Absorption of CO2 in a novel ternary deep eutectic solvent

doi:10.11949/j.issn.0438-1157.20141835

Abstract

Abstract: A series of novel ternary deep eutectic solvents (TDESs) were synthesized from N, N-dimethyl acetamide (DMA), choline chloride (CC) and ethylene glycol or glycerol with different mole ratios (n_DMA:n_CC:n_{ethylene glycol}=1:1:3, 1:1:4, n_DMA:n_CC:n_glycerol=1:1:3, 1:1:4). Solubilities of CO₂ in TDESs were determined in the temperature range T=293.15—323.15 K with 10℃ intervals under pressure ranging from 0 to 600.0 kPa using the isochoric saturation method. The solubility of CO₂ in the liquids increased linearly with increasing pressure and decreased with increasing temperature. Henry's constants were calculated, while TDES obtained from DMA, CC and ethylene glycol with mole ratio 1:1:3 showing the lowest value of 2.174 MPa·kg·mol^-¹ at 293.15 K. Thermodynamics of CO₂ absorption were also calculated, including enthalpy, entropy, Gibbs free energy. The negative enthalpy demonstrated that the process was exothermic.

Key words: solubility, CO₂, ternary deep eutectic solvent, Henry's constant, thermodynamics

摘要： 由N, N-二甲基乙酰胺、氯化胆碱、乙二醇或丙三醇以不同的摩尔比(1:1:3, 1:1:4)合成了一系列三元低共熔离子液体(n_DMA:n_CC:n_{ethylene glycol}=1:1:3, 1:1:4, n_DMA:n_CC:n_glycerol=1:1:3, 1:1:4)。在293.15～323.15 K温度下, 间隔10℃, 0～600.0 kPa压力范围内, 用等温饱和法测量了CO₂在三元体系中的溶解度。CO₂在体系中的溶解度随压力增大呈线性增大趋势, 随温度升高而减小。计算了亨利常数, 结果表明, CO₂在由N, N-二甲基乙酰胺, 氯化胆碱, 乙二醇以摩尔比1:1:3合成的三元体系, 温度为293.15 K下, 亨利常数最小, 最小值为2.174 MPa·kg·mol^-1。报道了关于CO₂吸收的热动力学性质, 包括焓变、熵变、Gibbs自由能变。其中, 焓变为负值, 说明此吸收为放热过程。

关键词: 溶解度, CO₂, 三元低共熔离子液体, 亨利常数, 热动力学性质

CLC Number:

TQ420.9

LI Guihua, SHAN Haifang, AI Ning, DENG Dongshun. Absorption of CO₂ in a novel ternary deep eutectic solvent[J]. , 2015, 66(S1): 25-31.

李桂花, 单海芳, 艾宁, 邓东顺. 三元低共熔离子液体中CO₂的吸收[J]. CIESC Journal, 2015, 66(S1): 25-31.

