化工学报 ›› 2021, Vol. 72 ›› Issue (11): 5443-5454.DOI: 10.11949/0438-1157.20210761

• 综述与专论 • 上一篇    下一篇

两亲嵌段共聚物基高内相乳液模板的制备与应用研究进展

李锦锦1(),吴优2,周寅宁1,罗正鸿1()   

  1. 1.上海交通大学化学化工学院,上海 200240
    2.上海电力大学环境与化学工程学院,上海 200090
  • 收稿日期:2021-06-07 修回日期:2021-08-20 出版日期:2021-11-05 发布日期:2021-11-12
  • 通讯作者: 李锦锦,罗正鸿
  • 作者简介:李锦锦(1987—),女,博士,助理研究员,jinjin__li@126.com
  • 基金资助:
    国家自然科学基金青年项目(21808140)

Progress in preparation and application of amphiphilic block copolymer stabilized high internal phase emulsion templates

Jinjin LI1(),You WU2,Yinning ZHOU1,Zhenghong LUO1()   

  1. 1.School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200420, China
    2.College of Environmental and Chemical Engineering, Shanghai University of Electric Power, Shanghai 200090, China
  • Received:2021-06-07 Revised:2021-08-20 Online:2021-11-05 Published:2021-11-12
  • Contact: Jinjin LI,Zhenghong LUO

摘要:

多孔聚合物材料具有孔隙率高、加工性能好、质量轻的特点,在化学工程、生物医学工程及环境工程等领域具有广阔的应用前景。高内相乳液模板法为多孔聚合物材料提供了一种简单高效的制备途径,且以此方法制备的多孔材料形状及结构可控,因而引起了人们的广泛关注。本文聚焦于两亲嵌段共聚物稳定的高内相乳液及其所制备多孔聚合物的最新研究进展。同时,介绍了该类型多孔聚合物材料在吸附分离、生物医学、能量存储及催化材料等领域的应用。最后,对该领域的未来发展进行了展望。

关键词: 高内相乳液, 聚合, 两亲嵌段共聚物, 多孔聚合物材料, 产品工程

Abstract:

Porous polymeric materials that possess high porosity, good processability, and light mass are widely used in chemical engineering, biomedical engineering, and environmental engineering. High internal phase emulsion (HIPE) templating provides a simple and efficient way to prepare porous polymer materials (i.e., polyHIPEs), and the shape and structure of the as-prepared polyHIPEs can be well controlled, therefore, it receives a great deal of attentions. This article focuses on the recent research progress of amphiphilic block copolymer stabilized HIPEs and the preparation of porous polymers by HIPE templating. In addition, frontiers in the applications of such porous polymeric materials in the fields of adsorption and separation, biomedicine, energy storage, and catalytic materials are also introduced. Finally, the future development in both of the preparation and application of polyHIPEs are prospected.

Key words: high internal phase emulsion, polymerization, amphiphilic block copolymer, porous polymeric materials, product engineering

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