Development and prospect of pivotal materials and technologies in sodium-ion batteries

doi:10.11949/0438-1157.20220728

Abstract

Abstract:

Due to the advantages of large reserves, low cost and high safety by sodium-ion battery, it is an effective substitute for lithium-ion battery. To a certain extent, sodium-ion battery can alleviate the limited development of energy storage battery by the shortage of lithium resources. This review not only has combed and analyzed the research status, challenges and future development trend as well as has selected the latest frontier overview of sodium-ion batteries, including cathode, anode and advanced characterization technology and so on, but also has discussed the current research hotspots of sodium-ion batteries, as to find the latest research hotspots and development trends and promote the efficient development of sodium-ion batteries. It is hoped that this paper can provide some enlightenment for the exploration and development of sodium-ion batteries.

Key words: sodium-ion battery, frontier progress, cathode materials, anode materials, characterization technology

摘要：

钠离子电池因其储量大、成本低和高安全性等优势，成为锂离子电池的有效替代品，可在一定程度上缓解锂资源短缺引发的储能电池发展受限问题。本文对钠离子电池发展现状、面临的挑战以及未来发展趋势进行梳理分析，并精选钠离子电池最新前沿综述，包括正极材料、负极材料和先进表征技术等，探讨当前钠离子电池的研究热点，为新能源材料领域技术研究提供参考。

关键词: 钠离子电池, 前沿进展, 正极材料, 负极材料, 表征技术

CLC Number:

O 646

Liubin SONG, Yixuan WANG, Yinjie KUANG, Yubo XIA, Zhongliang XIAO. Development and prospect of pivotal materials and technologies in sodium-ion batteries[J]. CIESC Journal, 2022, 73(11): 4814-4825.

宋刘斌, 王怡萱, 匡尹杰, 夏宇博, 肖忠良. 钠离子电池中关键材料及技术的发展与前景[J]. 化工学报, 2022, 73(11): 4814-4825.

Figures/Tables 7

Table 1 Comparison of properties for sodium and lithium

性质	钠	锂
离子半径/nm	0.102	0.076
原子量	22.99	6.94
密度/(g·cm^-3)	0.534	0.971
标准电极电势/V	-2.71	-3.04
比容量/(mA·h·g^-1)	1166	3862
丰度/%	2.83	0.006

Fig.1 Research trend of domestic sodium-ion battery from 1st January, 2013 to 10th April, 2021

Fig.2 Research trend of domestic and foreign sodium-ion battery from 1st January, 2013 to 10th April, 2021

Fig.3 The number of published papers on cobalt-free cathodes and cobalt-containing cathodes of SIBs from 2010 to 2020[71]

Fig.4 A comparison of the electrochemical stability of Mn/Fe/Ni/Cr/V-based cathodes[71]

Fig.5 Performance comparison between the PSM cathodes and other polyanionic cathodes in sodium full-cell[13]

Fig.6 Categories of energy storage mechanisms of organic electrodes in SIBs[96]

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