气液冷等离子体多相反应器基础研究与应用进展

doi:10.11949/0438-1157.20190698

摘要/Abstract

摘要：

等离子体作为物质存在的一种基本形态，因其特有的高活性而不同于固、液、气三种形态，逐渐应用于多个领域，并发展成了一门新兴学科。由于冷等离子体参与的气液化学反应能产生更多的活性物质，而且液体的流动性能够强化活性物质的传递，因此，气体放电产生的冷等离子体与液相反应在许多领域表现出重要的应用价值，更具有探究意义。综述了几种冷等离子体的放电形式以及表征技术，重点阐述了气液冷等离子体多相反应器的不同结构以及应用，并对气液冷等离子体技术发展进行了展望。

关键词: 冷等离子体, 气液两相流, 多相反应器, 传质, 气液反应

Abstract:

As a basic form of the substance, plasma is different from solid, liquid and gas due to its unique high activity. It has gradually been applied in many fields and has developed into a new discipline. The gas-liquid chemical reaction involving the non-thermal plasma could generate more reactive oxygen species, and the fluidity of liquid could enhance the mass transfer in the gas-liquid non-thermal plasma reactors. So, the reaction of non-thermal plasma generated by the gas discharge and liquid phase has an important application value in many fields. The discharge patterns and characterization techniques of various non-thermal plasmas are reviewed. Furthermore, the different structures and applications of gas-liquid non-thermal plasma multiphase reactors are highlighted, and then the development of gas-liquid non-thermal plasma is prospected.

Key words: non-thermal plasma, gas-liquid two-phase flow, multiphase reactor, mass transfer, gas-liquid reaction

中图分类号:

TQ 028.8

蔡勇, 梁闯, 罗勇, 初广文, 苏梦军, 孙宝昌, 陈建峰. 气液冷等离子体多相反应器基础研究与应用进展[J]. 化工学报, 2019, 70(10): 3847-3858.

Yong CAI, Chuang LIANG, Yong LUO, Guangwen CHU, Mengjun SU, Baochang SUN, Jianfeng CHEN. [J]. CIESC Journal, 2019, 70(10): 3847-3858.

图/表 7

图1 气液等离子体传递与反应特性的测量系统、浓度场分布、氧气放电过程发射光谱图

Fig.1 Schematic drawing of reactive-PLIF measurement equipment(a), diagram of concentration field distribution(b), temporally averaged emission spectra observed in oxygen discharge(c)

图2 气液分层式冷等离子体反应器

Fig.2 Gas-liquid stratified non-thermal plasma reactor

图3 鼓泡式冷等离子体反应器

Fig.3 Bubbling non-thermal plasma reactor

图4 雾化式冷等离子反应器

Fig.4 Spray non-thermal plasma reactor

图5 气液冷等离子体反应器分解水中有毒有机物的相对能量效率

Fig.5 Relative energy efficiencies of gas-liquid non-thermal plasma reactors for decomposing toxic organic compounds in water

