CIESC Journal ›› 2024, Vol. 75 ›› Issue (10): 3660-3668.DOI: 10.11949/0438-1157.20240299
• Separation engineering • Previous Articles Next Articles
Chenming GAO1(), Qian ZHANG1(
), Yang WEI2, Baolin ZHANG1, Qi WANG1, Xiangyang LI1, Le LI1, Bin XUE1, Wei HUANG1
Received:
2024-03-13
Revised:
2024-04-22
Online:
2024-11-04
Published:
2024-10-25
Contact:
Qian ZHANG
高晨明1(), 张乾1(
), 魏洋2, 张宝霖1, 王奇1, 李向阳1, 李乐1, 薛斌1, 黄伟1
通讯作者:
张乾
作者简介:
高晨明(1999—),男,硕士研究生,19935373644@163.com
基金资助:
CLC Number:
Chenming GAO, Qian ZHANG, Yang WEI, Baolin ZHANG, Qi WANG, Xiangyang LI, Le LI, Bin XUE, Wei HUANG. Extraction and separation of carbon from coal water slurry gasification fine slag by waterflow classifier[J]. CIESC Journal, 2024, 75(10): 3660-3668.
高晨明, 张乾, 魏洋, 张宝霖, 王奇, 李向阳, 李乐, 薛斌, 黄伟. 水煤浆煤气化细渣水流分级提炭分质[J]. 化工学报, 2024, 75(10): 3660-3668.
样品 | 工业分析/% | 元素分析/% | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Mar | Ad | Vd | FCd | Cd | Hd | Nd | O① | St,d | H/C | |
煤 | 1.15 | 5.72 | 30.24 | 64.04 | 73.83 | 4.01 | 0.76 | 15.43 | 0.25 | 0.65 |
细渣 | 63.22 | 63.03 | 5.59 | 31.38 | 35.09 | 0.65 | 0.20 | 0.13 | 0.90 | 0.22 |
Table 1 Proximate and ultimate analyses of the samples
样品 | 工业分析/% | 元素分析/% | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Mar | Ad | Vd | FCd | Cd | Hd | Nd | O① | St,d | H/C | |
煤 | 1.15 | 5.72 | 30.24 | 64.04 | 73.83 | 4.01 | 0.76 | 15.43 | 0.25 | 0.65 |
细渣 | 63.22 | 63.03 | 5.59 | 31.38 | 35.09 | 0.65 | 0.20 | 0.13 | 0.90 | 0.22 |
成分 | 质量分数/% |
---|---|
MgO | 8.06 |
Al2O3 | 16.33 |
SiO2 | 29.51 |
P2O5 | 0.79 |
SO3 | 5.16 |
ClO2 | 0.99 |
K2O | 1.33 |
CaO | 14.1 |
TiO2 | 0.86 |
Fe2O3 | 21.71 |
others | 1.18 |
Table 2 Inorganic mineral composition of the coal gasification fine slag by XRF analysis
成分 | 质量分数/% |
---|---|
MgO | 8.06 |
Al2O3 | 16.33 |
SiO2 | 29.51 |
P2O5 | 0.79 |
SO3 | 5.16 |
ClO2 | 0.99 |
K2O | 1.33 |
CaO | 14.1 |
TiO2 | 0.86 |
Fe2O3 | 21.71 |
others | 1.18 |
粒级/mm | 产率/% | 烧失量/% | 灰分 含量/% | 累计 产率/% | 筛上灰分/% |
---|---|---|---|---|---|
>0.50 | 3.64 | 47.81 | 52.19 | 3.64 | 52.19 |
0.50~0.25 | 16.34 | 67.71 | 32.29 | 19.98 | 35.36 |
0.25~0.18 | 19.68 | 64.43 | 35.57 | 39.66 | 56.63 |
0.18~0.15 | 11.89 | 58.80 | 41.20 | 51.55 | 38.05 |
0.15~0.074 | 21.45 | 39.10 | 60.90 | 73.00 | 46.93 |
0.074~0.065 | 25.34 | 18.27 | 81.73 | 98.34 | 55.05 |
0.065~0.043 | 1.55 | 15.26 | 84.74 | 99.89 | 69.85 |
0.043~0.03 | 0.03 | 3.26 | 96.74 | 99.92 | 71.99 |
<0.03 | 0.07 | 2.87 | 97.13 | 100.00 | 76.28 |
Table 3 Particle size distribution of fine slag
粒级/mm | 产率/% | 烧失量/% | 灰分 含量/% | 累计 产率/% | 筛上灰分/% |
---|---|---|---|---|---|
>0.50 | 3.64 | 47.81 | 52.19 | 3.64 | 52.19 |
0.50~0.25 | 16.34 | 67.71 | 32.29 | 19.98 | 35.36 |
0.25~0.18 | 19.68 | 64.43 | 35.57 | 39.66 | 56.63 |
0.18~0.15 | 11.89 | 58.80 | 41.20 | 51.55 | 38.05 |
0.15~0.074 | 21.45 | 39.10 | 60.90 | 73.00 | 46.93 |
0.074~0.065 | 25.34 | 18.27 | 81.73 | 98.34 | 55.05 |
0.065~0.043 | 1.55 | 15.26 | 84.74 | 99.89 | 69.85 |
0.043~0.03 | 0.03 | 3.26 | 96.74 | 99.92 | 71.99 |
<0.03 | 0.07 | 2.87 | 97.13 | 100.00 | 76.28 |
粒径/mm | 产率/% | 灰分 含量/% | 烧失量/% | 密度/ (g/cm3) | 持水量/% |