References 34

[1]	Paul S, Ghoshal A K, Mandal B. Theoretical studies on separation of CO2 by single and blended aqueous alkanolamine solvents in flat sheet membrane contactor (FSMC) [J]. Chemical Engineering Journal, 2008, 144(3): 352-360.
[2]	Jamal A, Meisen A, Lim C J. Kinetics of carbon dioxide absorption and desorption in aqueous alkanolamine solutions using a novel hemispherical contactor(Ⅱ): Experimental results and parameter estimation [J]. Chemical Engineering Science, 2006, 61(19): 6590-6603.
[3]	Kim I, Hoff K A, Hessen E T, Warberg T H, Svendsen H F. Enthalpy of absorption of CO2 with alkanolamine solutions predicted from reaction equilibrium constants [J]. Chemical Engineering Science, 2009, 64(9): 2027-2038.
[4]	Aparicio S, Atilhan M. Computational study of hexamethylguanidinium lactate ionic liquid: a candidate for natural gas sweetening [J]. Energy Fuels, 2010, 24(9): 4989-5001.
[5]	Revelli A L, Mutelet F, Jaubert J N. Prediction of partition coefficients of organic compounds in ionic liquids: use of a linear solvation energy relationship with parameters calculated through a group contribution method [J]. Ind. Eng. Chem. Res., 2010, 49(8): 3883-3892.
[6]	Mutelet F, Revelli A L, Jaubert J N, Sprunger L M, Acree W E, Baker G A. Partition coefficients of organic compounds in new imidazolium and tetralkylammonium based ionic liquids using inverse gas chromatography [J]. J. Chem. Eng. Data, 2010, 55(1): 234-242.
[7]	Revelli A L, Mutelet F, Jaubert J N, Martinez M G, Sprunger L M, Acree W E, Baker G A. Study of ether-, alcohol-, or cyano-functionalized ionic liquids using inverse gas chromatography [J]. J. Chem. Eng. Data, 2010, 55(7): 2434-2443.
[8]	Revelli A L, Mutelet F, Jaubert J N. High carbon dioxide solubilities in imidazolium-based ionic liquids and in poly(ethylene glycol) dimethyl ether [J]. J. Phys. Chem. B, 2010, 114(40): 12908-12913.
[9]	Bara J E, Carlisle T K, Gabriel C J, Camper D, Finotello A, Gin D L, Noble R D. Guide to CO2 separations in imidazolium-based room- temperature ionic liquids [J]. Ind. Eng. Chem. Res., 2009, 48(6): 2739-2751.
[10]	Pennline H W, Luebke D R, Jones K L, Myers C R, Morsi B I, Heintz Y J, Ilconich J B. Progress in carbon dioxide capture and separation research for gasification-based power generation point sources [J]. Fuel Process Technol., 2008, 89(9): 897-907.
[11]	Goodrich B F, Fuente J C, Gurkan B E, Zadigian D J, Price E A, Huang Y, Brennecke J F. Experimental measurements of amine-functionalized anion-tethered ionic liquids with carbon dioxide [J]. Ind. Eng. Chem. Res., 2011, 50(1): 111-118.
[12]	Bates E D, Mayton R D, Ntai I, Davis J H. CO2 capture by a task-specific ionic liquid [J]. J. Am. Chem. Soc., 2002, 124(6): 926-927.
[13]	Cui Y H, Chen Y F, Deng D S, Ai N, Zhao Y. Difference for the absorption of SO2 and CO2 on [Pnnnm][Tetz] (n=1, m=2, and 4) ionic liquids: a density functional theory investigation [J]. Journal of Molecular Liquids, 2014, 199: 7-14.
[14]	Makino T, Kanakubo M, Masuda Y, Umecky T, Suzuki A. CO2 absorption properties, densities, viscosities, and electrical conductivities of ethylimidazolium and 1-ethyl-3- methylimidazoliumionic liquids [J]. Fluid Phase Equilibria, 2014, 362: 300- 306.
[15]	Kumełan J, Tuma D, Kamps A P, Maurer G. Solubility of CO2 in the ionic liquids [bmim][CH3SO4] and [bmim][PF6] [J]. J. Chem. Eng. Data, 2006, 51(5): 1802-1807.
[16]	Wang M, Zhang L Q, Liu H, Zhang J Y, Zheng C G. Studies on CO2 absorption performance by imidazole-based ionic liquid mixtures [J]. J. Fuel Chem. Technol., 2012, 40(10): 1264-1268.
