Performance of amine functionalized mesoporous adsorbents for CO2 adsorption

doi:10.11949/j.issn.0438-1157.20180336

Abstract

Abstract:

Amine-functionalized nanomaterials have significant potential in CO₂ capture technology because of their low energy consumption, stable performance, and high regeneration capacity. To improve the CO₂ adsorption capacity, the high surface and mesoporous SBA-15 was used as the support for amine modification and CO₂ adsorption. The adsorbents prepared with different modified methods, amines and amine content were characterized by using the BET, XRD, FT-IR, thermo-gravimetric analysis, and TG adsorption test technologies. The adsorption results showed that the grafting of mixed amine modified APTES-SBA (U)-T60 with a high adsorption capacity of 192.05 mg/g under pure CO₂ at 75℃, which is higher than that of solvent extraction and calcination method. Mixed amine modified adsorbents exhibited a high thermal stability and reproducibility.

Key words: carbon dioxide, carbon dioxide capture, adsorbents, amine functionalization

摘要：

针对当前固体胺CO₂吸附剂存在吸附容量小、循环稳定性差等问题，采用高比表面积、易嫁接胺的介孔SBA-15作为载体，研究分子筛模板剂脱除方法和有机胺改性方法对制备的固体吸附剂吸附性能的影响，并采用N₂物理吸附、X射线衍射、红外光谱、热失重分析等表征技术并对样品进行表征。实验结果表明，通过嫁接和浸渍能够合成出不同有机胺负载量的胺功能化吸附剂，其中混合胺嫁接法改性的APTES-SBA（U）-T60吸附剂其吸附容量最大，在75℃下的纯CO₂气氛中吸附量达到192.05 mg/g，优于溶剂萃取和煅烧法去除模板剂。此外，混合胺嫁接法制备的样品在多次的吸/脱附操作下，CO₂吸附稳定性良好，表明混合胺修饰的吸附剂具有很好的稳定性和再生性。

关键词: 二氧化碳, 二氧化碳捕集, 吸附剂, 胺功能化

CLC Number:

TQ116.2

HE Kaiwu, TANG Siyang, LIU Changjun, YUE Hairong, LIANG Bin. Performance of amine functionalized mesoporous adsorbents for CO₂ adsorption[J]. CIESC Journal, 2018, 69(9): 3887-3895.

何凯武, 唐思扬, 刘长军, 岳海荣, 梁斌. 有机胺功能化介孔固体吸附剂吸附分离CO₂性能研究[J]. 化工学报, 2018, 69(9): 3887-3895.

