季铵盐链长及用量对CnTA+/蒙脱石纳米复合物吸附PAEs的影响

doi:10.11949/j.issn.0438-1157.20141376

化工学报 ›› 2015, Vol. 66 ›› Issue (3): 1042-1050.DOI: 10.11949/j.issn.0438-1157.20141376

季铵盐链长及用量对C_nTA⁺/蒙脱石纳米复合物吸附PAEs的影响

李莉^1,2, 孙红娟^1,2, 彭同江^1,2

1 西南科技大学固体废物处理与资源化省部共建教育部重点实验室, 四川绵阳 621010;
2 西南科技大学矿物材料及应用研究所, 四川绵阳 621010

收稿日期:2014-09-15 修回日期:2014-11-15 出版日期:2015-03-05 发布日期:2015-03-05
通讯作者: 孙红娟
基金资助:
国家自然科学基金项目(41372052);四川省教育厅项目(11ZB103)。

Effect of chain length and amount of quaternary ammonium salts on C_nTA⁺/montmorillonite nanocomposites adsorption of PAEs

LI Li^1,2, SUN Hongjuan^1,2, PENG Tongjiang^1,2

1 Key Laboratory of Ministry of Education for Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China;
2 Institute of Mineral Materials & Application, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China

Received:2014-09-15 Revised:2014-11-15 Online:2015-03-05 Published:2015-03-05
Supported by:
supported by the National Natural Science Foundation of China (41372052) and the Project in Sichuan Province Department of Education (11ZB103).

摘要/Abstract

摘要：

用具有相同结构但不同烷基碳链长度的系列季铵盐制得C_nTA⁺/蒙脱石纳米复合物,并对水溶液中邻苯二甲酸酯进行吸附实验。探讨了季铵盐烷基碳链链长和用量对制得的C_nTA⁺/蒙脱石纳米复合物吸附水溶液中PAEs效果的影响。结果表明:C_nTA⁺/蒙脱石纳米复合物能有效地吸附溶液中的PAEs,季铵盐烷基碳链链长及用量均对C_nTA⁺/蒙脱石纳米复合物的吸附效果产生影响。当季铵盐用量较低时,随着季铵盐烷基链长的增加,PAEs的吸附去除率增加;增大季铵盐用量,随着季铵盐烷基链长的增加,PAEs的吸附去除率先增大后减小。

关键词: 季铵盐, C_nTA⁺/蒙脱石纳米复合物, 纳米结构, 邻苯二甲酸酯, 水溶液, 吸附

Abstract:

Quaternary ammonium salts cation and montmorillonite nanocomposites (C_nTA⁺/montmorillonite nanocomposites) were prepared from a series of quaternary ammonium salts with the same structure but different alkyl carbon chain lengths to adsorb phthalate ester (PAEs) in aqueous solution. The effects of C_nTA⁺/montmorillonite nanocomposites prepared with different alkyl carbon chain lengths and amounts of quaternary ammonium salts on PAEs adsorption efficiency were investigated. C_nTA⁺/montmorillonite nanocomposites as-prepared could adsorb PAEs effectively. Alkyl carbon chain length and amount of quaternary ammonium salts both affected adsorption results. At a smaller amount of quaternary ammonium salts, the adsorption removal of PAEs increased with increasing alkyl chain length of quaternary ammonium salts. However, at a larger amount of quaternary ammonium salts, the adsorption removal of PAEs increased firstly and then decreased with increasing alkyl chain length of quaternary ammonium salts.

Key words: quaternary ammonium salts, C_nTA⁺/montmorillonite nanocomposites, nanostructure, phthalic esters, aqueous solution, adsorption

中图分类号:

X705
X506

李莉, 孙红娟, 彭同江. 季铵盐链长及用量对C_nTA⁺/蒙脱石纳米复合物吸附PAEs的影响[J]. 化工学报, 2015, 66(3): 1042-1050.

LI Li, SUN Hongjuan, PENG Tongjiang. Effect of chain length and amount of quaternary ammonium salts on C_nTA⁺/montmorillonite nanocomposites adsorption of PAEs[J]. CIESC Journal, 2015, 66(3): 1042-1050.