图6 冷等离子体反应器能效对比

Fig.6 Energy efficiency comparisons of various plasma reactors

图7 各种活性粒子的渗透深度

Fig.7 Penetration depth of various reactive species

参考文献 77

1	Tonks L , Langmuir I . A general theory of the plasma of an arc[J]. Physical Review, 1929, 34: 876.
2	颜彬航, 卢巍, 冯雪兰, 等 . 等离子体多相反应器基础研究和过程强化[J]. 化学反应工程与工艺, 2013, 29(3): 214-221.
	Yan B H , Lu W , Feng X L , et al . Fundamental study and process intensification in plasma multiphase reactors[J]. Chemical Reaction Engineering and Technology, 2013, 29(3): 214-221.
3	沙振舜 . 等离子体自传[M]. 南京: 南京大学出版社, 2016.
	Sha Z S . Autobiography of Plasma[M]. Nanjing: Nanjing University Press, 2016.
4	张秀玲, 于淼, 翟林燕 . 气液等离子体技术研究进展[J]. 化工进展, 2010, 29(11): 2034-2038.
	Zhang X L , Yu M , Zhai L Y . Advances in gas-liquid plasma technology[J]. Chemical Industry and Engineering Progress, 2010, 29(11): 2034-2038.
5	Lieberman M A , Lichtenberg A J . Principles of Plasma Discharges and Materials Processing[M]. New York: John Wiley & Sons, 2005.
6	杨培强, 王菲鹿, 赵刚 . 与天体物理相关的光电离等离子体的实验室研究[J]. 物理, 2011, 40(1): 23-27.
	Yang P Q , Wang F L , Zhao G . Laboratory studies of photoionized plasma related to astrophysics[J]. Pysics, 2011, 40(1): 23-27.
7	宋一中, 李亮 . 激光诱导Al等离子体连续辐射的时间分布[J]. 光学学报, 2001, 21(4): 404-409.
	Song Y Z , Li L . Time distribution of the continuum radiation in the plasma induced by laser ablating Al[J]. Acta Optica Sinica, 2001, 21(4): 404-409.
8	Sydorenko D , Kaganovich I D , Ventzek P L G , et al . Excitation of a global plasma mode by an intense electron beam in a DC discharge[J]. Physics of Plasmas, 2018, 25(1): 011606.
9	Dong S Y , Guo S M , Wen D , et al . Investigation on the mode of AC discharge in H₂O affected by temperature[J]. Plasma Science and Technology, 2018, 20: 045041.
10	Takashima K , Yin Z , Adamovich I V . Measurements and kinetic modeling of energy coupling in volume and surface nanosecond pulse discharges[J]. Plasma Sources Science and Technology, 2013, 22: 015013.
11	邵涛, 严萍 . 大气压气体放电及其等离子体应用[M]. 北京: 科学出版社, 2015.
	Shao T , Yan P . Atmospheric Pressure Gas Discharge and Applications[M]. Beijing: Science Press, 2015.
12	Akishev Y , Goossens O , Callebaut T , et al . The influence of electrode geometry and gas flow on corona-to-glow and glow-to-spark threshold currents in air[J]. Journal of Physics D: Applied Physics, 2001, 34: 2875.
13	张禹涛, 马腾才, 任春生, 等 . 空气中交流针-板大气压辉光放电[J]. 核聚变与等离子体物理, 2006, 26(4): 323-326.
	Zhang Y T , Ma T C , Ren C S , et al . AC pin-to-plate electrode atmospheric pressure glow discharge in air[J]. Nuclear Fusion and Plasma Physics, 2006, 26 (4): 323-326.
14	许根慧, 姜恩永, 盛京 . 等离子体技术与应用[M]. 北京: 化学工业出版社, 2006.
	Xu G H , Jiang E Y , Sheng J . Plasma Technology and Applications[M]. Beijing: Chemical Industry Press, 2006.
15	Chirokov A , Gutsol A , Fridman A , et al . A study of two-dimensional microdischarge pattern formation in dielectric barrier discharges[J]. Plasma Chemistry and Plasma Processing, 2006, 26(2): 127-135.
16	Koichi T , Yuki H , Kaname A , et al . Influence of electrode configuration on ozone synthesis and microdischarge property in dielectric barrier discharge reactor[J]. Vacuum, 2008, 83(1): 128-132.
