有机-无机杂化钙钛矿太阳能电池的研究进展

doi:10.11949/j.issn.0438-1157.20160996

摘要/Abstract

摘要：

有机-无机杂化钙钛矿材料不仅具有较高的光吸收能力和载流子迁移率，同时具有双极性特征以及合成方法简单等优点，目前已成为最有发展前途的太阳能电池材料，其光电转化效率在7年内从3.8%迅速提升到20%以上，并有进一步提高的空间。简单介绍了钙钛矿材料的结构与性质，综述了钙钛矿太阳能电池的研究进展，指出了目前电池发展中亟需解决的问题及未来的发展方向。

关键词: 有机-无机杂化钙钛矿, 太阳能, 复合材料, 介孔结构, 平面异质结

Abstract:

Hybrid organic-inorganic perovskite materials have received much attention in recent years because of their super light absorption coefficient, high charge carrier mobility, ambipolar property, and simple preparation procedure. Photon conversion efficiency of perovskite solar cells was raised from around 3.8% to over 20.4% in past 7 years and had potentials to be continuously enhanced. With a brief introduction of structures and optoelectronic properties of perovskite materials, development and device structures of perovskite solar cells were summarized. Further, challenging issues with current devices were explored and future development directions of perovskite solar cells were proposed.

Key words: organic-inorganic perovskite, solar energy, composites, mesoscopic structure, planar heterojunction

中图分类号:

TM914.4

陈超, 杨修春, 刘巍. 有机-无机杂化钙钛矿太阳能电池的研究进展[J]. 化工学报, 2017, 68(3): 811-820.

CHEN Chao, YANG Xiuchun, LIU Wei. Research progress of hybrid organic-inorganic perovskite solar cells[J]. CIESC Journal, 2017, 68(3): 811-820.

