木质素碳纳米材料制备及在催化中的应用研究进展

doi:10.11949/0438-1157.20210090

化工学报 ›› 2021, Vol. 72 ›› Issue (9): 4445-4457.DOI: 10.11949/0438-1157.20210090

木质素碳纳米材料制备及在催化中的应用研究进展

王欢¹(),符方宝¹,李琼¹,席跃宾²(),杨东杰¹()

^1.华南理工大学化学与化工学院，广东广州 510640
^2.齐鲁工业大学（山东省科学院）制浆造纸科学与技术教育部重点实验室，生物基材料与绿色造纸国家重点实验室，山东济南 250353

收稿日期:2021-01-13 修回日期:2021-03-30 出版日期:2021-09-05 发布日期:2021-09-05
通讯作者: 席跃宾,杨东杰
作者简介:王欢(1988—)，男，博士，助理研究员，cewanghuan@scut.edu.cn
基金资助:
国家重点研发计划项目(2018YFB1501503);国家自然科学基金项目(21878114);广东省自然科学基金项目(2018B030311052);中国博士后科学基金项目(2019M652901);制浆造纸科学与技术教育部重点实验室开放基金项目(KF201902)

Research progress on the preparation of lignin-derived carbon materials and their application in catalysis

Huan WANG¹(),Fangbao FU¹,Qiong LI¹,Yuebin XI²(),Dongjie YANG¹()

^1.School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
^2.Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, Shandong, China

Received:2021-01-13 Revised:2021-03-30 Online:2021-09-05 Published:2021-09-05
Contact: Yuebin XI,Dongjie YANG

摘要/Abstract

摘要：

木质素是自然界储量丰富的可再生资源，含碳量高且具有三维网状结构和大量共轭结构。碳材料是一类具有极大应用价值的催化材料，特别是在电催化、热催化和光催化领域。以木质素为原料制备高活性的木质素碳基催化剂是实现木质素高附加值利用有效的途径之一。木质素碳催化材料研究涉及化学、化工和物理等多个学科领域，制备性能优异和稳定性良好的木质素碳基催化剂仍充满挑战。本文主要总结了木质素碳材料的制备研究进展，以及介绍了木质素碳材料在光催化、热催化和电催化等领域的应用研究现状。此外，还分析了当前木质素碳基催化材料存在的问题，并展望了未来的发展趋势和重点研究方向。

关键词: 生物质, 木质素碳材料, 制备, 催化剂, 催化剂载体

Abstract:

Lignin is a renewable resource with abundant natural reserves, high carbon content, three-dimensional network structure, and a large number of conjugate structures. Carbon materials are a kind of catalyst materials with great application value, especially in the fields of electrocatalysis, thermal catalysis and photocatalysis. The preparation of lignin-derived carbon catalysts with high catalytic activity through precise control of their microstructure characteristics is one of the most effective ways to realize the ultra-high value-added utilization of lignin. The research of lignin-derived carbon catalysts is an interdisciplinary frontier subject involving chemistry, chemical engineering, physics and other disciplines. The controllable preparation of lignin-based carbon catalysts with excellent performance and good stability is still a challenging subject. This article mainly summarizes the recent research of lignin-derived carbon materials, and introduces the application in photocatalysis, thermal catalysis, and electrocatalysis. In addition, the current problems of lignin carbon-based catalytic materials are analyzed, and future development trends and key research directions are prospected.

Key words: biomass, lignin-derived carbon materials, preparation, catalyst, catalyst support

中图分类号:

TQ 028.8

王欢, 符方宝, 李琼, 席跃宾, 杨东杰. 木质素碳纳米材料制备及在催化中的应用研究进展[J]. 化工学报, 2021, 72(9): 4445-4457.

Huan WANG, Fangbao FU, Qiong LI, Yuebin XI, Dongjie YANG. Research progress on the preparation of lignin-derived carbon materials and their application in catalysis[J]. CIESC Journal, 2021, 72(9): 4445-4457.

图/表 10

图1 木质素碳基纳米材料的制备及其微结构特性

Fig.1 The preparation and microstructure characteristics of lignin-derived carbon nanomaterials

图2 SiO2/P123双模板法制备木质素碳材料流程及其微观形貌[39]

Fig.2 Flow chart and micro-morphologies of preparing lignin carbon material by SiO2/P123 co-template method[39]

图3 木质素碳纳米纤维的SEM、TEM和孔径分布图[42]

Fig.3 SEM, TEM images and pore size distribution of ECNFs[42]

图4 木质素花状碳制备流程和微观结构特性[47]

Fig.4 Preparation flow chart and microstructure characteristics of lignin-derived carbon nanoflower[47]

图5 分级木质素多孔碳的制备流程及其微结构特性[53]

Fig.5 The preparation process of hierarchical lignin-derived porous carbon and its micro-morphology and pore structure characteristics[53]

图6 ZnO/LHC复合材料的合成过程和微观形貌[32]

Fig.6 Preparation flow chart and micro morphology of ZnO/LHC composite[32]

图7 木质素碳基催化剂

Fig.7 Lignin-derived carbon-based catalysts

图8 木质素碳/ZnO纳米花复合材料光催化降解抗生素性能及其光催化机理[47]

Fig. 8 The photocatalytic degradation properties of lignin-derived carbon/ZnO nanoflower composites and their photocatalytic mechanism[47]

图9 N，S，Cl共掺杂的3D木质素多孔碳的微观形貌和电化学性能[52]

Fig.9 Micro-morphology and electrochemical properties of 3D porous lignin-derived multi-doped (N, S, Cl) carbon[52]

图10 木质素碳/Fe复合材料的微观形貌及其催化性能[68]

Fig. 10 Micromorphology and catalytic performance of lignin-derived carbon/Fe composite[68]

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木质素碳纳米材料制备及在催化中的应用研究进展

Research progress on the preparation of lignin-derived carbon materials and their application in catalysis

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