CIESC Journal ›› 2020, Vol. 71 ›› Issue (6): 2889-2899.DOI: 10.11949/0438-1157.20200075
• Material science and engineering, nanotechnology • Previous Articles Next Articles
Yongsheng WANG(),Xiaolin LAN,Tian QIU,Xinping ZHANG,Yingying WU,Li CHEN,Weixiang XU,Dongjie GUO,Zhengkang DUAN()
Received:
2020-01-17
Revised:
2020-03-30
Online:
2020-06-05
Published:
2020-06-05
Contact:
Zhengkang DUAN
王永胜(),兰小林,邱天,张新平,吴莹莹,陈莉,徐伟祥,郭栋杰,段正康()
通讯作者:
段正康
作者简介:
王永胜(1995—),男,硕士研究生,基金资助:
CLC Number:
Yongsheng WANG, Xiaolin LAN, Tian QIU, Xinping ZHANG, Yingying WU, Li CHEN, Weixiang XU, Dongjie GUO, Zhengkang DUAN. Synthesis and characterization of copper-based graphene composite catalyst[J]. CIESC Journal, 2020, 71(6): 2889-2899.
王永胜, 兰小林, 邱天, 张新平, 吴莹莹, 陈莉, 徐伟祥, 郭栋杰, 段正康. 铜基石墨烯复合催化剂的合成与表征[J]. 化工学报, 2020, 71(6): 2889-2899.
Fig.3 XRD patterns of hydrothermal products after different hydrothermal times (a), precursor of hydrothermal catalyst and reduced Cu/rGO catalyst (b)
序号 | 催化剂制备条件 | 反应时间/h | 初次排气温度/℃ | IDA 收率/% |
---|---|---|---|---|
1 | Cu/rGO(无TPA) | 5.4 | 163.4 | 68.82 |
2 | 水 | 4.2 | 158.0 | 76.89 |
3 | V(乙二醇)∶V(水)=1∶1 | 3.7 | 145.5 | 82.24 |
4 | V(乙醇)∶V(水)=1∶1 | 3.1 | 129.6 | 86.55 |
5 | pH= 12.0 | 3.9 | 156.1 | 78.21 |
6 | pH= 11.0 | 4.5 | 162.3 | 70.96 |
7 | pH= 7.0 | 6.5 | 167.2 | 29.37 |
8 | 水热2 h | 5.9 | 162.1 | 35.26 |
9 | 水热6 h | 4.4 | 159.9 | 68.19 |
10 | GO | 3.0 | — | — |
Table 1 Catalytic performance of samples in dehydrogenation of diethanolamine
序号 | 催化剂制备条件 | 反应时间/h | 初次排气温度/℃ | IDA 收率/% |
---|---|---|---|---|
1 | Cu/rGO(无TPA) | 5.4 | 163.4 | 68.82 |
2 | 水 | 4.2 | 158.0 | 76.89 |
3 | V(乙二醇)∶V(水)=1∶1 | 3.7 | 145.5 | 82.24 |
4 | V(乙醇)∶V(水)=1∶1 | 3.1 | 129.6 | 86.55 |
5 | pH= 12.0 | 3.9 | 156.1 | 78.21 |
6 | pH= 11.0 | 4.5 | 162.3 | 70.96 |
7 | pH= 7.0 | 6.5 | 167.2 | 29.37 |
8 | 水热2 h | 5.9 | 162.1 | 35.26 |
9 | 水热6 h | 4.4 | 159.9 | 68.19 |
10 | GO | 3.0 | — | — |
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