参考文献 76

[1]	LI G, SHROTRIYA V, HUANG J S, et al. High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends[J]. Nat. Mater., 2005, 4(11):864-868.
[2]	HAGFELDT A, BOSCHLOO G, SUN L, et al. Dye-sensitized solar cells[J]. Chem. Rev., 2010, 110(11):6595-6663.
[3]	BHUWALKA A, MIKE J F, HE M, et al. Quaterthiophene-benzobisazole copolymers for photovoltaic cells:effect of heteroatom placement and substitution on the optical and electronic properties[J]. Macromolecules, 2011, 44(24):9611-9617.
[4]	HE M, QIU F, LIN Z Q. Toward high-performance organic-inorganic hybrid solar cells:bringing conjugated polymers and inorganic nanocrystals in close contact[J]. Phys. Chem. Lett., 2013, 4(11):1788-1796.
[5]	KAKIAGE K, AOYAMA Y, YANO T, et al. Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes[J]. Chemical Communications, 2015, 51(88):15894-15897.
[6]	GREEN M A, EMERY K, HISHIKAWA Y, et al. Solar cell efficiency tables (version 36)[J]. Prog. Photovoltaics, 2010, 18(5):346-352.
[7]	XIE Y S, TANG Y Y, WU W J, et al. Porphyrin cosensitization for a photovoltaic efficiency of 11.5%:a record for non-ruthenium solar cells based on iodine electrolyte[J]. Journal of the American Chemical Society, 2015, 137(44):14055-14058.
[8]	WANG Y Q, CHEN B, WU W J, et al. Efficient solar cells sensitized by porphyrins with an extended conjugation framework and a carbazole donor:from molecular design to cosensitization[J]. Angewandte Chemie International Edition, 2014, 53(40):10779-10783.
[9]	SUN X, WANG Y Q, LI X, et al. Cosensitizers for simultaneous filling up of both absorption valleys of porphyrins:a novel approach for developing efficient panchromatic dye-sensitized solar cells[J]. Chemical Communications, 2014, 50(98):15609-15612.
[10]	PARK N G. Perovskite solar cells:an emerging photovoltaic technology[J]. Materials Today, 2015, 18(2):65-72.
[11]	HEPBASLI A. A key review on exergetic analysis and assessment of renewable energy resources for a sustainable future[J]. Renewable and Sustainable Energy Reviews, 2008, 12(3):593-661.
[12]	KOJIMA A, TESHIMA K, SHIRAI Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. Am. Chem. Soc., 2009, 131(17):6050-6051.
[13]	IM J H, LEE C R, LEE J W, et al. 6.5% efficient perovskite quantum-dot-sensitized solar cell[J]. Nanoscale, 2011, 3(10):4088-4093.
[14]	KIM H S, LEE C R, IM J H, et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J]. Sci. Rep., 2012, 2:591-597.
[15]	CHANG J A, IM S H, LEE Y H, et al. Panchromatic photon-harvesting by hole-conducting materials in inorganic-organic heterojunction sensitized-solar cell through the formation of nanostructured electron channels[J]. Nano Lett., 2012, 12(4):1863-1867.
[16]	NOH J H, IM S H, HEO J H, et al. Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells[J]. Nano Lett., 2013, 13(4):1764-1769.
[17]	ZHOU H P, CHEN Q, LI G, et al. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014, 345(6196):542-546.
[18]	YANG W S, NOH J H, JEON N J, et al. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J]. Science, 2015, 348(6240):1234-1237.
[19]	PARK N G. Organometal perovskite light absorbers toward a 20% efficiency low-cost solid-state mesoscopic solar cell[J]. Phys. Chem. Lett., 2013, 4(15):2423-2429.
[20]	FORRESTER W F, HINDE R M. Crystal structure of barium titanate[J]. Nature, 1945, 156:177.
[21]	ROOKSBY H P. Compounds of the structural type of calcium titanate[J]. Nature, 1945, 155:484.
[22]	GREEN M A, HO-BAILLIE A, SNAITH H J. The emergence of perovskite solar cells[J]. Nature Photonics, 2014, 8(7):506-514.
[23]	CAI B, XING Y D, YANG Z, et al. High performance hybrid solar cells sensitized by organolead halide perovskites[J]. Energy Environ. Sci., 2013, 6:1480-1485.
[24]	WOJCIECHOWSKI K, STRANKS S D, ABATE A, et al. Heterojunction modification for highly efficient organic-inorganic perovskite solar cells[J]. ACS Nano, 2014, 8(12):12701-12709.
[25]	MEI A Y, LI X, LIU L F, et al. A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability[J]. Science, 2014, 345(6194):295-298.
[26]	EDRI E, KIRMAYER S, CAHEN D, et al. High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J]. Phys. Chem. Lett., 2013, 4(6):897-902.
[27]	BURSCHKA J, DUALEH A, KESSLER F, et al. Tris(2-(1h-pyrazol-1-yl)pyridine)cobalt(Ⅲ) as p-type dopant for organic semiconductors and its application in highly efficient solid-state dye-sensitized solar cells[J]. Am. Chem. Soc., 2011, 133(45):18042-18045.
[28]	JANG S R, ZHU K, KO M J, et al. Voltage-enhancement mechanisms of an organic dye in high open-circuit voltage solid-state dye-sensitized solar cells[J]. ACS Nano, 2011, 5(10):8267-8274.
[29]	BAI Y, CHEN H, XIAO S, et al. Effects of a molecular monolayer modification of NiO nanocrystal layer surfaces on perovskite crystallization and interface contact toward faster hole extraction and higher photovoltaic performance[J]. Advanced Functional Materials, 2016, 26(17):2950-2958.
[30]	QIN P, TANAKA S, ITO S, et al. Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency[J]. Nature Communications, 2014, 5:3834.
[31]	JUNG J W, CHUEH C C, JEN A K Y. High-performance semitransparent perovskite solar cells with 10% power conversion efficiency and 25% average visible transmittance based on transparent CuSCN as the hole-transporting material[J]. Advanced Energy Materials, 2015, 5(17):429-436.
[32]	ETGAR L, GAO P, XUE Z, et al. Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells[J]. Journal of the American Chemical Society, 2012, 134(42):17396-17399.
[33]	AHARON S, GAMLIEL S, EL COHEN B, et al. Depletion region effect of highly efficient hole conductor free CH3NH3PbI3 perovskite solar cells[J]. Physical Chemistry Chemical Physics, 2014, 16(22):10512-10518.
[34]	LIU D, KELLY T L. Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J]. Nature Photonics, 2014, 8(2):133-138.
[35]	SONG J, ZHENG E, WANG X F, et al. Low-temperature-processed ZnO-SnO2 nanocomposite for efficient planar perovskite solar cells[J]. Solar Energy Materials and Solar Cells, 2016, 144:623-630.
[36]	LIU D, YANG J, KELLY T L. Compact layer free perovskite solar cells with 13.5% efficiency[J]. Journal of the American Chemical Society, 2014, 136(49):17116-17122.
[37]	KE W, FANG G, WAN J, et al. Efficient hole-blocking layer-free planar halide perovskite thin-film solar cells[J]. Nature Communications, 2015, 6:6700.
[38]	ZUO C T, BOLINK H J, HAN H W, et al. Advances in perovskite solar cells[J]. Advanced Science, 2016, 3(7):1500324.
[39]	KU Z, RONG Y, XU M, et al. Full printable processed mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells with carbon counter electrode[J]. Scientific Reports, 2013, 3:3132.
[40]	LI Z, KULKARNI S A, BOIX P P, et al. Laminated carbon nanotube networks for metal electrode-free efficient perovskite solar cells[J]. ACS Nano, 2014, 8(7):6797-6804.
[41]	RONG Y, KU Z, MEI A, et al. Hole-conductor-free mesoscopic TiO2/CH3NH3PbI3 heterojunction solar cells based on anatase nanosheets and carbon counter electrodes[J]. The Journal of Physical Chemistry Letters, 2014, 5(12):2160-2164.
[42]	CHEN H, WEI Z, HE H, et al. Solvent engineering boosts the efficiency of paintable carbon-based perovskite solar cells to beyond 14%[J]. Advanced Energy Materials, 2016, 6:1502087.
[43]	BURSCHKA J, PELLET N, MOON S J, et al. Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J]. Nature, 2013, 499(7458):316-319.
[44]	EPERON G E, BURLAKOV V M, DOCAMPO P, et al. Morphological control for high performance, solution-processed planar heterojunction perovskite solar cells[J]. Advanced Functional Materials, 2014, 24(1):151-157.
[45]	LIU M, JOHNSTON M B, SNAITH H J. Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature, 2013, 501(7467):395-398.
[46]	WANG J T W, BALL J M, BAREA E M, et al. Low-temperature processed electron collection layers of graphene/TiO2 nanocomposites in thin film perovskite solar cells[J]. Nano letters, 2013, 14(2):724-730.
[47]	WOJCIECHOWSKI K, SALIBA M, LEIJTENS T, et al. Sub-150℃ processed meso-superstructured perovskite solar cells with enhanced efficiency[J]. Energy & Environmental Science, 2014, 7(3):1142-1147.
[48]	CHEN Q, ZHOU H, HONG Z, et al. Planar heterojunction perovskite solar cells via vapor-assisted solution process[J]. Journal of the American Chemical Society, 2013, 136(2):622-625.
[49]	CHEN Y, ZHAO Y, LIANG Z. Non-thermal annealing fabrication of efficient planar perovskite solar cells with inclusion of NH4Cl[J]. Chemistry of Materials, 2015, 27(5):1448-1451.
[50]	YI C, LI X, LUO J, et al. Perovskite photovoltaics with outstanding performance produced by chemical conversion of bilayer mesostructured lead halide/TiO2 films[J]. Advanced Materials, 2016, 28:2964-2970.
[51]	LEE M M, TEUSCHER J, MIYASAKA T, et al. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J]. Science, 2012, 338(6107):643-647.
[52]	BI D, MOON S J, HÄGGMAN L, et al. Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures[J]. RSC Advances, 2013, 3(41):18762-18766.
