化工学报 ›› 2023, Vol. 74 ›› Issue (3): 1409-1418.DOI: 10.11949/0438-1157.20221597

• 过程安全 • 上一篇    

点火方式对欠膨胀氢气射流爆炸超压影响规律研究

武子超1(), 汪志雷1(), 李荣业1, 李可昕1, 华敏1, 潘旭海1(), 王三明2, 蒋军成1   

  1. 1.南京工业大学安全科学与工程学院,江苏 南京 211816
    2.南京安元科技股份有限公司,江苏 南京 211800
  • 收稿日期:2022-12-11 修回日期:2023-01-14 出版日期:2023-03-05 发布日期:2023-04-19
  • 通讯作者: 汪志雷,潘旭海
  • 作者简介:武子超(1999—),男,硕士研究生,kk@njtech.edu.cn
  • 基金资助:
    国家自然科学基金项目(52074158);江苏省重点研发计划(社会发展)项目(BE2020729);宁夏回族自治区2022年重点研发计划高新技术领域项目(2022BEE02001)

Study on the effect of ignition mode on overpressure of underexpanded hydrogen jet explosion

Zichao WU1(), Zhilei WANG1(), Rongye LI1, Kexin LI1, Min HUA1, Xuhai PAN1(), Sanming WANG2, Juncheng JIANG1   

  1. 1.College of Safety Science and Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
    2.Nanjing Safirst Technology Co. , Ltd. , Nanjing 211800, Jiangsu, China
  • Received:2022-12-11 Revised:2023-01-14 Online:2023-03-05 Published:2023-04-19
  • Contact: Zhilei WANG, Xuhai PAN

摘要:

针对自燃点火与电火花点火对欠膨胀氢气射流燃爆超压的变化规律开展实验研究,测量了自燃和电火花两种点火方式在不同释放压力下的爆炸超压与火焰传播速率,分析了初始压力和点火条件对爆炸超压的影响机制。实验结果表明:相同释放条件下,自燃点火比电火花点火引发的管外爆炸超压峰值更高,压力上升速率更快,且自燃点火的发展过程更稳定;随着缓冲罐内释放压力从6 MPa升高到9 MPa,自燃管外爆炸超压峰值先升高后降低,在释放压力为8 MPa时自燃引发的爆炸超压达到最大值15.97 kPa,而电火花点火源处的燃爆超压随释放压力的上升从7.23 kPa先降低至3.17 kPa后升高到4.19 kPa;电火花点火火焰在点火源处形成了不规则形状点火核,同时火焰传播速度大于自燃火焰发展速度。本研究对于加氢站设计和燃爆风险评估具有参考意义。

关键词: 爆炸, 氢, 燃爆超压, 氢泄漏, 安全

Abstract:

An experimental study was carried out on the variation of overpressure of underexpanded hydrogen jet ignition by spontaneous ignition and electric spark ignition. We measured the explosion overpressure and flame propagation rate of spontaneous ignition and electric spark ignition under different release pressures, we also analyzed the influence mechanism of initial pressure and ignition conditions on explosion overpressure. The experimental results show that under the same release conditions, the overpressure peak of spontaneous ignition is higher, the pressure rise rate is faster, and the development process of spontaneous ignition is more stable. With the release pressure of the buffer tank increasing from 6 MPa to 9 MPa, the explosion overpressure peak outside the spontaneous ignition tube first increases and then decreases. When the release pressure is 8 MPa, the explosion overpressure caused by spontaneous ignition reaches the maximum value of 15.97 kPa, while the explosion overpressure at the ignition source of electric spark decreases from 7.23 kPa to 3.17 kPa and then increases to 4.19 kPa with the increase of the release pressure. The spark ignition flame forms an irregularly shaped ignition core at the ignition source, and the flame propagation velocity is greater than the spontaneous combustion flame development velocity. This study has reference significance for the design of hydrogenation station and the risk assessment of ignition and explosion.

Key words: explosion, hydrogen, explosion overpressure, hydrogen leakage, security

中图分类号: