Ni/La2O2CO3催化剂对山梨醇氢解产物的选择性调控

doi:10.11949/j.issn.0438-1157.20170043

化工学报 ›› 2017, Vol. 68 ›› Issue (6): 2359-2367.DOI: 10.11949/j.issn.0438-1157.20170043

• 催化、动力学与反应器 • 上一篇下一篇

Ni/La₂O₂CO₃催化剂对山梨醇氢解产物的选择性调控

张涛^1,2, 刘琪英¹, 张彩红^2,3, 张琦¹, 马隆龙¹

1. 中国科学院广州能源研究所, 可再生能源与天然气水合物重点实验室, 广东广州 510640;
2. 中国科学技术大学纳米科学技术学院, 江苏苏州 215123;
3. 中国科学院大学, 北京 100049

收稿日期:2017-01-10 修回日期:2017-02-24 出版日期:2017-06-05 发布日期:2017-06-05
通讯作者: 刘琪英
基金资助:
国家自然科学基金项目（51376185，51536009，51576199）

Selective hydrogenolysis of sorbitol on Ni/La₂O₂CO₃ catalysts

ZHANG Tao^1,2, LIU Qiying¹, ZHANG Caihong^2,3, ZHANG Qi¹, MA Longlong¹

1. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
2. Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, Jiangsu, China;
3. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2017-01-10 Revised:2017-02-24 Online:2017-06-05 Published:2017-06-05
Contact: 10.11949/j.issn.0438-1157.20170043
Supported by:
supported by the National Natural Science Foundation of China(51376185, 51536009, 51576199)

摘要/Abstract

摘要：

采用共沉淀法制备了具有协同稳定作用的Ni/La₂O₂CO₃催化剂，用于山梨醇选择性氢解为小分子醇的研究。采用X射线衍射、氢气程序升温还原、CO₂程序升温脱附和扫描电镜对催化剂进行了表征。考察了不同配比Ni、La的加氢位点和碱性调控对山梨醇氢解产物的影响。结果表明，Ni、La摩尔比为2：3时，山梨醇转化率达到98.6%，C₂~C₃多元醇的产率达到43.8%，催化剂经2次反应后对山梨醇的转化率仍高达90%。探究了催化剂从酸性到碱性调变过程中，山梨醇氢解的产物分布，并提出了反应路径。

关键词: 山梨醇, 选择性催化还原, 纳米材料, 加氢, 共沉淀, C₂~C₃多元醇

Abstract:

Ni/La₂O₂CO₃ catalysts with different Ni/La ratios were prepared by co-precipitation and the performance was tested in selective hydrogenolysis of sorbitol to C₂—C₃ polyols. The catalysts were characterized by X-ray diffraction(XRD), H₂ temperature-programmed reduction(H₂-TPR), CO₂temperature-programmed desorption(CO₂-TPD) and scanning electron microscopy(SEM). The effect of hydrogenation and base regulation was investigated by varying the Ni/La ratios. The result shows that the conversion of sorbitol was 98.6% and the yields of C₂—C₃ polyols was 43.8% when the mole ratio of Ni to La is 2:3. After two times of reaction, the catalyst still achieved a sorbitol conversion of 90%. From acidic to alkaline, the products distribution of hydrogenolysis of sorbitol was discussed. The reaction pathway was also proposed based on the experiment results.

Key words: sorbitol, SCR, nanomaterials, hydrothermal, co-precipitation, C₂—C₃ polyols

中图分类号:

O643.3

张涛, 刘琪英, 张彩红, 张琦, 马隆龙. Ni/La₂O₂CO₃催化剂对山梨醇氢解产物的选择性调控[J]. 化工学报, 2017, 68(6): 2359-2367.

ZHANG Tao, LIU Qiying, ZHANG Caihong, ZHANG Qi, MA Longlong. Selective hydrogenolysis of sorbitol on Ni/La₂O₂CO₃ catalysts[J]. CIESC Journal, 2017, 68(6): 2359-2367.

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Ni/La₂O₂CO₃催化剂对山梨醇氢解产物的选择性调控

Selective hydrogenolysis of sorbitol on Ni/La₂O₂CO₃ catalysts

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