there was stronger anchoring and more intimate contacts between metal and carbon.The increase of adsorption heat for the sample with plasma treatment suggests that the bonding between hydrogen atoms and the surface of Ni/Maxsorb was stronger, which was in agreement with high-pressure hydrogen adsorption results.

Key words: plasma treatment, hydrogen spillover, hydrogen storage, Ni-doped, carbon

中图分类号:

TQ028.1
TK91

王召, 龚俊波. 等离子体法制备掺杂Ni碳材料的储氢性能[J]. 化工学报, 2013, 64(2): 696-701.

WANG Zhao, GONG Junbo. Performance of hydrogen storage of Ni-doped carbon prepared with plasma method[J]. CIESC Journal, 2013, 64(2): 696-701.

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等离子体法制备掺杂Ni碳材料的储氢性能

Performance of hydrogen storage of Ni-doped carbon prepared with plasma method

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