CIESC Journal ›› 2024, Vol. 75 ›› Issue (S1): 276-282.DOI: 10.11949/0438-1157.20240342

• Energy and environmental engineering • Previous Articles     Next Articles

Experimental study on simultaneous desulfurization and denitrification of red mud at low temperature

Angran ZHAO1(), Yongqiang HAN1, Zhipeng WANG1, Pengfei LI2, Yawei XU1, Huiling TONG1()   

  1. 1.Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
    2.Central Research Institute of Building and Construction Co. , Ltd, Mcc Group, Beijing 100088, China
  • Received:2024-03-26 Revised:2024-06-25 Online:2024-12-17 Published:2024-12-25
  • Contact: Huiling TONG

常温条件下赤泥同时脱硫脱硝实验研究

赵昂然1(), 韩永强1, 王志鹏1, 李鹏飞2, 许亚伟1, 佟会玲1()   

  1. 1.清华大学能源与动力工程系,北京 100084
    2.中冶建筑研究总院有限公司,北京 100088
  • 通讯作者: 佟会玲
  • 作者简介:赵昂然(1996—),男,博士研究生,助理工程师,zar1996@qq.com
  • 基金资助:
    华能集团总部科技项目“基础能源科技研究专项(二)”(HNKJ21-H31)

Abstract:

A fixed-bed reactor was used to study the simultaneous desulfurization and denitrification of red mud at 110℃, as well as the effects of water vapor concentration and SO2 to NO ratio. The physical properties and chemical composition of red mud were measured by BET (Brunauer Emmet Teller) surface area and porosity analyzer, pH meter, laser particle size analyzer (LDSA) and ICP (inductivity coupled plasma mass spectrometry). The experimental results showed that the denitrification efficiency of red mud was 2.4 times that of Ca(OH)2. The effect of NO content in the reaction gas on the removal of SO2 was less than 15%. When the SO2 to NO ratio approached 5, the removal efficiency of NO nearly approached 100%. The optimal range for the effect of water vapor was around 10%. When the water vapor concentration was too high, the conversion and removal of NO can be affected in the early stage, while the desulfurization and denitrification in the later stage were promoted. The effective components for desulfurization and denitrification in red mud mainly included alkaline components and metal oxides.

Key words: waste treatment, absorption, fixed-bed, simultaneous desulfurization and denitrification, red mud, gas-solid reaction

摘要:

采用固定床反应器研究了赤泥在110℃条件下的同时脱硫脱硝反应性能,以及水蒸气浓度和硫硝比对其的影响。采用氮气吸附仪、pH计、电导率计、激光粒度分析仪和电感耦合等离子体质谱仪等分析手段测试了赤泥的物理性质和化学组成。实验结果表明,赤泥的脱硝效率是Ca(OH)2的2.4倍;反应气体中NO含量对SO2的脱除影响只有不到15%,而硫硝比接近5时,NO的脱除率接近100%;水蒸气的影响存在10%附近的最佳范围,浓度过高会影响前期NO的转化及脱除,但有利于后期的脱硫脱硝效果。赤泥中脱硫脱硝的有效组分包括碱性成分和金属氧化物。

关键词: 废物处理, 吸收, 固定床, 同时脱硫脱硝, 赤泥, 气固反应

CLC Number: