工业固废活化钾长石-CO2矿化提钾的生命周期碳排放与成本评价

doi:10.11949/j.issn.0438-1157.20161754

摘要/Abstract

摘要：

利用工业固废活化非水溶性钾长石矿，矿化固定二氧化碳（CO₂）并提钾工艺，是同时处理工业固废、开发钾资源、减排CO₂等一举多得的CCUS路线。采用生命周期评价（LCA）方法，以生产含1 t K₂O的钾肥为功能单元，以传统的高炉冶炼钾长石制可溶性钾肥并联产白水泥工艺作为参照，对比评价了两种钾长石-工业固废体系矿化CO₂联产钾肥工艺过程的碳减排潜力和经济性。对工艺从原料开采、运输到产品生产的生命周期的温室气体排放量（简称“碳排放”）和成本进行了全流程的核算，研究了更全面的产品碳排放和成本分配方法。结果表明，无论是碳排放还是经济性，钾长石-工业固废体系矿化CO₂联产钾肥工艺均较传统工艺有很大提高，碳减排潜力分别可达81.16%和20.48%左右，成本可节约34.75%和45.11%左右。

关键词: 生命周期评价, 钾长石, 温室气体, 二氧化碳捕集, 废物处理

Abstract:

Using industrial solid waste to calcinate non-water-soluble natural K-feldspar for CO₂ mineralization and potassium extraction is a multi-functional CO₂ capture, utilization and storage (CCUS) technology that can treat industrial solid waste, utilize potassium resource and reduce greenhouse-gas (GHG) emissions. Life cycle assessment (LCA) was adopted based on a functional unit of the produced potash fertilizer containing 1 ton of K₂O to compare two emerging technologies of simultaneous potash fertilizer production and CO₂mineralization from K-feldspar and industrial solid waste (CaCl₂/phosphor-gypsum) with a traditional technology of potash fertilizer and white cement coproduction by smelting K-feldspar in blast furnace in terms of GHG-reduction potential and economic feasibility. The life-cycle (from raw material exploitation to transportation to production) GHG emissions and life-cycle cost of these technologies were accounted by using an improved allocation approach that considered the credit of avoided GHG emissions/cost from industrial solid waste treatment. The results showed that the two emerging technologies were preferred to the traditional technology in terms of both life-cycle GHG emissions and economic feasibility with GHG-reduction potential of about 81.16% and 20.48%, and cost savings of up to 34.75% and 45.11%, respectively.

Key words: life cycle assessment, K-feldspar, greenhouse gas, CO₂ capture, waste treatment

中图分类号:

TQ044.3

莫淳, 廖文杰, 梁斌, 李春, 岳海荣, 谢和平. 工业固废活化钾长石-CO₂矿化提钾的生命周期碳排放与成本评价[J]. 化工学报, 2017, 68(6): 2501-2509.

MO Chun, LIAO Wenjie, LIANG Bin, LI Chun, YUE Hairong, XIE Heping. Life-cycle greenhouse gas emissions and cost of potassium extraction and CO₂ mineralization via K-feldspar—industrial solid waste calcination[J]. CIESC Journal, 2017, 68(6): 2501-2509.

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[34]	丁竑广, 丁汝斌, 杨兴志, 等. 磷石膏制硫酸联产水泥仍是其综合利用的有效途径[J]. 硫磷设计与粉体工程, 2011(1):1-6. DING H G, DING R B, YANG X Z, et al. Phosphogypsum production of sulfuric acid and cement[J]. Sulphur Phosphorus & Bulk Materials Handling Related Engineering, 2011(1):1-6.
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[36]	SMIT M C. A north atlantic treaty organisation framework for life cycle costing[J]. International Journal of Computer Integrated Manufacturing, 2012, 25(4):444-456.
[37]	HOCHSCHORNER E, NORING M. Practitioners' use of life cycle costing with environmental costs-a Swedish study[J]. International Journal of Life Cycle Assessment, 2011, 16(9):897-902.
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[41]	任必锐. 利用纯碱废液获得的高钙卤水制备氯化钙产品研究[J]. 中国井矿盐, 2014, 45(6):15-16. REN B R. Study of calcium chloride products preparation with high calcium brine obtained by soda ash waste[J]. China Well and Rock Salt, 2014, 45(6):15-16.
[42]	茅爱新. 氨碱法纯碱生产中废液及碱渣的综合利用[J]. 化学工业与工程技术, 2001, 22(2):31-32. MAO A X. Comprehensive utilization of waste liquid and Soda dregs in soda product ion by ammonia-soda process[J]. Journal of Chemical Industry and Engineering, 2001, 22(2):31-32.

工业固废活化钾长石-CO₂矿化提钾的生命周期碳排放与成本评价

Life-cycle greenhouse gas emissions and cost of potassium extraction and CO₂ mineralization via K-feldspar—industrial solid waste calcination

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