References 37

[1]	SAMANTA A, ZHAO A, SHIMIZU G K H, et al. Post-combustion co2 capture using solid sorbents:a review[J]. Industrial & Engineering Chemistry Research, 2011, 51(4):1438-1463.
[2]	靖宇, 韦力, 王运东, 等. 混合胺改性SBA-15的二氧化碳吸附特性[J]. 化工学报, 2014, 65(1):328-336. JING Y, WEI L, WANG Y D, et al. Mixed-amine functionalized SBA-15 for CO2 adsorption[J]. CIESC Journal, 2014, 65(1):328-336.
[3]	靖宇, 韦力, 王运东. 吸附法捕集二氧化碳吸附剂的研究进展[J].化工进展, 2011, (S2):133-138. JING Y, WEI L, WANG Y D. The advances of adsorbents in the field of CO2 capture[J]. Chemical Industry and Engineering Progress, 2011, (S2):133-138.
[4]	SUMIDA K, ROGOW D L, MASON J A, et al. Carbon dioxide capture in metal-organic frameworks[J]. Chemical Reviews, 2012, 112(2):724-781.
[5]	WANG J, YANG J, KRISHNA R, et al. A versatile synthesis of metal-organic framework-derived porous carbons for CO2 capture and gas separation[J]. Journal of Materials Chemistry A, 2016, 4(48):19095-19106.
[6]	魏建文, 林志峰, 何泽瑜, 等. 蔗渣活性炭二次活化制备及其吸附CO2性能研究[J]. 无机材料学报, 2017, 32(1):18-24. WEI J W, LIN Z F, HE Z Y, et al. Bagasse activated carbon reactivation promotes adsorption of CO2[J]. Journal of Inorganic Materials, 2017, 32(1):18-24.
[7]	HUANG H Y, YANG R T, CHINN D, et al. Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas[J]. Industrial & Engineering Chemistry Research, 2003, 42(12):2427-2433.
[8]	XU X, SONG C, MILLER B G, et al. Influence of moisture on CO2 separation from gas mixture by a nanoporous adsorbent based on polyethylenimine-modified molecular sieve MCM-41[J]. Industrial & Engineering Chemistry Research, 2005, 44(21):8113-8119.
[9]	XU X, SONG C, ANDRESEN J M, et al. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture[J]. Energy & Fuels, 2002, 16(6):1463-1469.
[10]	CHEN H, LIANG Z, YANG X, et al. Experimental investigation of CO2 capture capacity:exploring mesoporous silica SBA-15 material impregnated with monoethanolamine and diethanolamine[J]. Energy & Fuels, 2016, 30(11):9554-9562.
[11]	LIU S H, LIN Y C, CHIEN Y C, et al. Adsorption of CO2 from flue gas streams by a highly efficient and stable aminosilica adsorbent[J]. Air & Waste, 2011, 61(2):226-233.
[12]	KISHOR R, GHOSHAL A K. Amine modified mesoporous silica for CO2 adsorption:the role of structural parameters[J]. Industrial & Engineering Chemistry Research, 2017, 56(20):6078-6087.
[13]	FAYAZ M, SAYARI A. Long-term effect of steam exposure on CO2 capture performance of amine-grafted silica[J]. ACS Applied Materials & Interfaces, 2017, 9(50):43747-43754.
[14]	RAO N, WANG M, SHANG Z, et al. CO2 adsorption by amine-functionalized MCM-41:a comparison between impregnation and grafting modification methods[J]. Energy & Fuels, 2018, 32(1):670-677.
[15]	BHAGIYALAKSHMI M, YUN L J, ANURADHA R, et al. Synthesis of chloropropylamine grafted mesoporous MCM-41, MCM-48 and SBA-15 from rice husk ash:their application to CO2 chemisorption[J]. Journal of Porous Materials, 2010, 17(4):475-484.
[16]	RAJESH A K, STEVEN S C C, YEE S, et al. Thermal and chemical stability of regenerable solid amine sorbent for CO2 capture[J]. Energy & Fuels, 2006, 20(4):1514-1520.
[17]	WANG L, YANG R T. Increasing selective CO2 adsorption on amine-grafted SBA-15 by increasing silanol density[J]. Journal of Physical Chemistry C, 2011, 115(43):21264-21272.
[18]	LI Y, SUN N, LI L, et al. Grafting of amines on ethanol-extracted SBA-15 for CO2 adsorption[J]. Materials, 2013, 6(3):981-999.
[19]	KLINTHONG W, CHAO K J, TAN C S. CO2 capture by as-synthesized amine-functionalized MCM-41 prepared through direct synthesis under basic condition[J]. Industrial & Engineering Chemistry Research, 2013, 52(29):9834-9842.
[20]	CHOI S, GRAY M L, JONES C W. Amine-tethered solid adsorbents coupling high adsorption capacity and renderability for CO2 capture from ambient air[J]. ChemSusChem, 2011, 4(5):628-635.
[21]	FUJIKI J, YAMADA H, YOGO K. Enhanced adsorption of carbon dioxide on surface-modified mesoporous silica-supported tetraethylenepentamine:role of surface chemical structure[J]. Microporous & Mesoporous Materials, 2015, 215(6):76-83.
[22]	JUNG H, LEE C H, JEON S, et al. Effect of amine double-functionalization on CO2 adsorption behaviors of silica gel-supported adsorbents[J]. Adsorption, 2016, 22(8):1137-1146.
[23]	SANZ R, CALLEJA G, ARENCIBIA A, et al. CO2 uptake and adsorption kinetics of pore-expanded SBA-15 double-functionalized with amino groups[J]. Energy & Fuels, 2013, 27(12):7637-7644.
[24]	HU H, ZHANG T, YUAN S, et al. Functionalization of multi-walled carbon nanotubes with phenylenediamine for enhanced CO2 adsorption[J]. Adsorption, 2017, 23(1):73-85.
[25]	丁志杰, 陈君华, 郭雨, 等. HNO3氧化脱除SBA-15中有机模板剂的研究[J]. 硅酸盐通报, 2009, 28(4):704-708. DING Z J, CHEN J H, GUO Y, et al. Study on removing organic template from SBA-15 by HNO3 oxidation treatment[J]. Bulletin of the Chinese Ceramic Society, 2009, 28(4):704-708.
[26]	苏赵辉, 陈启元, 李洁, 等. W掺杂SiO2介孔材料的制备与表征[J]. 物理化学学报, 2007, 23(11):1760-1764. SU Z H, CHEN Q Y, LI J, et al. Preparation and characterization of mesoporous silicon dioxide doped with tungsten[J]. Acta Physico-Chimica Sinica, 2007, 23(11):1760-1764.
[27]	KISHOR R, GHOSHAL A K. Polyethylenimine functionalized as-synthesized KIT-6 adsorbent for highly CO2/N2 selective separation[J]. Energy & Fuels, 2016, 30(11):9635-9644.
[28]	KUWAHARA Y, KANG D Y, COPELAND J R, et al. Dramatic enhancement of CO2 uptake by poly(ethyleneimine) using zirconosilicate supports[J]. Journal of the American Chemical Society, 2012, 134(26):10757-10760.
[29]	KUWAHARA Y, KANG D Y, COPELAND J R, et al. Enhanced CO2 adsorption over polymeric amines supported on heteroatom-incorporated SBA-15 silica:impact of heteroatom type and loading on sorbent structure and adsorption performance[J]. Chemistry-A European Journal, 2012, 18(52):16649-16664.
[30]	AHN H, MOON J H, HYUN S H, et al. Diffusion mechanism of carbon dioxide in zeolite 4A and CaX pellets[J]. Adsorption, 2004, 10(2):111-128.
[31]	NEWALKAR B L, CHOUDARY N V, TURAGA U T, et al. Adsorption of light hydrocarbons on HMS type mesoporous silica[J]. Microporous & Mesoporous Materials, 2003, 65(2):267-276.
[32]	DO D D. Adsorption Analysis:Equilibria and Kinetics[M]. London:Imperial College Press, 1998.
[33]	ZHANG X, QIN H, ZHENG X, et al. Development of efficient amine-modified mesoporous silica SBA-15 for CO2 capture[J]. Materials Research Bulletin, 2013, 48(10):3981-3986.
[34]	LIU Z L, TENG Y, ZHANG K, et al. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. Journal of Fuel Chemistry & Technology, 2013, 41(4):469-475.
[35]	SAYARI A, HEYDARIGORJI A, YANG Y. CO2-induced degradation of amine-containing adsorbents:reaction products and pathways[J]. Journal of the American Chemical Society, 2012, 134(33):13834-13842.
[36]	DIDAS S A, ZHU R, BRUNELLI N A, et al. Thermal, oxidative and CO2 induced degradation of primary amines used for CO2 capture:effect of alkyl linker on stability[J]. Journal of Physical Chemistry C, 2014, 118(23):12302-12311.
[37]	REZAEI F, LIVELY R P, LABRECHE Y, et al. Aminosilane-grafted polymer/silica hollow fiber adsorbents for CO2 capture from flue gas[J]. ACS Applied Materials & Interfaces, 2013, 5(9):3921-3931.