---|---|---|---|---|---|
>0.50 | 6.52 | 38.50 | 61.50 | 1.96 | 61.50 |
0.50~0.15 | 32.62 | 24.15 | 75.85 | 2.01 | 77.49 |
0.15~0.074 | 7.83 | 54.56 | 45.44 | 2.11 | 61.07 |
<0.074 | 50.29 | 79.39 | 19.61 | 2.51 | 21.02 |
Table 4 Fine slag wet screening
粒径/mm | 产率/% | 灰分 含量/% | 烧失量/% | 密度/ (g/cm3) | 持水量/% |
---|---|---|---|---|---|
>0.50 | 6.52 | 38.50 | 61.50 | 1.96 | 61.50 |
0.50~0.15 | 32.62 | 24.15 | 75.85 | 2.01 | 77.49 |
0.15~0.074 | 7.83 | 54.56 | 45.44 | 2.11 | 61.07 |
<0.074 | 50.29 | 79.39 | 19.61 | 2.51 | 21.02 |
样品/mm | 真密度/ (g/cm3) | 比表面积/ (m2/g) | 孔体积/ (cm3/g) |
---|---|---|---|
>0.50-F | 1.84 | 192.20 | 0.16 |
>0.50 | 1.96 | 130.15 | 0.09 |
>0.50-W | 2.27 | 97.45 | 0.10 |
0.50~0.15-F | 1.95 | 407.56 | 0.34 |
0.50~0.15 | 2.01 | 335.38 | 0.06 |
0.50~0.15-W | 2.18 | 222.16 | 0.14 |
0.15~0.074-F | 2.02 | 216.89 | 0.23 |
0.15~0.074 | 2.11 | 183.45 | 0.19 |
0.15~0.074-W | 2.51 | 87.56 | 0.14 |
<0.074-F | 2.39 | 226.09 | 0.25 |
<0.074 | 2.51 | 188.08 | 0.20 |
<0.074-W | 2.55 | 16.67 | 0.18 |
Table 5 Separation sample properties
样品/mm | 真密度/ (g/cm3) | 比表面积/ (m2/g) | 孔体积/ (cm3/g) |
---|---|---|---|
>0.50-F | 1.84 | 192.20 | 0.16 |
>0.50 | 1.96 | 130.15 | 0.09 |
>0.50-W | 2.27 | 97.45 | 0.10 |
0.50~0.15-F | 1.95 | 407.56 | 0.34 |
0.50~0.15 | 2.01 | 335.38 | 0.06 |
0.50~0.15-W | 2.18 | 222.16 | 0.14 |
0.15~0.074-F | 2.02 | 216.89 | 0.23 |
0.15~0.074 | 2.11 | 183.45 | 0.19 |
0.15~0.074-W | 2.51 | 87.56 | 0.14 |
<0.074-F | 2.39 | 226.09 | 0.25 |
<0.074 | 2.51 | 188.08 | 0.20 |
<0.074-W | 2.55 | 16.67 | 0.18 |
叶轮转速/(r/min) | 可燃体 回收率/% | 可燃体 质量分数/% | 综合效率/% |
---|---|---|---|
500 | 20.13 | 74.34 | 5.50 |
1000 | 25.75 | 75.29 | 7.88 |
1500 | 49.33 | 84.01 | 27.77 |
2000 | 51.91 | 76.58 | 18.06 |
2500 | 53.97 | 77.02 | 19.52 |
Table 6 The separation results of particle size (>0.074 mm) under different impeller speeds
叶轮转速/(r/min) | 可燃体 回收率/% | 可燃体 质量分数/% | 综合效率/% |
---|---|---|---|
500 | 20.13 | 74.34 | 5.50 |
1000 | 25.75 | 75.29 | 7.88 |
1500 | 49.33 | 84.01 | 27.77 |
2000 | 51.91 | 76.58 | 18.06 |
2500 | 53.97 | 77.02 | 19.52 |
水流速/(10 | 可燃体 回收率/% | 可燃体 质量分数/% | 综合效率/% |
---|---|---|---|
1.54 | 43.34 | 84.11 | 26.71 |
1.93 | 49.33 | 84.01 | 27.77 |
2.31 | 50.16 | 83.56 | 33.31 |
2.70 | 64.24 | 84.68 | 42.79 |
3.09 | 65.85 | 84.44 | 43.39 |
3.47 | 68.57 | 83.29 | 42.79 |
Table 7 The separation results of particle size (>0.074 mm) under different water velocities
水流速/(10 | 可燃体 回收率/% | 可燃体 质量分数/% | 综合效率/% |
---|---|---|---|
1.54 | 43.34 | 84.11 | 26.71 |
1.93 | 49.33 | 84.01 | 27.77 |
2.31 | 50.16 | 83.56 | 33.31 |
2.70 | 64.24 | 84.68 | 42.79 |
3.09 | 65.85 | 84.44 | 43.39 |
3.47 | 68.57 | 83.29 | 42.79 |
样品 | 综合效率/% | 可燃体 质量分数/% |
---|---|---|
全粒径细渣 | 18.93 | 55.90 |
先湿筛再逐级分级合计 | 44.35 | 64.45 |
先湿筛再逐级分级合计 (>0.074 mm) 宽粒级 (>0.074 mm) | 40.14 43.39 | 79.57 84.44 |
Table 8 Evaluation of water flow classification efficiency
样品 | 综合效率/% | 可燃体 质量分数/% |
---|---|---|
全粒径细渣 | 18.93 | 55.90 |
先湿筛再逐级分级合计 | 44.35 | 64.45 |
先湿筛再逐级分级合计 (>0.074 mm) 宽粒级 (>0.074 mm) | 40.14 43.39 | 79.57 84.44 |
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