[17]	Bernot R J, Kennedy E A, Lamberti G A. Effects of ionic liquids on the survival, movement, and feeding behavior of the freshwater snail [J]. Environ. Toxicol. Chem., 2005, 24(7): 1759-1765.
[18]	Latala A, Stepnowski P, Nedzi M, Mrozik W. Marine toxicity assessment of imidazolium ionic liquids: acute effects on the baltic algaeo ocystis submarina and cyclotella meneghiniana Aquat [J]. Toxicol., 2005, 73(1): 91-98.
[19]	Couling D J, Bernot R J, Docherty K M, Dixon J K, Maginn E J. Assessing the factors responsible for ionic liquid toxicity to aquatic organisms via quantitative structure-property relationship modeling [J]. Green Chem., 2006, 8(1): 82-90.
[20]	Siongco K R, Leron R B, Li M H. Densities, refractive indices, and viscosities of N, N-diethylethanol ammonium chloride- glycerol or-ethylene glycol deep eutectic solvents and their aqueous solutions [J]. J. Chem. Thermodynamics, 2013, 65: 65-72.
[21]	Li X Y, Hou M Q, Han B X, Wang X L, Zou L Z. Solubility of CO2 in a choline chloride + urea eutectic mixture [J]. J. Chem. Eng. Data, 2008, 53(2): 548-550.
[22]	Leron R B, Li M H. Solubility of carbon dioxide in a choline chloride-ethylene glycol based deep eutectic solvent [J]. Thermochimica Acta, 2013, 551: 14-19.
[23]	Leron R B, Li M H. Solubility of carbon dioxide in a eutectic mixture of choline chloride and glycerol at moderate pressures [J]. J. Chem. Thermodynamics, 2013, 57: 131-136.
[24]	María F, Adriaan V D B, Lawien F Z, Cor J P, Maaike C K. A new low transition temperature mixture (LTTM) formed by choline chloride + lactic acid: characterization as solvent for CO2 capture [J]. Fluid Phase Equilibria, 2013, 340: 77-84.
[25]	Chen Y F, Ai N, Li G H, Shan H F, Cui Y H, Deng D S. Solubilities of carbon dioxide in eutectic mixtures of choline chloride and dihydric alcohols [J]. J. Chem. Eng. Data, 2014, 59(4): 1247-1253.
[26]	Liu Y T, Chen Y A, Xing Y J. Synthesis and characterization of novel ternary deep eutectic solvents [J]. Chinese Chemical Letters, 2014, 25(1): 104-106.
[27]	Deng D S, Cui Y H, Chen D, Ai N. Solubility of CO2 in amide-based brønsted acidic ionic liquids [J]. J. Chem. Thermodyn., 2013, 57: 355-359.
[28]	Jacquemin J, Costa Gomes M F, Husson P, Majer V. Solubility of carbon dioxide, ethane, methane, oxygen, nitrogen, hydrogen, argon, and carbon monoxide in 1-butyl-3-methylimidazolium tetrafluoroborate between temperatures 283 K and 343 K and at pressures close to atmospheric [J]. J. Chem. Thermodyn., 2006, 38(4): 490-502.
[29]	Hasib-ur-Rahman M, Siaj M, Larachi F. Ionic liquids for CO2 capture-development and progress [J]. Chem. Eng. Process., 2010, 49(4): 313-322.
[30]	Zhang N, Zhang J B, Zhang Y F, Bai J, Wei X. H. Solubility and Henry's law constant of sulfur dioxide in aqueous polyethylene glycol 300 solution at different temperatures and pressures [J]. Fluid Phase Equilibria, 2013, 348: 9-16.
[31]	Cadena C, Anthony J L, Shah J K, Morrow T I, Brennecke J F, Maginn E J. Why is CO2 so soluble in imidazolium-based ionic liquids? [J]. J. Am. Chem. Soc., 2004, 126(16): 5300-5308.
[32]	Smith J M, van Ness H C, Abbott M M. Introduction to themical engineering thermodynamics (seventh edition) [R]. New York: Mc-Graw Hill, 2005.
[33]	Li G H, Deng D S, Chen Y F, Shan H F, Ai N. Solubilities and thermodynamic properties of CO2 in choline-chloride based deep eutectic solvents [J]. J. Chem. Thermodynamics, 2014, 75: 58-62.
[34]	Anthony J L, Maginn E J, Brennecke J F. Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate [J]. J. Phys. Chem. B, 2002, 106(29): 7315-7320.