Performance of amine functionalized mesoporous adsorbents for CO₂ adsorption

有机胺功能化介孔固体吸附剂吸附分离CO₂性能研究

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 37

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ruitao SONG, Pai WANG, Yunpeng WANG, Minxia LI, Chaobin DANG, Zhenguo CHEN, Huan TONG, Jiaqi ZHOU. Numerical simulation of flow boiling heat transfer in pipe arrays of carbon dioxide direct evaporation ice field [J]. CIESC Journal, 2023, 74(S1): 96-103.
[2]	Yifei ZHANG, Fangchen LIU, Shuangxing ZHANG, Wenjing DU. Performance analysis of printed circuit heat exchanger for supercritical carbon dioxide [J]. CIESC Journal, 2023, 74(S1): 183-190.
[3]	Xuejin YANG, Jintao YANG, Ping NING, Fang WANG, Xiaoshuang SONG, Lijuan JIA, Jiayu FENG. Research progress in dry purification technology of highly toxic gas PH₃ [J]. CIESC Journal, 2023, 74(9): 3742-3755.
[4]	Yepin CHENG, Daqing HU, Yisha XU, Huayan LIU, Hanfeng LU, Guokai CUI. Application of ionic liquid-based deep eutectic solvents for CO₂ conversion [J]. CIESC Journal, 2023, 74(9): 3640-3653.
[5]	Rui HONG, Baoqiang YUAN, Wenjing DU. Analysis on mechanism of heat transfer deterioration of supercritical carbon dioxide in vertical upward tube [J]. CIESC Journal, 2023, 74(8): 3309-3319.
[6]	Qiyu ZHANG, Lijun GAO, Yuhang SU, Xiaobo MA, Yicheng WANG, Yating ZHANG, Chao HU. Recent advances in carbon-based catalysts for electrochemical reduction of carbon dioxide [J]. CIESC Journal, 2023, 74(7): 2753-2772.
[7]	Chenxi LI, Yongfeng LIU, Lu ZHANG, Haifeng LIU, Jin’ou SONG, Xu HE. Quantum chemical analysis of n-heptane combustion mechanism under O₂/CO₂ atmosphere [J]. CIESC Journal, 2023, 74(5): 2157-2169.
[8]	Caihong LIN, Li WANG, Yu WU, Peng LIU, Jiangfeng YANG, Jinping LI. Effect of alkali cations in zeolites on adsorption and separation of CO₂/N₂O [J]. CIESC Journal, 2023, 74(5): 2013-2021.
[9]	Bingguo ZHU, Jixiang HE, Jinliang XU, Bin PENG. Heat transfer characteristics of supercritical pressure CO₂ in diverging/converging tube under cooling conditions [J]. CIESC Journal, 2023, 74(3): 1062-1072.
[10]	Renchu HE, Zhaohui ZHANG, Minglei YANG, Cong WANG, Zhenhao XI. Online optimization of gasoline blending considering carbon emissions [J]. CIESC Journal, 2023, 74(2): 818-829.
[11]	Min LI, Xueru YAN, Xinlei LIU. Advances in benzimidazole-linked polymer adsorbents and membranes [J]. CIESC Journal, 2023, 74(2): 599-616.
[12]	Chenyang SHEN, Kaihang SUN, Yueping ZHANG, Changjun LIU. Research progresses on In₂O₃ and In₂O₃ supported metal catalysts for CO₂ hydrogenation to methanol [J]. CIESC Journal, 2023, 74(1): 145-156.
[13]	Zhenyu LIU. Origin of low productivity of underground coal gasification: diffusion and reaction in stagnant boundary layer and gasification tunnel [J]. CIESC Journal, 2022, 73(8): 3299-3306.
[14]	Lei WANG, Yong JIANG, Dazhong ZHONG, Jiayuan LI, Genyan HAO, Qiang ZHAO, Jinping LI. Carbonized metal-organic framework for carbon dioxide reduction to ethylene and ethanol [J]. CIESC Journal, 2022, 73(8): 3576-3585.
[15]	Dan GUO, Yujie FANG, Yihan XU, Zhiyuan LI, Shouying HUANG, Shengping WANG, Xinbin MA. Research progress of the catalytic conversion of ethane and carbon dioxide [J]. CIESC Journal, 2022, 73(8): 3406-3416.