Effect of different amino modified conditions on carbon dioxide adsorption of NH2-MIL-53(Al)

doi:10.3969/j.issn.0438-1157.2014.05.053

CIESC Journal

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Effect of different amino modified conditions on carbon dioxide adsorption of NH₂-MIL-53(Al)

YANG Zhuhong¹, WU Peipei¹, ZHANG Suoying¹, LIU Hong¹, LIU Pengfei¹, YANG Qingyuan², LU Xiaohua¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China;
2 State Key Laboratory of Organic-Inorganic Composites, School of Chemistry and Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2014-01-02 Revised:2014-03-10 Online:2014-05-05 Published:2014-05-05
Supported by:
supported by the National Basic Research Program of China(2013CB733503), the National Natural Science Foundation of China(21136001) and the National High Technology Research and Development Program of China(2006AA03Z455).

不同氨基修饰条件对NH₂-MIL-53(Al)CO₂吸附性能的影响

杨祝红¹, 吴培培¹, 张所瀛¹, 刘红¹, 刘朋飞¹, 阳庆元², 陆小华¹

1 南京工业大学化学化工学院, 材料化学工程国家重点实验室, 江苏南京 210009;
2 北京化工大学有机无机复合材料国家重点实验室, 北京 100029

通讯作者: 杨祝红
基金资助:
国家重点基础研究发展计划项目（2013CB733503）；国家自然科学基金项目（21136001）；国家高技术研究发展计划项目（2006AA03Z455）。

Abstract

Abstract: With the hydrothermal synthesis method, MIL-53(Al) of different amino contents was prepared by changing the content of 2-amino terephthalic acid in ligands. The CO₂ adsorption of NH₂-MIL-53(Al) was investigated by varing the content, type of amino group and amino functional methods to improve the CO₂ capture performance of MIL-53(Al). The synthesized materials were characterized with XRD, TG, infrared spectroscopy and N₂adsorption measurements, and the adsorption performance of NH₂-MIL-53 towards CO₂was also investigated on the basis of the adsorption isotherms. The IR results indicated that the peak of —NH₂ was found in the range of 3500—3900 cm^-1, demonstrating that amino group was loaded successfully. The performance of CO₂ adsorption kept fitting with the amino group content of NH₂-MIL-53(Al), and when amino group content was 100%, better CO₂ adsorption than MIL-53(Al) prepared directly was observed. In addition, when MEA, DBU and MMEN were used for post-synthesis modifications, they all could not improve the adsorption performance of NH₂-MIL-53(Al) towards CO₂.

Key words: metal-organic framework, NH₂-MIL-53(Al), synthesis, CO₂ capture, adsorption, functionalization, amino contents, amino types

摘要： 采用水热合成法，通过改变配体中2-氨基对苯二甲酸的含量制备了不同氨基含量的NH₂-MIL-53（Al），考察了氨基含量，氨基功能化方法和氨基种类对NH₂-MIL-53（Al）的CO₂吸附性能的影响。傅里叶变换红外光谱表征（IR）发现在3500～3900 cm^-1处存在—NH₂基的伸缩振动带，氨基修饰成功。低压下，NH₂-MIL-53（Al）的CO₂吸附容量随氨基含量的增加而增大，且当氨基含量100%时，其CO₂吸附性能优于直接合成的NH₂-MIL-53（Al）。合成前修饰比合成后修饰，更有利于提高CO₂吸附容量。采用乙醇胺、1，8-二氮杂二环[5.4.0]十一碳-7-烯、N，N'-二亚乙基三胺进行后氨基功能化都不能提高MIL-53的CO₂吸附能力。

关键词: 金属有机骨架材料, NH₂-MIL-53(Al), 合成, CO₂捕集, 吸附, 功能化, 氨基含量, 氨基种类

CLC Number:

YANG Zhuhong, WU Peipei, ZHANG Suoying, LIU Hong, LIU Pengfei, YANG Qingyuan, LU Xiaohua. Effect of different amino modified conditions on carbon dioxide adsorption of NH₂-MIL-53(Al)[J]. CIESC Journal, DOI: 10.3969/j.issn.0438-1157.2014.05.053.

杨祝红, 吴培培, 张所瀛, 刘红, 刘朋飞, 阳庆元, 陆小华. 不同氨基修饰条件对NH₂-MIL-53(Al)CO₂吸附性能的影响[J]. 化工学报, DOI: 10.3969/j.issn.0438-1157.2014.05.053.

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Effect of different amino modified conditions on carbon dioxide adsorption of NH₂-MIL-53(Al)

不同氨基修饰条件对NH₂-MIL-53(Al)CO₂吸附性能的影响

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