化工学报 ›› 2017, Vol. 68 ›› Issue (12): 4750-4755.DOI: 10.11949/j.issn.0438-1157.20170775

• 能源和环境工程 • 上一篇    下一篇

角质酶/表面活性剂体系对混合办公废纸的协同脱墨作用

王凤1,2, 龙柱1,2,3, 吴美燕1,2, 陈杰1,2, 张辉3   

  1. 1 江南大学纺织服装学院造纸研究室, 江苏 无锡 214122;
    2 江南大学生态纺织教育部重点实验室, 江苏 无锡 214122;
    3 南京林业大学江苏省制浆造纸科学与技术重点实验室, 江苏 南京 210037
  • 收稿日期:2017-06-15 修回日期:2017-08-15 出版日期:2017-12-05 发布日期:2017-12-05
  • 通讯作者: 龙柱
  • 基金资助:

    国家自然科学基金项目(31270633);江苏省制浆造纸科学与技术重点实验室开放课题项目(201532)。

Deinking of mixed office waste paper by cutinase/surfactant system

WANG Feng1,2, LONG Zhu1,2,3, WU Meiyan1,2, CHEN Jie1,2, ZHANG Hui3   

  1. 1 Laboratory of Papermaking, School of Textiles & Clothing, Jiangnan University, Wuxi 214122, Jiangsu, China;
    2 Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, Jiangsu, China;
    3 Jiangsu Provincial Key Laboratory of Pulp and Paper Science and Technology, Nanjing Forestry University, Nanjing 210037, Jiangsu, China
  • Received:2017-06-15 Revised:2017-08-15 Online:2017-12-05 Published:2017-12-05
  • Supported by:

    supported by the National Natural Science Foundation of China(31270633).

摘要:

角质酶能够水解可溶性酯、不溶性甘油三酯和各种聚酯,因此可以水解油墨中的连接料,有代替脂肪酶应用于废纸脱墨领域的潜能。利用角质酶和实验室复配得到的表面活性剂协同应用于混合办公废纸脱墨领域,探讨其脱墨效果和最优工艺,并与常用商业脂肪酶进行脱墨效果比较。结果表明,角质酶在酶用量10 U·g-1,酶处理时间30 min,酶处理温度50℃,表面活性剂用量0.2%的条件下可以达到最优效果。与脂肪酶/表面活性剂以及单独用表面活性剂脱墨相比,角质酶脱墨后纸页的白度与油墨去除率更高,纸页的机械强度也较好。通过纸页性能的对比和扫描电镜(SEM)观察,角质酶的脱墨效果较脂肪酶更佳,角质酶/表面活性剂体系对混合办公废纸脱墨效果较好。

关键词: 角质酶, 表面活性剂, 混合办公废纸, 浮选脱墨

Abstract:

Cutinase is capable of hydrolyzing soluble esters, insoluble triglycerides and various polyesters, and thus it can hydrolyze the binder in the ink and have the potential to replace lipase in the field of waste paper deinking. Cutinase and self-made surfactant was synergically used in deinking of office waste paper. The deinking effect and optimum process were discussed and compared with the conventional commercial lipase. The results showed that the optimal effect of cutinase could be achieved under the conditions of enzyme dosage of 10 U·g-1, enzyme treatment time of 30 min, enzyme treatment temperature of 50℃ and surfactant dosage of 0.2%. Compared with lipase/surfactant and surfactant deinking, the brightness and ink removal rate of paper after cutinase deinking were higher and the mechanical strength of paper was also greatly improved. By comparison of the paper performance and scanning electron microscopy (SEM) analysis, the deinking effect of cutinase was better than that of lipase.

Key words: cutinase, surfactant, mixed office waste paper, flotation deinking

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