CIESC Journal ›› 2021, Vol. 72 ›› Issue (6): 3014-3021.DOI: 10.11949/0438-1157.20201711
• Special column for comprehensive utilization of salt lake resouces in Qinghai • Previous Articles Next Articles
LI Enze1(),YE Peiyuan1,WANG Yaxin1,KANG Jin1,YIN Caixia2,CHENG Fangqin1()
Received:
2020-11-30
Revised:
2021-03-05
Online:
2021-06-05
Published:
2021-06-05
Contact:
CHENG Fangqin
李恩泽1(),叶培远1,王亚欣1,康锦1,阴彩霞2,程芳琴1()
通讯作者:
程芳琴
作者简介:
李恩泽(1988—),男,博士,副教授,基金资助:
CLC Number:
LI Enze, YE Peiyuan, WANG Yaxin, KANG Jin, YIN Caixia, CHENG Fangqin. Synthesis and properties of solvent polar responsive butyl-cyclic tetrapyridine molecule for lithium extraction[J]. CIESC Journal, 2021, 72(6): 3014-3021.
李恩泽, 叶培远, 王亚欣, 康锦, 阴彩霞, 程芳琴. 溶剂极性响应型丁基-环四联吡啶提锂分子的合成及性能研究[J]. 化工学报, 2021, 72(6): 3014-3021.
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Fig.1 The synthetic route of butyl tetrapyridine, reversible changes of molecular structure under different solvent polarity and schematic complexion of lithium ion
Fig.7 The UV-Vis absorption spectra of compound C in the presence of Li+ or Mg2+ in 1,4-dioxan aqueous solution (LiCl and MgCl2 were used as salts, both the concentrations of Li+ and Mg2+ were 6×10-2 mol/L, the volume ratio of 1,4-dioxane to H2O was 1∶1)
Fig.8 HRMS spectrum of compound C in the presence of Li+ or Mg2+ in 1,4-dioxan aqueous solution (the concentration of compound C was 1×10-6 mol/L, the volume ratio of 1,4-dioxane to H2O was 1∶1)
离子 | 接收相增加质量(m接)/mg | 原料相剩余质量(m原)/mg | 分配系数(Kd) | 选择性分离因子(α) |
---|---|---|---|---|
Li+ | 3.553 | 63.946 | 0.056 | 56 |
Mg2+ | 0.069 | 67.430 | 0.001 |
Table 1 The partition coefficient and selective separation factor of Li+ and Mg2+ after membrane transport
离子 | 接收相增加质量(m接)/mg | 原料相剩余质量(m原)/mg | 分配系数(Kd) | 选择性分离因子(α) |
---|---|---|---|---|
Li+ | 3.553 | 63.946 | 0.056 | 56 |
Mg2+ | 0.069 | 67.430 | 0.001 |
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