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Kinetics of Photocatalytic Degradation of Methylene Blue overTiO2 Particles in Aqueous
Suspensions

SHI Zaifeng, FAN Yiqun, XU Nanping; SHI Jun   

  1. Membrane Science & Technology Research Center, Nanjing University ofChemical Technology,
    Nanjing 210009, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2000-03-28 Published:2000-03-28
  • Contact: SHI Zaifeng

Kinetics of Photocatalytic Degradation of Methylene Blue overTiO2 Particles in Aqueous
Suspensions

史载锋; 范益群; 徐南平; 时钧   

  1. Membrane Science & Technology Research Center, Nanjing University ofChemical Technology,
    Nanjing 210009, China
  • 通讯作者: 史载锋

Abstract: The kinetics of photodegradation of methylene blue over UV lightilluminated titania
particles in aqueous suspensions has been studied withdifferent initial methylene blue
concentrations and TiO2 particle sizes. The degradationrate increases with the decrease of
initial concentration and particlesize. A quasi-experienced model for photodegradation rate
is derivedbased mainly on the coinstantaneous effects of different initialconcentrations
and particle sizes. The mathematical relationships ofmodel parameters with initial
concentration and particle size are given.The model results of the photodegradation rate of
methylene blue arecoincident with the experimental data.

Key words: kinetics, photocatalytic, titaniaminipage

摘要: The kinetics of photodegradation of methylene blue over UV lightilluminated titania
particles in aqueous suspensions has been studied withdifferent initial methylene blue
concentrations and TiO2 particle sizes. The degradationrate increases with the decrease of
initial concentration and particlesize. A quasi-experienced model for photodegradation rate
is derivedbased mainly on the coinstantaneous effects of different initialconcentrations
and particle sizes. The mathematical relationships ofmodel parameters with initial
concentration and particle size are given.The model results of the photodegradation rate of
methylene blue arecoincident with the experimental data.

关键词: kinetics;photocatalytic;titaniaminipage