蒙脱土/聚醚砜-双马来酰亚胺复合材料微观形貌及性能

doi:10.11949/j.issn.0438-1157.20180197

化工学报 ›› 2018, Vol. 69 ›› Issue (S1): 148-154.DOI: 10.11949/j.issn.0438-1157.20180197

• 材料化学工程与纳米技术 • 上一篇下一篇

蒙脱土/聚醚砜-双马来酰亚胺复合材料微观形貌及性能

陈宇飞^1,2, 耿成宝¹, 楚洪月¹, 汪波涛¹, 郭红缘¹, 岳春艳¹

1 哈尔滨理工大学材料科学与工程学院, 黑龙江哈尔滨 150040;
2 哈尔滨理工大学工程电介质及应用技术教育部重点实验室, 黑龙江哈尔滨 150080

收稿日期:2018-02-12 修回日期:2018-03-01 出版日期:2018-09-30 发布日期:2018-09-30
通讯作者: 陈宇飞(1963-),女,教授,E-mail:chenyufei@hrbust.edu.cn
基金资助:
哈尔滨创新人才专项（2015RAXXJ029）。

Micro-morphology and properties of modified MMT/PES-MBAE composite

CHEN Yufei^1,2, GENG Chengbao¹, CHU Hongyue¹, WANG Botao¹, GUO Hongyuan¹, YUE Chunyan¹

1 College of Material Science and Engineering, Harbin University of Science and Technology, Harbin 150040, Heilongjiang, China;
2 Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, Heilongjiang, China

Received:2018-02-12 Revised:2018-03-01 Online:2018-09-30 Published:2018-09-30
Supported by:
supported by the Harbin Innovation Talent Project (2015RAXXJ029).

摘要/Abstract

摘要：

采用十八烷基三甲基氯化铵（OTAC）作为改性剂、通过离子交换法制备了改性蒙脱土（OTAC-MMT）；以4，4'-二氨基二苯甲烷双马来酰亚胺（MBMI）、3，3'-二烯丙基双酚A（BBA）及双酚A双烯丙基醚（BBE）为原料制备了复合材料基体（MBAE）；利用原位聚合法将OTAC-MMT和聚醚砜（PES）掺杂基体中制备OTAC-MMT/PES-MBAE复合材料。XRD结果分析表明：OTAC-MMT层间距相对于Na-MMT有明显增大。SEM微观形貌显示：OTAC-MMT片层结构更加明显且分散均匀；复合材料的表面更加粗糙，改性蒙脱土分散均匀，PES与基体树脂呈两相结构，出现了向不同方向发展的银纹和微裂纹，呈韧性断裂。当OMMT质量分数为2%、PES为3%时，OTAC-MMT/PES-MBAE复合材料的冲击强度和弯曲强度分别为14.54 kJ·m^-2和149.12 MPa，较MBAE树脂分别提高了55.5%和47.2%。介电性能测试表明：OTAC-MMT/PES-MBAE复合材料介电常数和损耗略有上升，但仍满足材料的使用要求。

关键词: 4,4'-二氨基二苯甲烷双马来酰亚胺, 蒙脱土, 十八烷基三甲基氯化铵, 微观形貌, 性能

Abstract:

Cetyltrimethyl ammonium chloride(OTAC) as modifier, modified montmorillonite(OTAC-MMT) was prepared via cation exchange. 4,4'-diamino diphenyl methane bismaleimide(MBMI), 3,3'-diallyl bisphenol A(BBA) and bisphenol-A diallyl ether(BBE) were used to synthesize MBAE matrix, OTAC-MMT/PES-MBAE composites were prepared from MBAE, OTAC-MMT and PES by in-situ polymerization method, respectively. The XRD result revealed that the interlayer spacing of OTAC-MMT increase obviously, which compared with Na-MMT. The SEM micro-morphology displayed that the layer structure of OTAC-MMT was more apparent and dispersed uniformly, the surface of composites were more rough than that of MBAE, PES and MBAE matrix presented two-phase, crazing and microcrack which direct in different directions were appeared, exhibited ductile fracture. When the mass fraction of OTAC-MMT was 2%, PES content was 4%, the impact strength and the bending strength of OTAC-MMT/PES-MBAE were 14.54 kJ·m^-2 and 143.12 MPa, enhance 55.5% and 47.2% than that of MBAE matrix, respectively. The dielectric constant and loss of the composite material showed a little increase while OTAC-MMT and PES exist, but OTAC-MMT could reduce the negative impacts of PES.

