化工学报 ›› 2015, Vol. 66 ›› Issue (3): 1208-1214.DOI: 10.11949/j.issn.0438-1157.20141252

• 材料化学工程与纳米技术 • 上一篇    下一篇

空调用纳米有机复合相变蓄冷材料制备与热物性

武卫东, 唐恒博, 苗朋柯, 张华   

  1. 上海理工大学制冷与低温工程研究所, 上海 200093
  • 收稿日期:2014-08-20 修回日期:2014-12-08 出版日期:2015-03-05 发布日期:2015-03-05
  • 通讯作者: 武卫东
  • 基金资助:

    国家自然科学基金项目(50606027);上海市自然科学基金项目(14ZR1429000)。

Preparation and thermal properties of nano-organic composite phase change materials for cool storage in air-conditioning

WU Weidong, TANG Hengbo, MIAO Pengke, ZHANG Hua   

  1. Institute of Refrigeration and Cryogenic Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
  • Received:2014-08-20 Revised:2014-12-08 Online:2015-03-05 Published:2015-03-05
  • Supported by:

    supported by National Natural Science Foundation of China(50606027) and the Natural Science Foundation of Shanghai (14ZR1429000).

摘要:

针对目前空调用有机相变蓄冷材料热导率低的问题,将具有高导热性的纳米材料(MWNTs、Al2O3、Fe2O3)添加到所开发制备的二元复合有机蓄冷材料(质量比73.7:26.3的辛酸/肉豆蔻醇)中,从纳米材料的种类和浓度两方面,研究其对复合有机蓄冷材料热物性的影响。实验发现:对于MWNTs、Al2O3、Fe2O3 3种纳米材料,当其质量分数分别小于0.3%、0.4%、0.8%时,对应纳米复合材料热导率随纳米材料浓度的增加幅度较为明显;与原二元复合有机相变蓄冷材料相比,添加0.3%的MWNTs,热导率提高26.3%;添加0.4%的Al2O3,热导率提高13.1%;添加0.8%的Fe2O3,热导率提高32.1%;当在一定纳米材料质量分数(如0.7%)下,加入纳米颗粒的复合材料导热性能效果依次为Fe2O3>MWNTs>Al2O3。不同纳米粒子的添加对原蓄冷材料的相变温度和相变潜热影响很小,相变温度变化波动最大为0.4℃,相变潜热变化波动范围最大为1.4%。

关键词: 有机相变材料, 空调蓄冷, 纳米材料, 热物性, 强化传热, 热传导, 制备

Abstract:

One of the greatest challenges in the application of organic phase change materials (PCMs) is to increase their thermal conductivity while maintaining high phase change enthalpy. To prepare nano-organic composite PCMs for air-conditioning cool storage, nanomaterials with high thermal conductivity, including multi-walled carbon nano-tubes (MWNTs), Al2O3 and Fe2O3, were respectively added into the organic composite PCMs of caprylic acid/myristyl alcohol (with mass ratio of 73.7 to 26.3), developed previously in this study. The thermal properties of nano-organic composite PCMs were analyzed by measuring their thermal conductivity coefficient. The kinds and concentrations of nano-materials are key influencing factors. The experiments showed that heat conductivities increased obviously when mass fractions of MWNTs, Al2O3 and Fe2O3 nanomaterials were less than 0.3%, 0.4% and 0.8%, respectively. Compared with the original PCMs, heat conductivity increased by 26.3% when mass fraction of MWNTs was 0.3%; heat conductivity increased by 13.1% when mass fraction of Al2O3 was 0.4%; the heat conductivity increased by 32.1% when mass fraction of Fe2O3 was 0.8%. The thermal conductivity enhancement effects were in the order of Fe2O3, MWNTs and Al2O3 at a specific mass fraction (e.g., 0.7%) of nanomaterials. The nano-organic composite PCMs prepared had a limited influence on phase change temperature and phase change enthalpy of the original PCMs, fluctuation of phase change temperature was less than 0.4℃, and the greatest fluctuation range of phase change enthalpy was 1.4%.

Key words: organic phase change materials, cool storage in air-conditioning, nanomaterials, thermal properties, heat transfer enhancement, heat conduction, preparation

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