参考文献 30

[1]	Zhou Q, Frost R L, He H, Xi Y. Changes in the surfaces of adsorbed p-nitrophenol on methyltrioctadecylammonium bromide organoclay—an XRD, TG, and infrared spectroscopic study [J]. Journal of Colloid and Interface Science, 2007, 314(2): 405-414
[2]	Beall G W. The use of organo-clays in water treatment [J]. Applied Clay Science, 2003, 24(1/2): 11-20
[3]	Fuller M, Smith J A, Burns S E. Sorption of nonionic organic solutes from water to tetraalkylammonium bentonites: mechanistic considerations and application of the Polanyi-Manes potential theory [J]. Journal of Colloid and Interface Science, 2007, 313(2): 405-413
[4]	Xi Y, Frost R L, He H. Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyl trimethyl, dialkyl dimethyl, and trialkyl methyl ammonium bromides [J]. Journal of Colloid and Interface Science, 2007, 305(1): 150-158
[5]	Ahmaruzzaman M. Adsorption of phenolic compounds on low-cost adsorbents: a review [J]. Advances in Colloid and Interface Science, 2008, 143(1/2): 48-67
[6]	Yui T, Fujii S, Matsubara K, Sasai R, Tachibana H, Yoshida H, Takagi K, Inoue H. Intercalation of a surfactant with a long polyfluoroalkyl chain into a clay mineral: unique orientation of polyfluoroalkyl groups in clay layers [J]. Langmuir, 2013, 29(34): 10705-10712
[7]	Zhu J, Shen W, Ma Y, Ma L, Zhou Q, Yuan P. The influence of alkyl chain length on surfactant distribution within organo- montmorillonites and their thermal stability [J]. Journal of Thermal Analysis and Calorimetry, 2012, 109(1): 301
[8]	Chun Y, Sheng G, Boyd S A. Sorptive characteristics of tetraakylammonium-exchanged smectite clays [J]. Clays and Clay Minerals, 2003, 51(4): 415-420
[9]	Stales C A, Peterson D R, Parkerton T F, Adams W J. The environmental fate of phthalate esters: a literature review [J]. Chemosphere, 1997, 35(4): 667-749
[10]	Giam C S, Atlas E, Powers Jr M A, Leonard J E. Phthalic Acid Esters//Anthropogenic Compounds [M]. Berlin: Springer Verlag Berlin Heidelberg, 1984: 67-142
[11]	Magdouli S, Daghrir R, Brar S K, Drogui P, Tyagi R D. Di 2-ethylhexylphtalate in the aquatic and terrestrial environment: a critical review [J]. Journal of Environmental Management, 2013, 127: 36-49
[12]	Matsumoto M, Hirata-Koizumi M, Ema M. Potential adverse effects of phthalic acid esters on human health: a review of recent studies on reproduction [J]. Regulatory Toxicology and Pharmacology, 2008, 50(1): 37-49
[13]	Martino Andrade A J, Chahoud I. Reproductive toxicity of phthalate esters [J]. Molecular Nutrition & Food Research, 2010, 54(1): 148-157
[14]	Julinová M, Slavík R. Removal of phthalates from aqueous solution by different adsorbents: a short review [J]. Journal of Environmental Management, 2012, 94(1): 13-24
[15]	Chen Yancui (陈彦翠), Sun Hongjuan(孙红娟),Peng Tongjiang(彭同江). Study on montmorillonite intercalated by a series of quaternary ammonium [J]. Non-Metallic Mines(非金属矿), 2008, 31(3): 18-21
[16]	Favre G L H. Organo-bentonites with quaternary alkylammonium ions [J]. Clay Minerals, 1991, 26: 19-32
[17]	Moraru V N. Structure formation of alkylammonium montmorillonites in organic media [J]. Applied Clay Science, 2001, 19(1-6): 11-26
[18]	Heinz H, Vaia R A, Krishnamoorti R, Farmer B L. Self-assembly of alkylammonium chains on montmorillonite: effect of chain length, head group structure, and cation exchange capacity [J]. Chemistry of Materials, 2007, 19(1): 59-68