17	池凌飞, 林揆训, 姚若河, 等 . Langmuir单探针诊断射频辉光放电等离子体及其数据处理[J]. 物理学报, 2001, 50(7): 1313-1317.
	Chi L F , Lin K X , Yao R H , et al . Diagnostic of RF plasma by using Langmuir probe and its numerical processing[J]. Acta Physica Sinica, 2001, 50(7): 1313-1317.
18	黄建军, 余建华, Teuner D . 射频放电阻抗测量用于等离子体诊断研究[J]. 物理学报, 2001, 50(12): 2403-2407.
	Huang J J , Yu J H , Teuner D . Plasma diagnosis of RF discharge by using impedance measurement[J]. Acta Physica Sinica, 2001, 50(12): 2403-2407.
19	Paranjpe A P , McVittie J P , Self S A . A tuned Langmuir probe for measurements in RF glow discharges[J]. Journal of Applied Physics, 1990, 67(11): 6718.
20	赵岩, 柏洋, 金成刚, 等 . 激光诱导荧光在低温等离子体诊断中的应用[J]. 激光与红外, 2012, 42(4): 365-371.
	Zhao Y , Bai Y , Jin C G , et al . Application of laser-induced fluorescence in the low-temperature plasma diagnosis[J]. Laser & Infrared, 2012, 42(4): 365-371.
21	Coburn J W , Chen M . Optical emission spectroscopy of reactive plasmas: a method for correlating emission intensities to reactive particle density[J]. Journal of Applied Physics, 1980, 51(6): 3134.
22	李兴文, 魏文赋, 吴坚, 等 . 激光诱导等离子体光学诊断方法研究综述[J]. 高电压技术, 2015, 41(6): 1788-1797.
	Li X W , Wei W F , Wu J , et al . Review of optical diagnosis methods for the laser produced plasmas[J]. High Voltage Engineering, 2015, 41(6): 1788-1797.
23	刘忠伟, 陈强, 王正铎, 等 . 大气压射流等离子体中O及OH自由基的发射光谱在线诊断[J]. 强激光与粒子束, 2010, 22(10): 2461-2464.
	Liu Z W , Chen Q , Wang Z D , et al . On-line diagnosis of O and OH radicals in atmospheric pressure plasma jet by optical emission spectroscopy[J]. High Power Laser and Particle Beams, 2010, 22(10): 2461.
24	Brühl S P , Russell M W , Gómez B J , et al . A study by emission spectroscopy of the active species in pulsed DC discharges[J]. Journal of Physics D: Applied Physics, 1997, 30: 2917.
25	吴蓉, 李燕, 朱顺官, 等 . 等离子体电子温度的发射光谱法诊断[J]. 光谱学与光谱分析, 2008, (4): 731-735.
	Wu R , Li Y , Zhu S G , et al . Emission spectroscopy diagnostics of plasma electron temperature[J]. Spectroscopy and Spectral Analysis, 2008, 28(4): 731-735.
26	Donnelly V M . Plasma electron temperatures and electron energy distributions measured by trace rare gases optical emission spectroscopy[J]. Journal of Physics D: Applied Physics, 2004, 37: 217.
27	刘峰 . 脉冲电晕放电与直流辉光放电中OH自由基等活性物种的光谱诊断[D]. 大连: 大连理工大学, 2008.
	Liu F . The spectroscopy diagnosis of OH radical and active species produced in pulsed corona discharge and DC glow discharge[D]. Dalian : Dalian University of Technology, 2008.
28	高亮 . 沿面放电等离子体OH自由基激光诱导荧光光谱诊断及生物学效应实验研究[D]. 大连: 大连理工大学, 2017.
	Gao L . Study on OH radical and its biological effect in surface discharge plasma using laser induced fluorescence spectroscopic technique[D]. Dalian: Dalian University of Technology, 2017.
29	冯雪兰, 程易 . 气液等离子体过程强化技术及其在高级氧化过程的应用[J]. 化工进展, 2018, (4): 1247-1256.
	Feng X L , Cheng Y . Process intensification technique of gas-liquid plasma and its application in advanced oxidation processes[J]. Chemical Industry and Engineering Progress, 2018, (4): 1247-1256.
30	Feng X L , Yan B H , Lu W , et al . Visualization of coupled mass transfer and reaction in a gas-liquid dielectric barrier discharge reactor[J]. Chemical Engineering Journal, 2014, 245: 47-55.
