CIESC Journal ›› 2018, Vol. 69 ›› Issue (9): 3887-3895.DOI: 10.11949/j.issn.0438-1157.20180336

Previous Articles     Next Articles

Performance of amine functionalized mesoporous adsorbents for CO2 adsorption

HE Kaiwu1, TANG Siyang1, LIU Changjun1, YUE Hairong1,2, LIANG Bin1,2   

  1. 1. College of Chemical engineering, Sichuan University, Chengdu 610065, Sichuan, China;
    2. Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610065, Sichuan, China
  • Received:2018-03-30 Revised:2018-06-25 Online:2018-09-05 Published:2018-09-05
  • Supported by:

    supported by the National Key R&D Program of China (2018YFB0605700) and the China Petrochemical Corporation (15H0493).

有机胺功能化介孔固体吸附剂吸附分离CO2性能研究

何凯武1, 唐思扬1, 刘长军1, 岳海荣1,2, 梁斌1,2   

  1. 1. 四川大学化学工程学院, 四川 成都 610065;
    2. 四川大学新能源与低碳技术研究院, 四川 成都 610065
  • 通讯作者: 岳海荣
  • 基金资助:

    国家重点研发计划项目(2018YFB0605700);中国石油化工股份公司合作项目(15H0493)。

Abstract:

Amine-functionalized nanomaterials have significant potential in CO2 capture technology because of their low energy consumption, stable performance, and high regeneration capacity. To improve the CO2 adsorption capacity, the high surface and mesoporous SBA-15 was used as the support for amine modification and CO2 adsorption. The adsorbents prepared with different modified methods, amines and amine content were characterized by using the BET, XRD, FT-IR, thermo-gravimetric analysis, and TG adsorption test technologies. The adsorption results showed that the grafting of mixed amine modified APTES-SBA (U)-T60 with a high adsorption capacity of 192.05 mg/g under pure CO2 at 75℃, which is higher than that of solvent extraction and calcination method. Mixed amine modified adsorbents exhibited a high thermal stability and reproducibility.

Key words: carbon dioxide, carbon dioxide capture, adsorbents, amine functionalization

摘要:

针对当前固体胺CO2吸附剂存在吸附容量小、循环稳定性差等问题,采用高比表面积、易嫁接胺的介孔SBA-15作为载体,研究分子筛模板剂脱除方法和有机胺改性方法对制备的固体吸附剂吸附性能的影响,并采用N2物理吸附、X射线衍射、红外光谱、热失重分析等表征技术并对样品进行表征。实验结果表明,通过嫁接和浸渍能够合成出不同有机胺负载量的胺功能化吸附剂,其中混合胺嫁接法改性的APTES-SBA(U)-T60吸附剂其吸附容量最大,在75℃下的纯CO2气氛中吸附量达到192.05 mg/g,优于溶剂萃取和煅烧法去除模板剂。此外,混合胺嫁接法制备的样品在多次的吸/脱附操作下,CO2吸附稳定性良好,表明混合胺修饰的吸附剂具有很好的稳定性和再生性。

关键词: 二氧化碳, 二氧化碳捕集, 吸附剂, 胺功能化

CLC Number: