CIESC Journal ›› 2023, Vol. 74 ›› Issue (5): 1862-1874.DOI: 10.11949/0438-1157.20230135
• Reviews and monographs • Previous Articles Next Articles
Xu GUO1,2(), Yongzheng ZHANG3, Houbing XIA1,2, Na YANG4, Zhenzhen ZHU1,2, Jingyao QI1,2()
Received:
2023-02-21
Revised:
2023-04-20
Online:
2023-06-29
Published:
2023-05-05
Contact:
Jingyao QI
郭旭1,2(), 张永政3, 夏厚兵1,2, 杨娜4, 朱真珍1,2, 齐晶瑶1,2()
通讯作者:
齐晶瑶
作者简介:
郭旭(1996—),男,博士研究生,guox96@163.com
基金资助:
CLC Number:
Xu GUO, Yongzheng ZHANG, Houbing XIA, Na YANG, Zhenzhen ZHU, Jingyao QI. Research progress in the removal of water pollutants by carbon-based materials via electrooxidation[J]. CIESC Journal, 2023, 74(5): 1862-1874.
郭旭, 张永政, 夏厚兵, 杨娜, 朱真珍, 齐晶瑶. 碳基材料电氧化去除水体污染物的研究进展[J]. 化工学报, 2023, 74(5): 1862-1874.
项目 | 反应式 | 序号 |
---|---|---|
间接氧化 | (2) | |
(3) | ||
析氧反应 | (4) | |
(5) | ||
(6) | ||
(7) |
Table 1 Comparison of indirect oxidation (·OH mediated) and oxygen evolution reactions
项目 | 反应式 | 序号 |
---|---|---|
间接氧化 | (2) | |
(3) | ||
析氧反应 | (4) | |
(5) | ||
(6) | ||
(7) |
Fig.1 (a) Acid pretreated carbon nanotube sponge electro-oxidation for removal of PFOA[26]; (b) Schematic diagram of carbon nanotube/urethane sponge electrochemical filter operation[27]
Fig.2 Schematic diagram of Ni@Ni3S2/CNT electrode with nanoheterojunction structure for low energy consumption of hydrogen precipitation (cathode) and electrocatalytic removal of ethanolamine contaminants from brine (anode)[34]
材料名称 | 析氧过电位 | 电解质 | 污染物 | 去除率/% | 矿化度 | 活性位点 | 活性物种 | 能耗 | 文献 |
---|---|---|---|---|---|---|---|---|---|
酸处理后 SWCNT海绵 | — | Na2SO4 | 100 μg·L-1 PFOA | 90(60 min) | — | 含氧官能团、 疏水碳骨架 | — | — | [ |
聚氨酯海绵负载MWCNT | — | Na2SO4 | 0.2 mmol·L-1 TCH | 92 | — | — | — | 5~100 kW·h·kg-1 | [ |
0.06 mmol·L-1 MO | 94 | — | |||||||
CNT-EO | — | Na2SO4 | 1.0 mmol·L-1 PhOH | — | 去除0.22 mg·h-1·cm-2 | — | ·OH | — | [ |
CNT-HNO3 | — | — | 去除0.06 mg·h-1·cm-2 | — | |||||
Pt/CNT | — | NaOH | 1 mmol·L-1 DCF | 74(6 h) | 48%(8 h) | Pt | 直接氧化 | — | [ |
Ru/CNT | — | NaHCO3/ Na2CO3 | 88(8 h) | 27%(8 h) | Ru | 直接氧化 | — | ||
Ni@Ni3S2/MWCNT | — | NaCl | 0.5 mol·L-1 ETA | 约38(20 h) | — | Ni | 直接氧化 | — | [ |
Ti/SnO2-Sb2O3/ CNT-PbO2 | 1.79 V (vs SCE) | Na2SO4 | 100 mg·L-1 MO | 78.6(2 h) | 58.2%(2 h) | — | ·OH | 225.40 kW·h·kg-1 | [ |