Key words: 4,4'-diamino diphenyl methane bismaleimide, montmorillonite, cetyltrimethyl ammonium chloride, microstructure, properties

中图分类号:

TQ326.9

陈宇飞, 耿成宝, 楚洪月, 汪波涛, 郭红缘, 岳春艳. 蒙脱土/聚醚砜-双马来酰亚胺复合材料微观形貌及性能[J]. 化工学报, 2018, 69(S1): 148-154.

CHEN Yufei, GENG Chengbao, CHU Hongyue, WANG Botao, GUO Hongyuan, YUE Chunyan. Micro-morphology and properties of modified MMT/PES-MBAE composite[J]. CIESC Journal, 2018, 69(S1): 148-154.

参考文献 30

[1]	TAKEICHI T, UCHIDA S, INOUE Y, et al. Preparation and properties of polymer alloys consisting of high-molecular-weight benzoxazine and bismaleimide[J]. High Performance Polymers, 2014, 26(3):265-273.
[2]	罗甜. 二烯丙基双酚A改性双马来酰亚胺耐高温胶黏剂研究[D]. 武汉:武汉理工大学, 2010. LUO T. Study on diallyl bisphenol A modify BMI high temperature resistance adhesive[D]. Wuhan:Wuhan University of Technology, 2010.
[3]	CHEN X, YE J, YUAN L, et al. Multi-functional ladderlike polysiloxane:synthesis, characterization and its high performance flame retarding bismaleimide resins with simultaneously improved thermal resistance, dimensional stability and dielectric properties[J]. Journal of Materials Chemistry A, 2014, 20(2):7491-7501.
[4]	CHEN Y F, WANG B T, LI F L, et al. Micro-structure, mechanical properties and dielectric properties of bisphenol a allyl compound-bismaleimide modified by super-critical silica and polyethersulfone composite[J]. Journal of Electronic Materials, 2017, 46(7):4656-4661.
[5]	CHENG Q, BAO J, ZHANG C, et al. High mechanical performance composite conductor:multi-walled carbon nanotube sheet/bismaleimide nanocomposites[J]. Advanced Functional Materials, 2009, 20(19):3219-3225.
[6]	ZHOU J T, YAO Z J, ZHOU C, et al. Mechanical properties of PLA/PBS foamed composites reinforced by organophilic montmorillonite[J]. Applied Clay Science, 2014, 131(18):332-339.
[7]	LOUISE B, HENK N W, GEOFFREY C, et al. Rheology modification of montmorillonite dispersions by colloidal silica[J]. Rheologica Acta, 2014, 53(5):373-384.
[8]	中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. 塑料试样状态调节和试验的标准环境:GB/T 2918-1998[S]. 北京:中国标准出版社, 1998. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China. Standard environment for state regulation and testing of plastic samples:GB/T 2918-1998[S]. Beijing:Standards Press of China, 1998.
[9]	中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. 树脂浇铸体性能试验方法:GB/T 2567-2008[S]. 北京:中国标准出版社, 2008. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China. Test methods for properties of resin casting boby:GB/T 2567-2008[S]. Beijing:Standards Press of China, 2008.
[10]	WANG Y Q, WANG X Q, DUAN Y F, et al. Modification of momtmorillonite with poly(oxypropylene) amine hydrochlorides:basal spacing amount intercalated and thermal stability[J]. Clays and Clay Minerals, 2011, 59(11):507-517.
[11]	XING J, WANG X B, DENG B Y, et al. Modification of montmorillonite by different surfactants and its use for the preparation of polyphenylene sulfide nanocomposites[J]. High Performance Polymers, 2016, 28(5):618-629.
[12]	程雷, 王汝敏, 王小建. 烯丙基化合物改性双马来酰亚胺树脂的研究进展[J]. 中国胶粘剂, 2009, 18(4):58-63. CHENG L, WANG R M, WANG X J. Research progress of bismaleimide resin modified by allyl compounds[J]. China Adhesives, 2009, 18(4):58-63.
[13]	李斌. 有机化蒙脱土改性沥青的制备、性能及其改性机理研究[D]. 武汉:武汉理工大学, 2010. LI B. Preparation performance and modification mechanism of organo-montmorillonite modified asphalt[D]. Wuhan:Wuhan University of Technology, 2010.
[14]	YAN H, LI P, NING R, et al. Tribological properties of bismaleimide composites with surface-modified SiO2 nanoparticles[J]. Journal of Applied Polymer Science, 2008, 110(3):1375-1381.
