化工学报 ›› 2008, Vol. 59 ›› Issue (4): 1051-1057.

• 材料化学工程与纳米技术 • 上一篇    下一篇

生态化利用油页岩制备白炭黑和氧化铝

李勇;冯宗玉;薛向欣;贺燕;乔桂波   

  1. 东北大学材料与冶金学院,辽宁 沈阳 110004;沈阳理工大学材料科学与工程学院,辽宁 沈阳 110168
  • 出版日期:2008-04-05 发布日期:2008-04-05

Ecological utilization of oil shale by preparing silica and alumina

LI Yong;FENG Zongyu;XUE Xiangxin;HE Yan;QIAO Guibo   

  • Online:2008-04-05 Published:2008-04-05

摘要:

利用油页岩为原料,首先采用碱溶-沉淀法制备了白炭黑,降低了油页岩中的SiO2的含量,具体工艺条件为:NaOH/SiO2(物质的量)=4,水/油页岩(质量)=1,100℃,6 h,粒径≥0.15 mm。然后采用酸浸法,制备了γ-Al2O3,降低了油页岩中的Al2O3和Fe2O3的含量,具体条件为:酸浸液中用NaOH溶液调整到pH=12.0,过滤分离,再用HCl调整溶液pH=6.0,使Al2O3和Fe2O3完全分离。最后得到了含量为71.6%的干酪根,并经FT-IR验证。

关键词: 油页岩, 白炭黑, 氧化铝, 生态化利用

Abstract:

Silica was prepared by alkali dissolution-precipitation with oil shale as starting material, and the content of SiO2 in oil shale was reduced.The detailed processing conditions were as follows: molar ratio of NaOH to SiO2 was 4, mass ratio of water to oil shale was 1, the treating condition was at 100℃ for 6 h, and grain size was more than 0.15 mm.Then acid leaching of oil shale was performed to prepare γ-Al2O3, and the content of Al2O3 and Fe2O3 in oil shale was reduced too.The acid leachate solution was modulated to pH=12.0 by adding alkali solution, and a mixture of γ-Al2O3 and Fe2O3 was precipitated and filtered, then γ-Al2O3 and Fe2O3 were separated completely by adding acid solution to pH=6.0.Finally, the treated oil shale had a kerogen content of 71.6% and the kerogen was validated by FT-IR.

Key words: 油页岩, 白炭黑, 氧化铝, 生态化利用