化工学报 ›› 2003, Vol. 54 ›› Issue (5): 702-703.

• 催化、动力学与反应器 • 上一篇    下一篇

辉光放电等离子体增强制备甲烷催化燃烧的高分散Pd/Al2O3催化剂

韩森; 于开录; 何琲; 刘昌俊   

  1. 天津大学化工学院一碳化学与化工国家重点实验室
  • 出版日期:2003-05-25 发布日期:2003-05-25

PLASMA-ENHANCED PREPARATION OF HIGHLY DISPERSED Pd/Al2O3 CATALYST FOR CATALYTIC COMBUSTION OF METHANE

HAN Sen,YU Kailu,HE Fei ,LIU Changjun   

  • Online:2003-05-25 Published:2003-05-25

关键词: 等离子体, 甲烷催化燃烧, Pd/Al2O3催化剂

Abstract: A novel Pd/Al2O3 catalyst prepared by glow discharge plasma technology is reported.The results of H2-chemisorption indicate that palladium dispersion of the plasma-prepared Pd/Al2O3 reaches 29.7%,which is about 5 times higher than Pd/Al2O3 prepared by conventional preparation.Meanwhile,the particle diameter of the plasma-prepared catalyst is 3.8 nm, but the particle diameter of the conventional catalyst is 20.4 nm.Such plasma-prepared Pd/Al2O3 catalyst shows a higher activity for catalytic combustion of methane than the conventional catalyst.Methane conversion reaches 90% at 400 ℃, but it is only near 30% for the conventional catalyst at the same temperature.

Key words: 等离子体, 甲烷催化燃烧, Pd/Al2O3催化剂