31	Feng X L , Shao T , Wang W T , et al . Visualization of in situ oxidation process between plasma and liquid phase in two dielectric barrier discharge plasma reactors using planar laser induced fluorescence technique[J]. Plasma Chemistry and Plasma Processing, 2012, 32(6): 1127-1137.
32	吴淑群, 董熙, 裴学凯, 等 . 基于激光诱导荧光法诊断大气压低温等离子体射流中OH自由基和O原子的时空分布[J]. 电工技术学报, 2017, 32(8): 82-94.
	Wu S Q , Dong X , Pei X K , et al . Laser induced fluorescence diagnostics of the temporal and spatial distribution of OH radicals and O atom in a low temperature plasma jet at atmospheric pressure[J]. Transactions of China Electrotechnical Society, 2017, 32(8): 82-94.
33	Shiota H , Itabashi H , Satoh K , et al . Phenol decomposition by pulsed discharge plasma above a water surface in oxygen and argon atmosphere[J]. Electrical Engineering in Japan, 2013, 184(1): 1-9.
34	Sun B , Aye N N , Gao Z Y , et al . Characteristics of gas-liquid pulsed discharge plasma reactor and dye decoloration efficiency[J]. Journal of Environmental Sciences, 2012, 24(5): 840-845.
35	Grabowski L R , van Veldhuizen E M , Pemen A J M , et al . Corona above water reactor for systematic study of aqueous phenol degradation[J]. Plasma Chemistry and Plasma Processing, 2006, 26(1): 3-17.
36	Wang X , Li Z , Lan T , et al . Sulfite oxidation in seawater flue gas desulfurization by plate falling film corona-streamer discharge[J]. Chemical Engineering Journal, 2013, 225: 16-24.
37	Wang B W , Dong B , Xu M , et al . Degradation of methylene blue using double-chamber dielectric barrier discharge reactor under different carrier gases[J]. Chemical Engineering Science, 2017, 168(4): 90-100.
38	Shang K F , Zhang Q , Lu N , et al . Evaluation on a double-chamber gas-liquid phase discharge reactor for benzene degradation[J]. Plasma Science and Technology, 2019, 21: 075502.
39	王保伟, 王超, 徐艳, 等 . 介质阻挡放电等离子体反应器降解盐酸四环素[J]. 化工学报, 2018, 69(4): 1687-1694.
	Wang B W , Wang C , Xu Y , et al . Degradation of tetracycline hydrochloride using dielectric barrier discharge plasma reactor[J]. CIESC Journal, 2018, 69(4): 1687-1694.
40	Zhang Y , Zhou M , Lei L . Degradation of 4-chlorophenol in different gas-liquid electrical discharge reactors[J]. Chemical Engineering Journal, 2007, 132(1/2/3): 325-333.
41	Homma H , Katayama H , Yasuoka K . Pulsed dielectric barrier discharge of argon gas in gas-liquid two-phase flow[J]. IEEE Transactions on Plasma Science, 2008, 36(4): 1344-1345.
42	Njatawidjaja E , Sugiarto A T , Ohshima T , et al . Decoloration of electrostatically atomized organic dye by the pulsed streamer corona discharge[J]. Journal of Electrostatics, 2005, 63(5): 353-359.
43	Panorel I , Kornev I , Hatakka H , et al . Pulsed corona discharge for degradation of aqueous humic substances[J]. Water Science & Technology Water Supply, 2011, 11(2): 238-245.
44	Kobayashi T , Sugai T , Handa T , et al . The effect of spraying of water droplets and location of water droplets on the water treatment by pulsed discharge in air[J]. IEEE Transactions on Plasma Science, 2010, 38(10): 2675-2680.
45	Malik M A . Water purification by plasmas: which reactors are most energy efficient[J]. Plasma Chemistry and Plasma Processing, 2010, 30(1): 21-31.