[19]	Kwolek T, Hodorowicz M, Stadnicka K, Czapkiewicz J. Adsorption isotherms of homologous alkyldimethyl-benzylammonium bromides on sodium montmorillonite [J]. Journal of Colloid and Interface Science, 2003, 264(1): 14-19
[20]	Zhu Jianxi(朱建喜), He Hongping(何宏平), Guo Jiugao(郭九皋), Yang Dan(杨丹), Xie Xiande(谢先德). Study on the relationship between the arrangement models of organic cation in HDTMA+- montomorillonite and its theoretic sizes [J]. Journal of Mineralogy and Petrology(矿物岩石), 2003, 23(4): 1-4
[21]	Ong L K, Soetaredjo F E, Kurniawan A, Ayucitra A, Liu J, Ismadji S. Investigation on the montmorillonite adsorption of biocidal compounds incorporating thermodynamical-based multicomponent adsorption isotherm [J]. Chemical Engineering Journal, 2014, 241: 9-18
[22]	Venkata Mohan S, Shailaja S, Rama Krishna M, Sarma P N. Adsorptive removal of phthalate ester (di-ethyl phthalate) from aqueous phase by activated carbon: a kinetic study [J]. Journal of Hazardous Materials, 2007, 146(1/2): 278-282
[23]	Peng Changjun(彭昌军), Jiang Xiuli(姜秀丽), Ji Hongfang(计红芳), Wang Yuanpeng(王远鹏), Ouyang Tong(欧阳通), Li Qingbiao(李清彪). Adsorption behavior of Fe-Mn binary oxide towards As(Ⅲ) and As(Ⅴ) and its application in biogas slurry [J].CIESC Journal (化工学报), 2014, 65(5): 1848-1855
[24]	Xu Xiaoyu(徐晓宇), Sun Yue(孙悦), Shen Jian(沈健), Zhai Yulong(翟玉龙). Adsorption behavior of basic nitrides in model oil on HY and USY [J]. Chemical Industry and Engineering Progress (化工进展), 2014, 33(4): 1035-1040
[25]	Serodio P, Nogueira J. Considerations on ultra-trace analysis of phthalates in drinking water [J]. Water Research, 2006, 40(13): 2572-2582
[26]	Nguyen T H, Goss K U, Ball W P. Polyparameter linear free energy relationships for estimating the equilibrium partition of organic compounds between water and the natural organic matter in soils and sediments [J]. Environmental Science & Technology, 2005, 39(4): 913-924
[27]	Wang J, Zhou Y, Li A, Xu L. Adsorption of humic acid by bi-functional resin JN-10 and the effect of alkali-earth metal ions on the adsorption [J]. Journal of Hazardous Materials, 2010, 176(1/2/3): 1018-1026
[28]	Xu Zhengwen(许正文), Zhao Yunlong(赵云龙), Shi Jing(史静), Lu Jiangang(陆建刚), Cheng Ling(承玲), Li Saichao(李赛超), Liu Cong(刘聪). Removal of mono-n-butyl phthalate in aqueous phase by bifunctional polymeric adsorbent NXD-2 [J]. CIESC Journal (化工学报), 2014, 65(4): 1462-1468
[29]	Tang Yini(唐旖旎), Wu Pingxiao(吴平霄), Hou Yakun(侯雅琨). Adsorption properties of salmon sperm DNA on organic and inorganic modified montmorillonite [J]. Journal of Functional Materials(功能材料), 2012, 43(13): 1712-1717
[30]	Liu Zhiping(刘芝平), Zhang Qiangqiang(张嫱嫱), Ma Jinghong(马静红), Li Ruifeng(李瑞丰). Adsorption of n-paraffins on mesoporous 5A zeolites [J]. CIESC Journal (化工学报), 2014, 65(3): 934-941

季铵盐链长及用量对C_nTA⁺/蒙脱石纳米复合物吸附PAEs的影响

Effect of chain length and amount of quaternary ammonium salts on C_nTA⁺/montmorillonite nanocomposites adsorption of PAEs

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季铵盐链长及用量对CnTA+/蒙脱石纳米复合物吸附PAEs的影响

Effect of chain length and amount of quaternary ammonium salts on CnTA+/montmorillonite nanocomposites adsorption of PAEs

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季铵盐链长及用量对C_nTA⁺/蒙脱石纳米复合物吸附PAEs的影响

Effect of chain length and amount of quaternary ammonium salts on C_nTA⁺/montmorillonite nanocomposites adsorption of PAEs