Absorption of CO₂ in a novel ternary deep eutectic solvent

三元低共熔离子液体中CO₂的吸收

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 34

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xin YANG, Wen WANG, Kai XU, Fanhua MA. Simulation analysis of temperature characteristics of the high-pressure hydrogen refueling process [J]. CIESC Journal, 2023, 74(S1): 280-286.
[2]	Minghui CHANG, Lin WANG, Jiajia YUAN, Yifei CAO. Study on the cycle performance of salt solution-storage-based heat pump [J]. CIESC Journal, 2023, 74(S1): 329-337.
[3]	Chao HU, Yuming DONG, Wei ZHANG, Hongling ZHANG, Peng ZHOU, Hongbin XU. Preparation of high-concentration positive electrolyte of vanadium redox flow battery by activating vanadium pentoxide with highly concentrated sulfuric acid [J]. CIESC Journal, 2023, 74(S1): 338-345.
[4]	Baomin DAI, Qilong WANG, Shengchun LIU, Jianing ZHANG, Xinhai LI, Fandi ZONG. Thermodynamic performance analysis of combined cooling and heating system based on combination of CO₂ with the zeotropic refrigerant assisted subcooled [J]. CIESC Journal, 2023, 74(S1): 64-73.
[5]	Tianyang YANG, Huiming ZOU, Hui ZHOU, Chunlei WANG, Changqing TIAN. Experimental investigation on heating performance of vapor-injection CO₂ heat pump for electric vehicles at -30℃ [J]. CIESC Journal, 2023, 74(S1): 272-279.
[6]	Jianbo HU, Hongchao LIU, Qi HU, Meiying HUANG, Xianyu SONG, Shuangliang ZHAO. Molecular dynamics simulation insight into translocation behavior of organic cage across the cellular membrane [J]. CIESC Journal, 2023, 74(9): 3756-3765.
[7]	Meisi CHEN, Weida CHEN, Xinyao LI, Shangyu LI, Youting WU, Feng ZHANG, Zhibing ZHANG. Advances in silicon-based ionic liquid microparticle enhanced gas capture and conversion [J]. CIESC Journal, 2023, 74(9): 3628-3639.
[8]	Feifei YANG, Shixi ZHAO, Wei ZHOU, Zhonghai NI. Sn doped In₂O₃ catalyst for selective hydrogenation of CO₂ to methanol [J]. CIESC Journal, 2023, 74(8): 3366-3374.
[9]	Xudong YU, Qi LI, Niancu CHEN, Li DU, Siying REN, Ying ZENG. Phase equilibria and calculation of aqueous ternary system KCl + CaCl₂ + H₂O at 298.2, 323.2, and 348.2 K [J]. CIESC Journal, 2023, 74(8): 3256-3265.
[10]	Manzheng ZHANG, Meng XIAO, Peiwei YAN, Zheng MIAO, Jinliang XU, Xianbing JI. Working fluid screening and thermodynamic optimization of hazardous waste incineration coupled organic Rankine cycle system [J]. CIESC Journal, 2023, 74(8): 3502-3512.
[11]	Guixian LI, Abo CAO, Wenliang MENG, Dongliang WANG, Yong YANG, Huairong ZHOU. Process design and evaluation of CO₂ to methanol coupled with SOEC [J]. CIESC Journal, 2023, 74(7): 2999-3009.
[12]	Lei MAO, Guanzhang LIU, Hang YUAN, Guangya ZHANG. Efficient preparation of carbon anhydrase nanoparticles capable of capturing CO₂ and their characteristics [J]. CIESC Journal, 2023, 74(6): 2589-2598.
[13]	Xueyan WEI, Yong QIAN. Experimental study on the low to medium temperature oxidation characteristics and kinetics of micro-size iron powder [J]. CIESC Journal, 2023, 74(6): 2624-2638.
[14]	Ke CHEN, Li DU, Ying ZENG, Siying REN, Xudong YU. Phase equilibria and calculation of quaternary system LiCl+MgCl₂+CaCl₂+H₂O at 323.2 K [J]. CIESC Journal, 2023, 74(5): 1896-1903.
[15]	Hao WANG, Siyang TANG, Shan ZHONG, Bin LIANG. An investigation of the enhancing effect of solid particle surface on the CO₂ desorption behavior in chemical sorption process with MEA solution [J]. CIESC Journal, 2023, 74(4): 1539-1548.