46	Stratton G R , Bellona C L , Dai F , et al . Plasma-based water treatment: conception and application of a new general principle for reactor design[J]. Chemical Engineering Journal, 2015, 273: 543-550.
47	Adamovich I , Baalrud S D , Bogaerts A , et al . The 2017 plasma roadmap: low temperature plasma science and technology[J]. Journal of Physics D: Applied Physics, 2017, 50: 323001.
48	Chen C , Liu D X , Liu Z C , et al . A model of plasma-biofilm and plasma-tissue interactions at ambient pressure[J]. Plasma Chemistry and Plasma Processing, 2014, 34(3): 403-441.
49	Doubla A , Laminsi S , Nzali S , et al . Organic pollutants abatement and biodecontamination of brewery effluents by a non-thermal quenched plasma at atmospheric pressure[J]. Chemosphere, 2007, 69(2): 332-337.
50	Ma Y , Zhang G J , Shi X M , et al . Chemical mechanisms of bacterial inactivation using dielectric barrier discharge plasma in atmospheric air[J]. IEEE Transactions on Plasma Science, 2008, 36(4): 1615-1620.
51	郑超 . 低温等离子体和脉冲电场灭菌技术[D]. 杭州: 浙江大学, 2013.
	Zheng C . Non-thermal plasma and pulsed electric field induced disinfection[D]. Hangzhou: Zhejiang University, 2013.
52	Fridman G , Brooks A D , Balasubramanian M , et al . Comparison of direct and indirect effects of non-thermal atmospheric-pressure plasma on bacteria[J]. Plasma Processes and Polymers, 2007, 4(4): 370-375.
53	巩建英 . 辉光放电等离子体技术处理难降解有机污染物及机理研究[D]. 上海: 上海交通大学, 2008.
	Gong J Y . Efficient degradation of organic pollutions by contact glow discharge and its mechanism study[D]. Shanghai : Shanghai Jiaotong University, 2008.
54	Stratton G R , Dai F , Bellona C L , et al . Plasma-based water treatment: efficient transformation of perfluoroalkyl substances in prepared solutions and contaminated groundwater[J]. Environmental Science & Technology, 2017, 51(3): 1643-1648.
55	Zhang H , Yang L , Yu Z , et al . Inactivation of microcystis aeruginosa by DC glow discharge plasma: Impacts on cell integrity, pigment contents and microcystins degradation[J]. Journal of Hazardous Materials, 2014, 268: 33-42.
56	江波 . 渣油加氢技术进展[J]. 中外能源, 2012, 17(9): 64-68.
	Jiang B . Advances in residuum hydrofining technology[J]. Sino-Global Energy, 2012, 17(9): 64-67.
57	于红, 凌伟, 赵明, 等 . 介质阻挡放电等离子体与重油反应的研究[J]. 核聚变与等离子体物理, 2012, 32(3): 271-277.
	Yu H , Ling W , Zhao M , et al . Reaction of dielectric barrier discharge plasma with crude oil[J]. Nuclear Fusion and Plasma Physics, 2012, 32(3): 271-277.
58	Hao H G , Wu B S , Yang J L , et al . Non-thermal plasma enhanced heavy oil upgrading[J]. Fuel, 2015, 149(1): 162-173.
59	刘淑鹤, 方向晨, 张喜文, 等 . 丙烷脱氢催化反应机理及动力学研究进展[J]. 化工进展, 2009, 28(2): 259-266.
	Liu S H , Fang X C , Zhang X W , et al . Advances in catalytic mechanisms and kinetics of propane dehydrogenation[J]. Chemical Industry and Engineering Progress, 2009, 28(2): 259-266.
60	崔艳宏, 王超, 王安杰, 等 . 二氧化碳和甲醇氢等离子体催化反应合成碳酸二甲酯[J]. 天然气化工, 2016, 41(3): 48-51.
	Cui Y H , Wang C , Wang A J , et al . Hydrogen plasma catalytic synthesis of dimethyl carbonate from carbon dioxide and methanol[J]. Natural Gas Chemical Industry, 2016, 41(3): 48-51.
61	王莉萍, 廖瑞瑞, 陶丽红, 等 . 辉光放电电解等离子体引发合成高吸水性树脂[J]. 化学通报, 2013, 76(7): 635-639.
