化工学报 ›› 2018, Vol. 69 ›› Issue (6): 2339-2352.DOI: 10.11949/j.issn.0438-1157.20180096
崔希利, 邢华斌
收稿日期:
2018-01-22
修回日期:
2018-03-26
出版日期:
2018-06-05
发布日期:
2018-06-05
通讯作者:
邢华斌
基金资助:
国家自然科学基金项目(21725603,21436010);浙江省自然科学基金项目(LZ18B060001)。
CUI Xili, XING Huabin
Received:
2018-01-22
Revised:
2018-03-26
Online:
2018-06-05
Published:
2018-06-05
Supported by:
supported by the National Natural Science Foundation of China (21725603, 21436010) and the Natural Science Foundation of Zhejiang Province (LZ18B060001).
摘要:
烯烃、烷烃和炔烃等结构相似物的高效分离是石油化学工业可持续发展的关键过程之一。低碳烃化合物结构和性质相近,仅在碳数和不饱和度存在微小差异,传统低温精馏过程选择性低、能耗高。金属有机框架材料/多孔配位聚合物(MOF/PCP)的结构多样性及可设计性使其可以精确识别相似物分子间的微小差异,在低碳烃分离领域取得重要进展。综述了金属有机框架材料在碳二/碳三的烯烃、炔烃和烷烃分离体系中取得的最新进展以及分离机理,探讨了金属有机框架材料在低碳烃吸附分离研究中存在的问题和发展方向。
中图分类号:
崔希利, 邢华斌. 金属有机框架材料分离低碳烃的研究进展[J]. 化工学报, 2018, 69(6): 2339-2352.
CUI Xili, XING Huabin. Separation of light hydrocarbons with metal-organic frameworks[J]. CIESC Journal, 2018, 69(6): 2339-2352.
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