Ti/SnO2-Sb2O3/ Bi-CNT-PbO2 | 1.89 V (vs SCE) | 84.8(2 h) | 81.8%(2 h) | — | ·OH | 165.57 kW·h·kg-1 | |||
Bi-Sb-SnO2-CNT | — | Na2SO4 | 0.5 mmol·L-1 PhOH | 约40 (100 min) | 22%(100 min) | — | ·OH | — | [ |
Sb-SnO2-CNT | 约30 (100 min) | 13%(100 min) | |||||||
Ti/MWCNTs/ SnO2-Sb-Er | 2.15 V (vs SCE) | Na2SO4 | 50 mg·L-1 Cefotaxime | 83.7 (60 min) | 约80% (60 min) | — | ·OH | — | [ |
Ti/MWCNTs/ SnO2-Sb | 约1.9 V (vs SCE) | 100 (60 min) | 约65% (60 min) |
Table 2 Comparison of typical carbon nanotube-based anode materials and their parameters related to degradation of pollutants
材料名称 | 析氧过电位 | 电解质 | 污染物 | 去除率/% | 矿化度 | 活性位点 | 活性物种 | 能耗 | 文献 |
---|---|---|---|---|---|---|---|---|---|
酸处理后 SWCNT海绵 | — | Na2SO4 | 100 μg·L-1 PFOA | 90(60 min) | — | 含氧官能团、 疏水碳骨架 | — | — | [ |
聚氨酯海绵负载MWCNT | — | Na2SO4 | 0.2 mmol·L-1 TCH | 92 | — | — | — | 5~100 kW·h·kg-1 | [ |
0.06 mmol·L-1 MO | 94 | — | |||||||
CNT-EO | — | Na2SO4 | 1.0 mmol·L-1 PhOH | — | 去除0.22 mg·h-1·cm-2 | — | ·OH | — | [ |
CNT-HNO3 | — | — | 去除0.06 mg·h-1·cm-2 | — | |||||
Pt/CNT | — | NaOH | 1 mmol·L-1 DCF | 74(6 h) | 48%(8 h) | Pt | 直接氧化 | — | [ |
Ru/CNT | — | NaHCO3/ Na2CO3 | 88(8 h) | 27%(8 h) | Ru | 直接氧化 | — | ||
Ni@Ni3S2/MWCNT | — | NaCl | 0.5 mol·L-1 ETA | 约38(20 h) | — | Ni | 直接氧化 | — | [ |
Ti/SnO2-Sb2O3/ CNT-PbO2 | 1.79 V (vs SCE) | Na2SO4 | 100 mg·L-1 MO | 78.6(2 h) | 58.2%(2 h) | — | ·OH | 225.40 kW·h·kg-1 | [ |
Ti/SnO2-Sb2O3/ Bi-CNT-PbO2 | 1.89 V (vs SCE) | 84.8(2 h) | 81.8%(2 h) | — | ·OH | 165.57 kW·h·kg-1 | |||
Bi-Sb-SnO2-CNT | — | Na2SO4 | 0.5 mmol·L-1 PhOH | 约40 (100 min) | 22%(100 min) | — | ·OH | — | [ |
Sb-SnO2-CNT | 约30 (100 min) | 13%(100 min) | |||||||
Ti/MWCNTs/ SnO2-Sb-Er | 2.15 V (vs SCE) | Na2SO4 | 50 mg·L-1 Cefotaxime | 83.7 (60 min) | 约80% (60 min) | — | ·OH | — | [ |
Ti/MWCNTs/ SnO2-Sb | 约1.9 V (vs SCE) | 100 (60 min) | 约65% (60 min) |
Fig.3 (a) The edge sulfur containing and skeletal sulfur doped graphene by modulating the precursors and preparation[20]; (b) Sulfur doped reduced graphene oxide as an active layer to enhance the electrooxidation performance and stability of Ti/Ce-Mn/SnO2-Sb-La electrodes[48]
Fig.4 Schematic diagram of a bifunctional Co3O4 nanosphere-loaded nitrogen-doped reduced graphene oxide electrode for simultaneous electro-oxidation of methylene blue removal and CO2 reduction for selective methanol production[53]
