木质素慢速热解机理

doi:10.3969/j.issn.0438-1157.2013.05.035

化工学报 ›› 2013, Vol. 64 ›› Issue (5): 1757-1765.DOI: 10.3969/j.issn.0438-1157.2013.05.035

木质素慢速热解机理

程辉^1,2, 余剑¹, 姚梅琴^1,3, 许光文¹

1. 中国科学院过程工程研究所, 多相复杂系统国家重点实验室, 北京 100190;
2. 中海油气电集团国际贸易有限公司, 北京100027;
3. 中国科学院研究生院, 北京 100039

收稿日期:2012-08-24 修回日期:2012-10-31 出版日期:2013-05-05 发布日期:2013-05-05
通讯作者: 余剑,许光文
作者简介:程辉(1984-),男,硕士研究生。
基金资助:
国家自然科学基金项目(21106156,21006110)。

Mechanism analysis of lignin slow pyrolysis

CHENG Hui^1,2, YU Jian¹, YAO Meiqin^1,3, XU Guangwen¹

1. Institute of Process Engineering, China Academy of Science, Beijing 100190, China;
2. CNOOC Gas & Power Group International Trade Company, Beijing 100027, China;
3. Graduate University of Chinese Academy of Sciences, Beijing 100039, China

Received:2012-08-24 Revised:2012-10-31 Online:2013-05-05 Published:2013-05-05
Supported by:
supported by the National Natural Science Foundation of China(21106156,21006110).

摘要/Abstract

摘要： 利用热重考察了不同升温速率下木质素的热解特性,结合红外光谱对木质素热解的不同阶段生成的半焦的表征结果,分析了木质素在慢速升温条件下的热裂解机理,表明:木质素的热解是一个旧键断裂挥发、新键重组的过程。热解过程随着反应时间的推移依次分为水分挥发、支链断裂重组或挥发和芳环缩聚成碳3个阶段。采用Flynn-Wall-Ozawa方法,根据不同升温速率下测得的失重速率变化求算后两个阶段的活化能,结果分别为64 kJ·mol^-1和132 kJ·mol^-1,进一步证明了木质素热解的分段特征,并表明芳环缩聚成碳所需活化能远大于与苯环相连的支链断裂所需的能量。

关键词: 热重分析, 木质素, 热解机理, 红外分析

Abstract: The characteristics of lignin pyrolysis was investigated by TG at different heating rate, combined with FTIR characterization of the chars from different stages of slow pyrolysis of lignin to analyze lignin pyrolysis mechanism at slow heating rate.The results show that pyrolysis of lignin is a process involving breakage of old chemical branched chains and recombination of new branched chains.With time extending i.e.temperature rising, there are three successive stages in process of lignin pyrolysis:dewatering, breakage-recombination-volatilization of branched chains and polymerization of aromatic rings and formation of carbon.Based on the weight loss rate at different heating rates, according to the Flynn-Wall-Ozawa equation, the calculation of kinetic parameters resulted in activation energies of 64 kJ穖ol^-1 and 132 kJ穖ol^-1 for the latter two pyrolysis stages, respectively.This indicates further that the pyrolysis of lignin carried out in different stages and the breakage of the branded chains was easier than the polymerization of aromatic rings.

Key words: thermo gravimetric analysis, lignin pyrolysis, mechanism, FTIR analysis

中图分类号:

TQ351.1

程辉, 余剑, 姚梅琴, 许光文. 木质素慢速热解机理[J]. 化工学报, 2013, 64(5): 1757-1765.

CHENG Hui, YU Jian, YAO Meiqin, XU Guangwen. Mechanism analysis of lignin slow pyrolysis[J]. CIESC Journal, 2013, 64(5): 1757-1765.

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木质素慢速热解机理

Mechanism analysis of lignin slow pyrolysis

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