[15]	MANFREDI L B, SANTIS H D, VAZQUEZ A. Influence of the addition of montmorillonite to the matrix of unidirectional glass fibre/epoxy composites on their mechanical and water absorption properties[J]. Composites A:Applied Science and Manufacturing, 2008, 39(11):1726-1731.
[16]	TIMOFEEVA M N, PANCHENKO V N, KRUPSKAYA V, et al. Effect of nitric acid modification of montmorillonite clay on synthesis of solketal from glycerol and acetone[J]. Catalysis Communications, 2017, 90(12):65-69.
[17]	HONG P H, RAY L F, THOR B, et al. Changes in the morphology of organoclays with HDTMA(+) surfactant loading[J]. Applied Clay Science, 2006, 31(3):262-271.
[18]	XI Y F, FROST R L, HE H P. Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyltrimethyl, dialkyl dimethyl, and trialkyl methyl ammonium bromides[J]. J. Colloid Interface Sci., 2007, 305:1502-1158.
[19]	CHOU C C, CHANG Y C, CHANG M L, et al. Conformational change of trifunctional poly(oxypropylene)amines intercalated within a layered silicate confinement[J]. Macromolecules, 2004, 37(2):473-477.
[20]	赵新福, 张清杰, 郭健, 等. 环氧化合物上浆处理的MWCNTs对MWCNTs/环氧树脂复合材料性能的影响[J]. 复合材料学报, 2017, 34(2):247-255. ZHAO X F, ZHANG Q J, GUO J, et al. Effect of epoxide sizing treated MWCNTS on the properties of MWCNTS/epoxy composites[J]. Acta Materiae Compositae Sinica, 2017, 34(2):247-255.
[21]	张晓亮. 蒙脱土/聚合物纳米复合材料的制备及性能研究[D]. 合肥:安徽大学, 2013. ZHANG X L. Study on preparation and properties of polymer/montmorillonite nanocomposites[D]. Hefei:Anhui University, 2013.
[22]	SUN S J, GUO M C, YI X S, et al. Preparation and characterization of a naphthalene-modified poly(aryl ether ketone) and its phase separation morphology with bismaleimide resin[J]. Polymer Bulletin, 2017, 74(5):1519-1533.
[23]	WANG B W, YIN Y C, LIU C J, et al. Synthesis and characterization of clay/polyaniline nanofiber hybrids[J]. Applied Polymer Science, 2013, 128(35):1304-1312.
[24]	JANA M, LUDMILA S, VALÉRIA B. Near-infrared spectroscopy as an effective tool for monitoring the conformation of alkylammonium surfactants in montmorillonite interlayers[J]. Vibrational Spectroscopy, 2016, 84:44-52.
[25]	NAVEAU E, CALBERG C, DETREMBLEUR C. Organo modification of montmorillonite in supercritical carbon dioxide[J]. Applied Clay Science, 2011, 51(4):467-472.
[26]	陈宇飞, 谭珺琰, 张清宇, 等. 超临界SiO2/聚醚砜-双马来酰亚胺复合材料微观结构及性能[J]. 复合材料学报, 2015, 32(3):665-672. CHEN Y F, TAN J Y, ZHANG Q Y, et al. Microstructure and heat-resistance of SCE-Al2O3/PES-MBAE composite[J]. Acta Materiae Compositae Sinica, 2015, 32(3):665-672.
[27]	郭宁. 蒙脱土/环氧树脂纳米复合材料结构形态与介电性能机理研究[D]. 哈尔滨:哈尔滨理工大学, 2014. GUO N. Structure morphology and dielectric performance mechanism of montmorillonite/epoxy resin nanocomposites[D]. Harbin:Harbin University of Science and Technology, 2014.
[28]	陈宇飞, 代起望, 滕成君. 超临界氧化铝/聚醚砜-双马来酰亚胺复合材料的微观结构与耐热性[J]. 复合材料学报, 2015, 32(3):665-672. CHEN Y F, DAI Q W, TENG C J. Microstructure and heat-resistance of SCE-Al2O3/PES-MBAE composite[J]. Acta Materiae Compositae Sinica, 2015, 32(3):665-672.
[29]	FU Q T, QING Q L, XUAN W, et al. Investigation of electrical properties of LDPE/ZnO nanocomposite dielectrics[J]. Transactions on Dielectrics and Electrical Insulation, 2012, 19(3):763-769.
[30]	ALAPATI S, THOMAS M J. Electrical treeing and the associated PD characteristics in LDPE nanocomposites[J]. Transactions on Dielectrics and Electrical Insulation, 2012, 19(2):697-704.

蒙脱土/聚醚砜-双马来酰亚胺复合材料微观形貌及性能

Micro-morphology and properties of modified MMT/PES-MBAE composite

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