	Wang L P , Liao R R , Tao L H , et al . Synthesis of composite superabsorbent resin by using glow-discharge electrolysis plasma[J]. Chemistry, 2013, 76(7): 635-639.
62	Yan Z C , Li C , Lin W H . Hydrogen generation by glow discharge plasma electrolysis of methanol solutions[J]. International Journal of Hydrogen Energy, 2009, 34(1): 48-55.
63	Hawtof R , Ghosh S , Guarr E , et al . Catalyst-free, highly selective synthesis of ammonia from nitrogen and water by a plasma electrolytic system[J]. Science Advances, 2019, 5(1): 5778.
64	Chen Q , Li J S , Li Y F . A review of plasma liquid interactions for nanomaterial synthesis[J]. Journal of Physics D: Applied Physics, 2015, 48: 424005.
65	Mariotti D , Patel J , Švrček V , et al . Plasma-liquid interactions at atmospheric pressure for nanomaterials synthesis and surface engineering[J]. Plasma Processes and Polymers, 2012, 9: 1074-1085.
66	Kaneko T , Baba K , Harada T , et al . Novel gas-liquid interfacial plasmas for synthesis of metal nanoparticles[J]. Plasma Processes and Polymers, 2009, 6: 713-718.
67	Ananth A , Mok Y S . Synthesis of RuO₂ nanomaterials under dielectric barrier discharge plasma at atmospheric pressure: influence of substrates on the morphology and application[J]. Chemical Engineering Journal, 2014, 239(1): 290-298.
68	Lin L L , Starostin S A , Li S R , et al . Synthesis of yttrium oxide nanoparticles via a facile microplasma-assisted process[J]. Chemical Engineering Science, 2018, 178(16): 157-166.
69	Brettholle M , Hoefft O , Klarhöfer L , et al . Plasma electrochemistry in ionic liquids: deposition of copper nanoparticles[J]. Physical Chemistry Chemical Physics, 2010, 12(8): 1750-1755.
70	Qin W , Cheng S M , Zhou B , et al . Controllable synthesis of silicon nano-particles using a one-step PECVD-ionic liquid strategy[J]. Journal of Materials Chemistry A, 2015, 3(19): 10233-10237.
71	Zhao H , Shao L , Chen J F . High-gravity process intensification technology and application[J]. Chemical Engineering Journal, 2010, 156(3): 588-593.
72	陈建峰, 邹海魁, 刘润静, 等 . 超重力反应沉淀法合成纳米材料及其应用[J]. 现代化工, 2001, (9): 9-12.
	Chen J F , Zou H K , Liu R J , et al . Synthesis of nanomaterials by high gravity reactive precipitation method and applications[J]. Modern Chemical Industry, 2001, (9): 9-12.
73	初广文, 罗勇, 邹海魁, 等 . 超重力反应强化技术在酸性气体尾气处理中的工业应用[J]. 化学反应工程与工艺, 2013, 29(3): 193-198.
	Chu G W , Luo Y , Zou H K , et al . Reaction process intensification: applications of acidic tail-gas treatment by high gravity technology[J]. Chemical Reaction Engineering and Technology, 2013, 29(3): 193-198.
74	Cai Y , Luo Y , Sun B C , et al . A novel plasma-assisted rotating disk reactor: enhancement of degradation efficiency of rhodamine B[J]. Chemical Engineering Journal, 2019, 337: 119897.
75	Bruggeman P , Leys C . Non-thermal plasmas in and in contact with liquids[J]. Journal of Physics D: Applied Physics, 2015, 42(5): 053001.
76	Samukawa S , Hori M , Rauf S , et al . The 2012 plasma roadmap[J]. Journal of Physics D: Applied Physics, 2012, 45(25): 253001.
77	Foster, John E . Plasma-based water purification: challenges and prospects for the future[J]. Physics of Plasmas, 2017, 24(5): 055501.

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