材料名称 | 析氧过电位 | 电解质 | 污染物 | 去除率/% | 矿化度/% | 活性位点 | 活性物种 | 能耗 | 文献 |
---|---|---|---|---|---|---|---|---|---|
P-N-GN | — | NaCl | 10 mg·L-1 APAP | 98.2±1.8 (60 min) | 78.5(180 min) | 含磷、氮元素 的官能团 | 活性氯和 | 0.017 kW·h·g-1 | [ |
A-SGO | — | NaCl | 10×10-6 BPA | 97(120 min) | 78.5(60 min) | —COOH,—OH和C—SO3 | 活性氯和 | — | [ |
S-GO/Pt/TiO2 | — | NaCl | 10 mg·L-1 APAP | 98(90 min) | 44.1(4 h) | —SO x 旁边的 碳原子 | 直接氧化 | 0.069 kW·h·g-1 | [ |
—SO x | 活性氯 和·OH | ||||||||
Ti/Ce-Mn/ SnO2-Sb-La-S-rGO | 2.12 V | Na2SO4 | 100 mg·L-1 PhOH | 89.5(120 min) | 79.8(120 min) | — | ·OH | — | [ |
GNP-PbO2 | 2.05 V (vs SCE) | Na2SO4 | 100 mg·L-1 ENO | 92.69(120 min) | 62.5(120 min) | — | ·OH | — | [ |
Borophene-rGO | — | 磷酸盐缓冲液和NaCl | 1 µmol·L-1 DTR | 89±1 | — | —O—C— B—N— | ·OH和1O2 | 4.13 kW·h·m-3 | [ |
hBN-rGO | 76±1 | — | 5.73 kW·h·m-3 | ||||||
Cu-rGO-PC | — | Na2SO4 | 20 mg·L-1 DCF | 100(60 min) | — | rGO | 直接氧化 | — | [ |
Cu | ·OH和 活性氯 | ||||||||
Co3O4/N-rGO | — | KOH | 100 mg·L-1 MB | 100(30 min) | — | Co | ·OH | — | [ |
Table 3 Comparison of typical graphene-based anode materials and their parameters related to degradation of pollutants
材料名称 | 析氧过电位 | 电解质 | 污染物 | 去除率/% | 矿化度/% | 活性位点 | 活性物种 | 能耗 | 文献 |
---|---|---|---|---|---|---|---|---|---|
P-N-GN | — | NaCl | 10 mg·L-1 APAP | 98.2±1.8 (60 min) | 78.5(180 min) | 含磷、氮元素 的官能团 | 活性氯和 | 0.017 kW·h·g-1 | [ |
A-SGO | — | NaCl | 10×10-6 BPA | 97(120 min) | 78.5(60 min) | —COOH,—OH和C—SO3 | 活性氯和 | — | [ |
S-GO/Pt/TiO2 | — | NaCl | 10 mg·L-1 APAP | 98(90 min) | 44.1(4 h) | —SO x 旁边的 碳原子 | 直接氧化 | 0.069 kW·h·g-1 | [ |
—SO x | 活性氯 和·OH | ||||||||
Ti/Ce-Mn/ SnO2-Sb-La-S-rGO | 2.12 V | Na2SO4 | 100 mg·L-1 PhOH | 89.5(120 min) | 79.8(120 min) | — | ·OH | — | [ |
GNP-PbO2 | 2.05 V (vs SCE) | Na2SO4 | 100 mg·L-1 ENO | 92.69(120 min) | 62.5(120 min) | — | ·OH | — | [ |
Borophene-rGO | — | 磷酸盐缓冲液和NaCl | 1 µmol·L-1 DTR | 89±1 | — | —O—C— B—N— | ·OH和1O2 | 4.13 kW·h·m-3 | [ |
hBN-rGO | 76±1 | — | 5.73 kW·h·m-3 | ||||||
Cu-rGO-PC | — | Na2SO4 | 20 mg·L-1 DCF | 100(60 min) | — | rGO | 直接氧化 | — | [ |
Cu | ·OH和 活性氯 | ||||||||
Co3O4/N-rGO | — | KOH | 100 mg·L-1 MB | 100(30 min) | — | Co | ·OH | — | [ |
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