化工学报 ›› 2013, Vol. 64 ›› Issue (1): 198-209.DOI: 10.3969/j.issn.0438-1157.2013.01.022

• 综述与专论 • 上一篇    下一篇

金属配合物配体上离子取代基对其部分催化性能影响的研究进展

胡敬辉1, 姚加2, 王从敏2, 陈志荣1, 李浩然1,2   

  1. 1. 浙江大学化学工程与生物工程学系,化学工程联合国家重点实验室,浙江 杭州 310027;
    2. 浙江大学化学系,浙江 杭州 310027
  • 收稿日期:2012-08-20 修回日期:2012-09-07 出版日期:2013-01-05 发布日期:2013-01-05
  • 通讯作者: 李浩然
  • 作者简介:胡敬辉(1985—),男,博士研究生。
  • 基金资助:

    国家自然科学基金重点项目(20990221)。

Research progress of metal complex catalysts with ionic substituents on ligand

HU Jinghui1, YAO Jia2, WANG Congmin2, CHEN Zhirong1, LI Haoran1,2   

  1. 1. State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China;
    2. Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China
  • Received:2012-08-20 Revised:2012-09-07 Online:2013-01-05 Published:2013-01-05
  • Supported by:

    supported by the National Natural Science Foundation of China (20990221).

摘要: 常规有机取代基在调节催化剂活性方面已经得到广泛的应用与研究。近年来常被用于回收均相催化剂的离子取代基也逐渐被用于调节催化剂的活性。本文着重综述了近十年来离子取代基在调节金属配合物部分催化剂活性方面的研究进展,同时指出了目前离子取代基在调节催化剂催化性能方面存在的问题、挑战及发展方向。

关键词: 离子取代基, 金属配合物, 催化剂

Abstract: Conventional organic substituents on the ligand of metal complex catalysts have been widely used to tune their activities and selectivities.Recently, ionic substituents, which usually enable the homogeneous catalyst dissolve in water and be recovered, are also involved in improving the activity of catalyst.The research progress of how ionic substituents on the ligand of metal complex catalyst tuned its activity in the past decade is reviewed.Furthermore, the problems, challenges, and directions of this field are presented.

Key words: ionic substituent, metal complex, catalyst

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