含草酸钾的超细水雾抑制甲烷爆炸的特性

doi:10.11949/j.issn.0438-1157.20180671

化工学报 ›› 2018, Vol. 69 ›› Issue (12): 5359-5369.DOI: 10.11949/j.issn.0438-1157.20180671

含草酸钾的超细水雾抑制甲烷爆炸的特性

杨克^1,3, 纪虹^2,3, 邢志祥^1,3, 黄维秋^2,3, 王宇^1,3, 张平^1,3

1. 常州大学环境与安全工程学院, 江苏常州 213164;
2. 常州大学石油工程学院, 江苏常州 213164;
3. 国家安全生产监督管理总局油气储运安全技术创新中心, 江苏常州 213164

收稿日期:2018-06-18 修回日期:2018-08-07 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: 纪虹
基金资助:
国家自然科学基金项目（51704041，51574046）；江苏省自然科学基金项目（BK20150269）；江苏高校自然科学研究面上项目（17KJD620001）；安全生产重大事故防治关键技术科技项目（Jiangsu-0015-2017AQ）。

Characteristics on methane explosion suppression by ultrafine water mist containing potassium oxalate

YANG Ke^1,3, JI Hong^2,3, XING Zhixiang^1,3, HUANG Weiqiu^2,3, WANG Yu^1,3, ZHANG Ping^1,3

1. School of Environment and Safety Engineering, Changzhou University, Changzhou 213164, Jiangsu, China;
2. School of Petroleum Engineering, Changzhou University, Changzhou 213164, Jiangsu, China;
3. Oil and Gas Storage Safety Technology Innovation Center of State Administration of Work Safety, Changzhou 213164, Jiangsu, China

Received:2018-06-18 Revised:2018-08-07 Online:2018-12-05 Published:2018-12-05
Supported by:
supported by the National Natural Science Foundation of China (51704041, 51574046), the Natural Science Foundation of Jiangsu Province(BK20150269), Jiangsu University Natural Science Research Surface Project (17KJD620001) and the Key Technical Project Prevention of Serious Accidents in Safety Production (Jiangsu-0015-2017AQ).

摘要/Abstract

摘要：

为研究含草酸钾的超细水雾对抑制甲烷爆炸有效性的影响，采用自制的半封闭管道进行抑爆实验，研究了草酸钾浓度的变化对超细水雾粒径的影响以及对甲烷抑爆性能的影响，分析了不同浓度草酸钾条件下火焰传播速度、爆炸超压、平均升压速率以及爆炸威力指数参数变化。实验结果表明：添加草酸钾对超细水雾的粒径特性影响较小；对于体积分数为9.5%的甲烷，在相同的通雾时间下，当草酸钾浓度为2%时，抑爆性能最显著，火焰传播速度、最大爆炸超压、平均升压速率以及爆炸威力指数较纯甲烷自由爆炸时分别下降了57.1%、66.3%、77.9%、91.5%；较纯水超细水雾分别下降了43.1%、61.3%、75.3%、90.5%；草酸钾的热解温度较低能够增强超细水雾的物理惰化作用并阻断化学链式反应从而有效抑制甲烷爆炸。

关键词: 草酸钾, 超细水雾, 甲烷, 抑爆机理, 安全

Abstract:

To study the effect of ultra-fine water mist containing potassium oxalate on the effectiveness of suppressing methane explosion, a self-made semi-confined chamber was used for explosion suppression experiments to study the effect of changes in potassium oxalate concentration on the particle size of ultra-fine water mist and the performance of methane explosion suppression. The effects of explosion performance were analyzed. The parameters of flame propagation speed, explosion overpressure, average pressure increase rate and explosion power index were analyzed under different concentrations of potassium oxalate. The experimental results show that the addition of potassium oxalate has little effect on the particle size characteristics of ultra-fine water mist. Under the same spraying time, 2% potassium oxalate concentration shows the most significant explosion suppression performance for the 9.5% volume fraction of methane. Compared with the no spraying condition, the flame propagation velocity, maximum explosion overpressure, average pressure rise rate, and explosion power index decreased by 57.1%, 66.3%, 77.9%, and 91.5%, respectively; compared with pure water ultra-fine water mist suppressing the explosion, those parameters decreased by 43.1%, 61.3%, 75.3%, and 90.5%, respectively. The lower pyrolysis temperature of potassium oxalate can enhance the physical inserting of ultra-fine water mist and block the chemical chain reaction to suppress the explosion of methane effectively.

Key words: potassium oxalate, ultrafine water mist, methane, mechanism of explosion suppression, safety

中图分类号:

TD712

杨克, 纪虹, 邢志祥, 黄维秋, 王宇, 张平. 含草酸钾的超细水雾抑制甲烷爆炸的特性[J]. 化工学报, 2018, 69(12): 5359-5369.

YANG Ke, JI Hong, XING Zhixiang, HUANG Weiqiu, WANG Yu, ZHANG Ping. Characteristics on methane explosion suppression by ultrafine water mist containing potassium oxalate[J]. CIESC Journal, 2018, 69(12): 5359-5369.

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含草酸钾的超细水雾抑制甲烷爆炸的特性

Characteristics on methane explosion suppression by ultrafine water mist containing potassium oxalate

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