CIESC Journal ›› 2023, Vol. 74 ›› Issue (7): 2919-2925.DOI: 10.11949/0438-1157.20230406
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Bin LI1,2(), Zhenghu XU1, Shuang JIANG1,2(), Tianyong ZHANG1,2,3()
Received:
2023-04-26
Revised:
2023-07-19
Online:
2023-08-31
Published:
2023-07-05
Contact:
Shuang JIANG, Tianyong ZHANG
李彬1,2(), 徐正虎1, 姜爽1,2(), 张天永1,2,3()
通讯作者:
姜爽,张天永
作者简介:
李彬(1982—),男,博士,副教授,libin@tju.edu.cn
基金资助:
CLC Number:
Bin LI, Zhenghu XU, Shuang JIANG, Tianyong ZHANG. Clean and efficient synthesis of accelerator CBS by hydrogen peroxide catalytic oxidation method[J]. CIESC Journal, 2023, 74(7): 2919-2925.
李彬, 徐正虎, 姜爽, 张天永. 双氧水催化氧化法清洁高效合成促进剂CBS[J]. 化工学报, 2023, 74(7): 2919-2925.
序号 | 催化剂 | 收率/% | 纯度/% |
---|---|---|---|
1 | 无 | 84.9 | 99.3 |
2 | 乙二胺四乙酸铁钠 | 82.5 | 97.8 |
3 | 酞菁铁 | 84.0 | 98.3 |
4 | 四磺酸酞菁铁 | 81.9 | 96.0 |
5 | 酸性绿1 | 85.6 | 98.8 |
6 | 乙二胺四乙酸铜钠 | 91.1 | 95.3 |
7 | 酞菁铜 | 82.9 | 97.3 |
8 | 醋酸铜 | 94.6 | 94.3 |
9 | 乙二胺四乙酸钴钠 | 83.2 | 97.3 |
10 | 四磺酸酞菁钴 | 81.4 | 97.7 |
11 | 乙二胺四乙酸锰钠 | 82.1 | 97.8 |
12 | 酞菁锰 | 83.3 | 96.3 |
13 | 4-羟基TEMPO | 84.8 | 98.9 |
Table 1 Effects of different catalysts on the yield and purity of CBS
序号 | 催化剂 | 收率/% | 纯度/% |
---|---|---|---|
1 | 无 | 84.9 | 99.3 |
2 | 乙二胺四乙酸铁钠 | 82.5 | 97.8 |
3 | 酞菁铁 | 84.0 | 98.3 |
4 | 四磺酸酞菁铁 | 81.9 | 96.0 |
5 | 酸性绿1 | 85.6 | 98.8 |
6 | 乙二胺四乙酸铜钠 | 91.1 | 95.3 |
7 | 酞菁铜 | 82.9 | 97.3 |
8 | 醋酸铜 | 94.6 | 94.3 |
9 | 乙二胺四乙酸钴钠 | 83.2 | 97.3 |
10 | 四磺酸酞菁钴 | 81.4 | 97.7 |
11 | 乙二胺四乙酸锰钠 | 82.1 | 97.8 |
12 | 酞菁锰 | 83.3 | 96.3 |
13 | 4-羟基TEMPO | 84.8 | 98.9 |
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