[53]	YANG X C, LIU W, REN P. All solid-state solar cells based on CH3NH3PbI3-sensitized TiO2 nanotube arrays[J]. Physica E:Low-dimensional Systems and Nanostructures, 2016, 83:322-328.
[54]	GURINA G I, SAVCHENKO K V. Intercalation and formation of complexes in the system of lead (Ⅱ) iodide-ammonia[J]. Journal of Solid State Chemistry, 2004, 177(3):909-915.
[55]	YE M, XIN X, LIN C, et al. High efficiency dye-sensitized solar cells based on hierarchically structured nanotubes[J]. Nano Letters, 2011, 11(8):3214-3220.
[56]	BALL J M, LEE M M, HEY A, et al. Low-temperature processed meso-superstructured to thin-film perovskite solar cells[J]. Energy & Environmental Science, 2013, 6(6):1739-1743.
[57]	XING G, MATHEWS N, SUN S, et al. Long-range balanced electron-and hole-transport lengths in organic-inorganic CH3NH3PbI3[J]. Science, 2013, 342(6156):344-347.
[58]	STRANKS S D, EPERON G E, GRANCINI G, et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J]. Science, 2013, 342(6156):341-344.
[59]	LI W, LI J, WANG L, et al. Post modification of perovskite sensitized solar cells by aluminum oxide for enhanced performance[J]. Journal of Materials Chemistry A, 2013, 1(38):11735-11740.
[60]	CHEN H, PAN X, LIU W, et al. Efficient panchromatic inorganic-organic heterojunction solar cells with consecutive charge transport tunnels in hole transport material[J]. Chemical Communications, 2013, 49(66):7277-7279.
[61]	SHI J, DONG J, LÜ S, et al. Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells:high efficiency and junction property[J]. Applied Physics Letters, 2014, 104(6):063901.
[62]	XU X B, LI S H, ZHANG H, et al. A power pack based on organometallic perovskite solar cell and supercapacitor[J]. ACS Nano, 2015, 9(2):1782-1787.
[63]	CHEN W, WU Y Z, YUE Y F, et al. Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers[J]. Science, 2015, 350(6263):944-948.
[64]	NIU G, LI W, MENG F, et al. Study on the stability of CH3NH3PbI3 films and the effect of post-modification by aluminum oxide in all-solid-state hybrid solar cells[J]. Mater. Chem. A., 2014, 2(3):705-710.
[65]	MISRA R K, AHARON S, LI B L, et al. Temperature-and component-dependent degradation of perovskite photovoltaic materials under concentrated sunlight[J]. Phys. Chem. Lett., 2015, 6(3):326-330.
[66]	YANG J L, SIEMPELKAMP B D, LIU D Y, et al. Investigation of CH3NH3PbI3 degradation rates and mechanisms in controlled humidity environments using in situ techniques[J]. ACS Nano, 2015, 9(2):1955-1963.
[67]	WANG Q Y, YANG X C, WANG X L, et al. Synthesis of N-doped TiO2 mesosponge by solvothermal transformation of anodic TiO2 nanotubes and enhanced photoelectrochemical performance[J]. Electrochimica Acta, 2012, 62:158-162.
[68]	WANG Q Y, YANG X C, LIU D, et al. Fabrication, characterization and photocatalytic properties of Ag nanoparticles modified TiO2 NTs[J]. Alloy. Compd., 2012, 527:106-111.
[69]	MALINKIEWICZ O, YELLA A, LEE Y H, et al. Perovskite solar cells employing organic charge-transport layers[J]. Nat. Photonics, 2014, 8(2):128-132.
[70]	KIM J H, CHUEH C C, WILLIMAS, S T, et al. Room-temperature, solution-processable organic electron extraction layer for high-performance planar heterojunction perovskite solar cells[J]. Nanoscale, 2015, 7(41):17343-17349.
[71]	XIAO J Y, SHI J J, LIU H B, et al. Efficient CH3NH3PbI3 perovskite solar cells based on graphdiyne (GD)-modified P3HT hole-transporting material[J]. Adv. Energy Mater., 2015, 5(8):1401943.
[72]	CHRISTIANS J A, FUNG R C M, KAMAT P V. An inorganic hole conductor for organo-lead halide perovskite solar cells. Improved hole conductivity with copper iodide[J]. Am. Chem. Soc., 2014, 136(2):758-764.
[73]	CHAVHAN S, MIGUEL O, GRANDE H J, et al. Organo-metal halide perovskite-based solar cells with CuSCN as the inorganic hole selective contact[J]. Mater. Chem. A, 2014, 2(32):12754-12760.
[74]	TRIFILETTI V, ROIATI V, COLELLA S, et al. NiO/MAPbI(3-x)Cl(x)/PCBM:a model case for an improved understanding of inverted mesoscopic solar cells[J]. ACS Appl. Mater. Interfaces, 2015, 7(7):4283-4289.
[75]	NOEL N K, STRANKS S D, ABATE A, et al. Lead-free organic-inorganic tin halide perovskites for photovoltaic applications[J]. Energy Environ. Sci., 2014, 7(9):3061-3068.
[76]	RYU S, NOH J H, JEON N J, et al. Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor[J]. Energy Environ. Sci., 2014, 7(8):2614-2618.

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