CIESC Journal ›› 2020, Vol. 71 ›› Issue (10): 4760-4772.DOI: 10.11949/0438-1157.20200065

• Surface and interface engineering • Previous Articles     Next Articles

High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts

Xue LUO1(),Haijun HUANG1(),Ziping LUO1,Zhiyong WANG1,Xiaojing MU1,Hongru LI1,Xinchao WANG1,2,Shengtao ZHANG1,Fang GAO1()   

  1. 1.School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
    2.College of Pharmacy, Heze University, Heze 274015, Shandong, China
  • Received:2020-01-16 Revised:2020-04-13 Online:2020-10-05 Published:2020-10-05
  • Contact: Fang GAO

无患子果皮提取物的纳微米聚集体对钢的高效缓蚀

罗雪1(),黄海军1(),罗自萍1,王治永1,穆小静1,李红茹1,王新潮1,2,张胜涛1,高放1()   

  1. 1.重庆大学化学化工学院,重庆 400044
    2.菏泽学院药学院,山东 菏泽 274015
  • 通讯作者: 高放
  • 作者简介:罗雪(1994—),女,硕士研究生,xueluo1994@163.com|黄海军(1993—),男,博士研究生,hhjbfn@163.com
  • 基金资助:
    国家自然科学基金项目(21376282);重庆大学研究生创新基金资助项目(CYB18046);中国博士后科学基金项目(22012T50762);重庆市自然科学基金项目(cstc2018jcyjAX0668)

Abstract:

To seek green, sustainable and natural plant extracts with the potential for large-scale application as corrosion inhibitors, this article selects the extracts of the Sapindus mukorossi Gaertn peels with surfactant properties as the research object. Hence, this article uses Sapindus mukorossi Gaertn peel extracts (SMGPE) with surfactant properties as the study candidate. This survey presents efficient extraction of Sapindus mukorossi Gaertn peels by simply refluxing ethanol solution. It is shown that SMGPE can process orderly nano-micro meters aggregation in DMF/HCl (volume ratio: 50/50, 1.0 mol/L HCl solution) mixed solution through self-organization at the room temperature.The results show that the predominantly strong chemical adsorption of formed SMGPE aggregates on the studied Q235 steel specimens is suggested through the detection of FT-IR, Raman as well as XPS spectroscopy. This study further determines the corrosion inhibition effect of the stable SMGPE aggregates for the studied steel specimens in 1.0 mol/L HCl aqueous solution based on electrochemical method. The results suggest that the SMGPE aggregates can inhibit corrosion of the steel specimens in HCl solution efficiently, and the greatest corrosion inhibition efficiency is over 90%.

Key words: self-aggregation, adsorption, steel, HCl solution, corrosion

摘要:

为寻求绿色、可持续与具备大规模应用潜能的天然植物提取物作为缓蚀剂,选择具有表面活性剂性质的无患子果皮提取物作为研究对象。通过简便乙醇回流萃取获得无患子果皮提取物。在室温条件下,无患子果皮提取物在DMF(NN-二甲基甲酰胺)/HCl水溶液的混合溶液 (体积比50/50,1.0 mol/L HCl 溶液) 中能够发生自组装产生有序的纳微米聚集材料。傅里叶变换红外光谱 (FT-IR)与X射线光电子能谱 (XPS) 研究表明了无患子果皮提取物聚集体能够对Q235钢表面产生化学吸附作用。利用电化学方法研究了无患子果皮提取物聚集体吸附在钢表面后,在1.0 mol/L盐酸水溶液中的缓蚀性能。结果表明无患子果皮提取物聚集体能够有效抑制钢被盐酸腐蚀,最大缓蚀效率达到90%以上。

关键词: 自聚集, 吸附, 钢, 盐酸溶液, 腐蚀

CLC Number: